Safety Data Sheet Basazol Yellow 46 L na Revision date : 2016/03/29 Page: 1/10

Transcription

1 Revision date : 2016/03/29 Page: 1/10 1. Identification Product identifier used on the label Basazol Yellow 46 L na Recommended use of the chemical and restriction on use Recommended use*: Colorants for the paper industry * The Recommended use identified for this product is provided solely to comply with a Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF Canada Inc. 100 Milverton Drive Mississauga, ON L5R 4H1, CANADA Telephone: Emergency telephone number CANUTEC (reverse charges): (613) BASF HOTLINE: (800) 454-COPE (2673) Other means of identification Chemical family: methine dye 2. Hazards Identification According to Hazardous Products Regulations (HPR) (SOR/ ) Classification of the product Met. Corr. 1 Corrosive to metals Skin Corr./Irrit. 1A Skin corrosion/irritation Eye Dam./Irrit. 1 Serious eye damage/eye irritation Aquatic Acute 3 Hazardous to the aquatic environment - acute Aquatic Chronic 3 Hazardous to the aquatic environment - chronic Label elements Pictogram:

2 Revision date : 2016/03/29 Page: 2/10 Signal Word: Danger Hazard Statement: H290 H314 H402 H412 May be corrosive to metals. Causes severe skin burns and eye damage. Harmful to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary Statements (Prevention): P280 Wear protective gloves/protective clothing/eye protection/face protection. P273 Avoid release to the environment. P260 Do not breathe dust or mist. P264 Wash with plenty of water and soap thoroughly after handling. P234 Keep only in original container. Precautionary Statements (Response): P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P390 Absorb spillage to prevent material damage. Precautionary Statements (Storage): P405 Store locked up. P406 Store in corrosive resistant/ container with a resistant inner liner. Precautionary Statements (Disposal): P501 Dispose of contents/container to hazardous or special waste collection point. Hazards not otherwise classified If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. 3. Composition / Information on Ingredients According to Hazardous Products Regulations (HPR) (SOR/ ) CAS Number Weight % Chemical name Trade Secret >= < 75.0% Basic yellow dye >= < 50.0% Acetic acid

3 Revision date : 2016/03/29 Page: 3/10 4. First-Aid Measures Description of first aid measures General advice: Immediately remove contaminated clothing. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). First aid personnel should pay attention to their own safety. If inhaled: If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention. If on skin: Remove contaminated clothing. Rinse skin immediately with plenty of water for minutes. Seek medical attention. Consult a skin specialist. If in eyes: Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. If swallowed: Immediately rinse mouth and then drink plenty of water, do not induce vomiting, seek medical attention. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11. Further important symptoms and effects are so far not known. Hazards: Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire-Fighting Measures Extinguishing media Suitable extinguishing media: water spray, dry powder, foam Special hazards arising from the substance or mixture Hazards during fire-fighting: harmful vapours Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of fire. Advice for fire-fighters

4 Revision date : 2016/03/29 Page: 4/10 Protective equipment for fire-fighting: Wear a self-contained breathing apparatus in confined areas or when exposed to combustion products. Further information: Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Avoid contact with the skin, eyes and clothing. Use personal protective clothing. Environmental precautions Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater. Methods and material for containment and cleaning up For small amounts: Pick up with absorbent material (e.g. sand, sawdust, general-purpose binder). Dispose of absorbed material in accordance with regulations. For large amounts: Pump off product. Spills should be contained, solidified, and placed in suitable containers for disposal. 7. Handling and Storage Precautions for safe handling Avoid contact with the skin, eyes and clothing. No special measures necessary if stored and handled correctly. Protection against fire and explosion: No explosion proofing necessary. Conditions for safe storage, including any incompatibilities Segregate from foods and animal feeds. Suitable materials for containers: High density polyethylene (HDPE) Further information on storage conditions: Store protected against freezing. 8. Exposure Controls/Personal Protection Components with occupational exposure limits Acetic acid OSHA PEL PEL 10 ppm 25 mg/m3 ; TWA value 10 ppm 25 mg/m3 ; ACGIH TLV STEL value 15 ppm ; TWA value 10 ppm ; Advice on system design: Provide local exhaust ventilation to maintain recommended P.E.L.

5 Revision date : 2016/03/29 Page: 5/10 Personal protective equipment Respiratory protection: Wear respiratory protection if ventilation is inadequate. Respiratory protection in case of vapour/aerosol release. Wear a NIOSH-certified (or equivalent) organic vapour/particulate respirator. Hand protection: Wear chemical resistant protective gloves. Eye protection: Tightly fitting safety goggles (chemical goggles) and face shield. Body protection: Body protection must be chosen based on level of activity and exposure. General safety and hygiene measures: Eye wash fountains and safety showers must be easily accessible. Wear protective clothing as necessary to prevent contact. Avoid inhalation of vapours/mists. Wash soiled clothing immediately. 9. Physical and Chemical Properties Form: liquid Odour: moderate odour, of acetic acid Odour threshold: Colour: yellow ph value: approx. 2 Freezing point: approx. < -10 C ( 1 ATM) Information on: Acetic acid Boiling point: C ( 1,013 hpa) Literature data Sublimation point: Flash point: > 100 C No flash point - Measurement made up to the indicated temperature, pilot light extinguishes. Flammability: not flammable Lower explosion limit: Upper explosion limit: Autoignition: approx. > 430 C Vapour pressure: Information on: Acetic acid Vapour pressure: Density: Relative density: Vapour density: Partitioning coefficient n- octanol/water (log Pow): Self-ignition temperature: Thermal decomposition: 20.9 hpa ( 25 C) Literature data g/cm3 ( 20 C) not self-igniting (other) (ASTM D93) (measured) No decomposition if correctly stored and handled.

