SAFETY DATA SHEET according to 1907/2006/EC, Article 31

Transcription

1 SAFETY DATA SHEET according to 907/2006/EC, Article 3 Page /8 SECTION : Identification of the substance/mixture and of the company/undertaking.. Product identifier Product name CAS No EC No Index No Product code D00.2. Relevant identified uses of the substance or mixture and uses advised against Description.3. Details of the supplier of the safety data sheet Company Address Web Sure Chemicals Limited Martindale Industrial Estate Hawks Green Cannock Staffordshire WS 7XN Telephone Fax Emergency telephone number sales@surechemicals.co.uk Emergency telephone number Company SECTION 2: Hazards identification Sure Chemicals Limited 8am to 5pm 2.. Classification of the substance or mixture date 2... Classification - 67/548/EEC Main hazards Classification - EC 272/ Label elements Hazard pictograms C; R35 Symbols: C: Corrosive. Causes severe burns. Skin Corr. A: H34; Signal Word Hazard Statement Danger Skin Corr. A: H34 - Causes severe skin burns and eye damage. Copyright 205 ChemSoft Limited. All rights reserved.

2 date Page 2/ Label elements Precautionary Statement: Prevention Precautionary Statement: Response Precautionary Statement: Storage Precautionary Statement: Disposal 2.3. Other hazards Other hazards P260 - Do not breathe dust/fume/gas/mist/vapours/spray. P264 - Wash thoroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P30+P330+P33 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P36+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P35+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P30 -Immediately call a POISON CENTER/doctor/. P32 - Specific treatment (see on this label). P363 - Wash contaminated clothing before reuse. P405 - Store locked up. P50 - Dispose of contents/container to No further hazards known. SECTION 3: Composition/information on ingredients 3.. Substances 67/548/EEC / 999/45/EC Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Sulphuric acid % % C; R35 M-factor. EC 272/2008 Chemical Name Index No. CAS No. EC No. REACH Registration Number Conc. (%w/w) Classification Sulphuric acid % % Skin Corr. A: H34; M-factor. SECTION 4: First aid measures 4.. Description of first aid measures Inhalation Eye contact Skin contact Ingestion 4.2. Most important symptoms and effects, both acute and delayed Inhalation Eye contact Skin contact Ingestion Inhalation of vapour may cause shortness of breath. Move the exposed person to fresh air. Seek medical attention. Causes burns. Causes severe inflammation and may damage the cornea. Seek medical attention. Causes burns. Wash off immediately with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Ingestion causes burns to the respiratory tract. DO NOT INDUCE VOMITING. If swallowed, seek medical advice immediately and show this container or label. Vapours may cause coughing and shortness of breath. Causes severe burns very quickly. Causes severe burns very quickly. If swallowed, cause severe burns to the oseophagus and/or respiratory tract Indication of any immediate medical attention and special treatment needed General information SECTION 5: Firefighting measures Treat symptomatically. If ever unsure, seek medical attention/advice immediately. Extremely corrosive to eyes and skin. Will cause severe burns within a very short time. Copyright 205 ChemSoft Limited. All rights reserved.

3 date Page 3/8 5.. Extinguishing media 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters SECTION 6: Accidental release measures Use as appropriate: Carbon dioxide (CO2), Dry chemical, Foam. Corrosive. Burning produces irritating, toxic and obnoxious fumes. Wear suitable respiratory equipment when necessary. Wear protective clothing. 6.. Personal precautions, protective equipment and emergency procedures 6.2. Environmental precautions 6.3. Methods and material for containment and cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.. Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities 7.3. Specific end use(s) Suitable packaging Ensure adequate ventilation of the working area. Evacuate personnel to a safe area. Wear suitable protective equipment. Do not allow product to enter drains. Prevent further spillage if safe. Neutralise with soda ash. Absorb with inert, absorbent material. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. See section 7 for handling information. See section 8 for personal protection information. See section 3 for disposal information. Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Wear protective clothing. Keep in a cool, dry, well ventilated area. Keep containers tightly closed. Use for intended use only. Never add water to, always add to water. CAUTION - Heat is generated, sometimes violently. Plastic containers. SECTION 8: Exposure controls/personal protection 8.. Control parameters 8... Exposure Limit Values WEL 8-hr limit ppm: - WEL 8-hr limit mg/m3: Exposure controls WEL 5 min limit ppm: - WEL 5 min limit mg/m3: - WEL 8-hr limit mg/m3 total - WEL 5 min limit mg/m3 total - inhalable dust: inhalable dust: WEL 8-hr limit mg/m3 total - WEL 5 min limit mg/m3 total - respirable dust: respirable dust: Appropriate engineering controls Individual protection measures Ensure adequate ventilation of the working area. Wear chemical protective clothing. Copyright 205 ChemSoft Limited. All rights reserved.

