: Bonide Rose Shield Concentrate

Transcription

1 Date of issue: 05/20/2015 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Mixture Product code : : 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Fungicide Insecticide 1.3. Details of the supplier of the safety data sheet Bonide Products, Inc Sutliff Road Oriskany, NY T (315) Emergency telephone number Emergency number : CHEMTREC - 1 (800) and/or 1 (703) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Not classified 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS08 : Warning GHS07 : H320 - Causes eye irritation H332 - Harmful if inhaled H335 - May cause respiratory irritation H336 - May cause drowsiness or dizziness H373 - May cause damage to organs through prolonged or repeated exposure through prolonged or repeated exposure. : P260 - Do not breathe mist P271 - Use only outdoors or in a well-ventilated area P264 - Wash hands and face thoroughly after handling P304 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention P312 - Call a POISON CENTER/doctor/physician if you feel unwell P405 - Store locked up P501 - Dispose of contents/container to in accordance with local/national regulations 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients Mixture 05/20/2015 EN (English US) Page 1

2 Name Product identifier % Classification (GHS-US) Difenoconazole (CAS No) Not classified thiamethoxam (CAS No) Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 lambda-cyhalothrin (CAS No) Acute Tox. 3 (Oral), H301 Acute Tox. 4 (Dermal), H312 Acute Tox. 2 (Inhalation:dust,mist), H330 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact : Drowsiness or dizziness. : Respiratory irritation. : May cause temporary itching, tingling, burning or numbness of exposed skin, called paresthesia. : Eye irritation Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture Fire hazard : During a fire, irritating and possibly toxic gases may be generated by thermal decomposition or combustion Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 05/20/2015 EN (English US) 2/6

3 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Provide good ventilation in process area to prevent formation of vapor Conditions for safe storage, including any incompatibilities Storage conditions : Store in original container. Keep container closed when not in use. Incompatible products : Strong bases. strong acids. Incompatible materials : Sources of ignition Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters DNEL DNEL < 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Respiratory protection : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear approved mask. : When using, do not eat, drink or smoke. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear to slightly hazy yellow liquid. Color : Clear to slightly yellow. Odor : Minimal, if any. Odor threshold ph : Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density : 1.05 Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Explosive limits /20/2015 EN (English US) 3/6

4 SECTION 10: Stability and reactivity Reactivity Chemical stability Stable under normal conditions Possibility of hazardous reactions Conditions to avoid Extremely high or low temperatures Incompatible materials none known Hazardous decomposition products Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity thiamethoxam ( ) LD50 oral rat LD50 dermal rat LC50 inhalation rat (mg/l) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) 1563 mg/kg (Rat) > 2000 mg/kg (Rat) > 3.7 mg/l/4h (Rat) ph: ph: Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact : Based on available data, the classification criteria are not met. : Respiratory irritation. : May cause temporary itching, tingling, burning or numbness of exposed skin, called paresthesia. : Eye irritation. SECTION 12: Ecological information Toxicity thiamethoxam ( ) LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 > 100 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) > 100 mg/l (48 h; Daphnia magna) > 114 mg/l (96 h; Lepomis macrochirus) > 119 mg/l (96 h; Ostreidae) Persistence and degradability Persistence and degradability 05/20/2015 EN (English US) 4/6

5 lambda-cyhalothrin ( ) Persistence and degradability Bioaccumulative potential Bioaccumulative potential thiamethoxam ( ) Log Pow lambda-cyhalothrin ( ) Bioaccumulative potential Mobility in soil Other adverse effects : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT No dangerous good in sense of transport regulations Additional information : No supplementary information available. ADR Transport document description : Transport by sea Air transport SECTION 15: Regulatory information This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION: Harmful if swallowed. Harmful if absorbed through skin. Harmful if inhaled. Avoid breathing vapor or spray mist. Remove and wash contaminated clothing before reuse. Causes moderate eye irritation. Avoid contact with skin, eyes or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet US Federal regulations Not listed on the United States TSCA (Toxic Substances Control Act) inventory International regulations CANADA EU-Regulations 05/20/2015 EN (English US) 5/6

6 Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified National regulations US State regulations SECTION 16: : None. Full text of H-phrases: see section 16: Acute Tox. 2 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category Acute Tox. 3 (Oral) Acute toxicity (oral) Category Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category Acute Tox. 4 (Oral) Acute toxicity (oral) Category Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category Aquatic Chronic 1 Hazardous to the aquatic environment - Chronic Hazard Category H301 Toxic if swallowed H302 Harmful if swallowed H312 Harmful in contact with skin H330 Fatal if inhaled H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects SDS US (GHS HazCom 2012) - Pesticides This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. 05/20/2015 EN (English US) 6/6