6 Revision date : 2016/03/29 Page: 6/10 Viscosity, dynamic: Viscosity, kinematic: Solubility in water: Miscibility with water: Solubility (quantitative): Solubility (qualitative): Evaporation rate: Other Information: 10. Stability and Reactivity Pa.s ( 20 C) miscible miscible If necessary, information on other physical and chemical parameters is indicated in this section. Reactivity No hazardous reactions if stored and handled as prescribed/indicated. Corrosion to metals: Corrosive effect on metals. Oxidizing properties: Not an oxidizer. Chemical stability The product is chemically stable. Possibility of hazardous reactions No hazardous reactions when stored and handled according to instructions. The product is chemically stable. Conditions to avoid Avoid freezing. Avoid extreme heat. Incompatible materials No substances known that should be avoided. Hazardous decomposition products Decomposition products: Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated. Thermal decomposition: No decomposition if correctly stored and handled. 11. Toxicological information Primary routes of exposure Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity/Effects Acute toxicity Assessment of acute toxicity: Of low toxicity after single ingestion.

7 Revision date : 2016/03/29 Page: 7/10 Oral Type of value: LD50 Species: rat (male/female) Value: approx. 2,700 mg/kg (BASF-Test) Inhalation Dermal Assessment other acute effects Irritation / corrosion Assessment of irritating effects: Corrosive! Damages skin and eyes. Skin Species: rabbit Result: Corrosive. Method: OECD Guideline 404 Eye Species: rabbit Result: Risk of serious damage to eyes. Method: OECD Guideline 405 Sensitization Assessment of sensitization: A sensitizing effect on particularly sensitive individuals cannot be excluded. Based on available Data, the classification criteria are not met. Chronic Toxicity/Effects Repeated dose toxicity Assessment of repeated dose toxicity: The substance may cause damage to the liver after repeated ingestion of high doses, as shown in animal studies. Genetic toxicity Assessment of mutagenicity: Based on available Data, the classification criteria are not met. Carcinogenicity Assessment of carcinogenicity: Based on available Data, the classification criteria are not met. Reproductive toxicity Assessment of reproduction toxicity: Based on available Data, the classification criteria are not met. Teratogenicity Assessment of teratogenicity: Based on available Data, the classification criteria are not met. Other Information The product has been assessed on the basis of the components available data. To some extent data gaps exist for individual components. Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11.

8 Revision date : 2016/03/29 Page: 8/10 Further important symptoms and effects are so far not known. 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Toxicity to fish LC50 (96 h) mg/l, Leuciscus idus (static) Slightly toxic. Microorganisms/Effect on activated sludge Toxicity to microorganisms EC50: mg/l Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low concentrations. Persistence and degradability Assessment biodegradation and elimination (H2O) Poorly biodegradable. Colourants are by their nature very stable and are therefore not readily biodegradable under conditions prevailing in surface water or in effluent treatment plants. Elimination information Information on: Acetic acid 96 % DOC reduction (20 d) (Static test) (aerobic, domestic sewage) 40.2 % BOD of the ThOD (24 h) (aerobic, activated sludge, domestic) Mobility in soil Assessment transport between environmental compartments The substance will not evaporate into the atmosphere from the water surface. Adsorption to solid soil phase is expected. Additional information Other ecotoxicological advice: Do not discharge substance/product into sewer system. Do not allow to enter soil, waterways or waste water channels. The product has not been tested. 13. Disposal considerations Waste disposal of substance: Must be disposed of or incinerated in accordance with local regulations. Container disposal: Dispose of in a licensed facility. Recommend crushing, puncturing or other means to prevent unauthorized use of used containers.

9 Revision date : 2016/03/29 Page: 9/ Transport Information Land transport TDG Hazard class: 8 Packing group: III ID number: UN 2801 Hazard label: 8 Proper shipping name: DYE, LIQUID, CORROSIVE, N.O.S. (contains ACETIC ACID, C.I.BASIC YELLOW 96) Sea transport IMDG Hazard class: 8 Packing group: III ID number: UN 2801 Hazard label: 8 Marine pollutant: NO Proper shipping name: DYE, LIQUID, CORROSIVE, N.O.S. (contains ACETIC ACID, C.I.BASIC YELLOW 96) Air transport IATA/ICAO Hazard class: 8 Packing group: III ID number: UN 2801 Hazard label: 8 Proper shipping name: DYE, LIQUID, CORROSIVE, N.O.S. (contains ACETIC ACID, C.I.BASIC YELLOW 96) 15. Regulatory Information Federal Regulations Registration status: Chemical DSL, CA released / listed 16. Other Information SDS Prepared by: BASF NA Product Regulations SDS Prepared on: 2016/03/29 We support worldwide Responsible Care initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring

10 Revision date : 2016/03/29 Page: 10/10 the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. Basazol Yellow 46 L na is a registered trademark of BASF Canada or BASF SE END OF DATA SHEET