4 4/8 date 8.2. Exposure controls Eye / face protection Skin protection - Handprotection Skin protection - Other Respiratory protection Thermal hazards Approved safety goggles. Face shield. Chemical resistant gloves (PVC). Wear suitable protective clothing. Not normally required. SECTION 9: Physical and chemical properties 9.. Information on basic physical and chemical properties Appearance Liquid Colour Red Odour Mild Odour threshold No data available ph Melting point No data available Initial boiling point >90 Flash point No data available Evaporation rate No data available Flammability (solid, gas) Not Applicable Autoignition temperature No data available Explosive properties No data available Oxidising properties No data available Vapour pressure No data available Relative density.84 typical Viscosity No data available Vapour density No data available Upper Explosive Limit No data available Lower Explosive Limit No data available Decomposition temperature No data available Water solubility Partition coefficient (n-octanol/water) SECTION 0: Stability and reactivity 0.. Reactivity 0.2. Chemical stability 0.3. Possibility of hazardous reactions 0.4. Conditions to avoid 0.5. Incompatible materials No data available 0.6. Hazardous decomposition products Soluble in water. Stable under normal conditions. Reacts violently with water. Reacts with alkaline materials. Oxidises many organic materials. Reacts with many metals to liberate highly flammable hydrogen gas. Reacts with limestone, marble, concrete, artificial stone, etc with production of carbon dioxide gas. Avoid extremes of temperature. Copyright 205 ChemSoft Limited. All rights reserved.

5 5/8 date 0.6. Hazardous decomposition products SECTION : Toxicological information.. Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity STOT-single exposure STOT-repeated exposure Aspiration hazard..4. Toxicological Information Causes burns to the oseophagus and/or respiratory tract. Causes severe burns. Causes burns. Classified as skin corrosive, no sensitising effects. No data available SECTION 2: Ecological information 2.. Toxicity 2.2. Persistence and degradability 2.3. Bioaccumulative potential 2.4. Mobility in soil No data available Product will decrease the ph of the effluent. (acidic). Lowering of ph below 5 will induce fatalities in aquatic life. Soluble in water Results of PBT and vpvb assessment 2.6. Other adverse effects SECTION 3: Disposal considerations General information Disposal of packaging SECTION 4: Transport information Hazard pictograms Dispose of in compliance with all local and national regulations. Dispose of via approved waste disposal company. Do NOT reuse empty containers. Copyright 205 ChemSoft Limited. All rights reserved.

6 6/8 date 4.. UN number UN UN proper shipping name SULPHURIC ACID 4.3. Transport hazard class(es) ADR/RID 8 Subsidiary risk - IMDG 8 Subsidiary risk - IATA 8 Subsidiary risk Packing group Packing group 4.5. Environmental hazards Environmental hazards Marine pollutant ADR/RID II No No Hazard ID 80 Tunnel Category IMDG EmS Code IATA (E) Packing Instruction (Cargo) 855 Maximum quantity Packing Instruction (Passenger) Maximum quantity F-A S-B 30 L 85 L SECTION 5: Regulatory information 5.. Safety, health and environmental regulations/legislation specific for the substance or mixture Regulations 5.2. Chemical safety assessment SECTION 6: Other information Other information REGULATION (EC) No 907/2006 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 8 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 488/94 as well as Council Directive 76/769/EEC and Commission Directives 9/55/EEC, 93/67/EEC, 93/05/EC and 2000/2/EC. A chemical safety assessment has not been carried out for the substance or the mixture by the supplier. This document differs from the previous version in the following areas:. - Description. - CAS No. - EC No. - Index No. 2 - Other hazards. Copyright 205 ChemSoft Limited. All rights reserved.

7 7/8 date Other information Text of risk phrases in Section Classification - EC 272/ Hazard pictograms. 2 - Signal Word. 2 - Precautionary Statement: Prevention. 2 - Precautionary Statement: Response. 2 - Precautionary Statement: Storage. 2 - Precautionary Statement: Disposal. 4 - Inhalation. 4 - Eye contact. 4 - Skin contact. 4 - Ingestion Indication of any immediate medical attention and special treatment needed Reference to other sections. 8 - Skin protection - Other. 8 - Thermal hazards Information on basic physical and chemical properties (Appearance) Information on basic physical and chemical properties (Colour) Information on basic physical and chemical properties (Odour) Information on basic physical and chemical properties (Melting point) Information on basic physical and chemical properties (Flash point) Information on basic physical and chemical properties (Autoignition temperature) Information on basic physical and chemical properties (Explosive properties) Information on basic physical and chemical properties (Oxidising properties) Information on basic physical and chemical properties (Vapour pressure) Information on basic physical and chemical properties (Viscosity) Information on basic physical and chemical properties (Vapour density) Information on basic physical and chemical properties (Evaporation rate) Information on basic physical and chemical properties (Upper Explosive Limit) Information on basic physical and chemical properties (Lower Explosive Limit) Information on basic physical and chemical properties (Decomposition temperature) Information on basic physical and chemical properties (Partition coefficient (n-octanol/water)) Information on basic physical and chemical properties (Odour threshold) Hazardous decomposition products Reactivity Incompatible materials Toxicological Information. - Acute toxicity. - Respiratory or skin sensitisation. - Germ cell mutagenicity. - Carcinogenicity. - Reproductive toxicity. - Serious eye damage/irritation. - STOT-single exposure. - STOT-repeated exposure. - Aspiration hazard Toxicity Persistence and degradability Bioaccumulative potential Results of PBT and vpvb assessment Other adverse effects. 3 - Further information. 4 - IMDG Chemical safety assessment. 5 - Regulations. R35 - Causes severe burns. Copyright 205 ChemSoft Limited. All rights reserved.

8 8/8 date Other information Text of Hazard Statements in Section 3 Further information Skin Corr. A: H34 - Causes severe skin burns and eye damage. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process. Copyright 205 ChemSoft Limited. All rights reserved.