SAFETY DATA SHEET HYDROGEN PEROXIDE 35%

Transcription

1 SAFETY DATA SHEET SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name CAS number EU index number EC number Relevant identified uses of the substance or mixture and uses advised against Identified uses Oxygen Bleaching Agent 1.3. Details of the supplier of the safety data sheet Supplier IDEAL MANUFACTURING LTD. ATLAS HOUSE, BURTON ROAD FINEDON, WELLINGBOROUGH NORTHANTS. NN9 5HX , 24hr Emergency number Emergency telephone number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification Physical hazards Not Classified Health hazards Acute Tox. 4 - H302 Acute Tox. 4 - H332 Skin Corr. 1A - H314 Eye Dam. 1 - H318 Environmental hazards Not Classified Classification (67/548/EEC or 1999/45/EC) Xn;R22. Xi;R37/38,R Label elements EC number Pictogram Signal word Hazard statements Danger 1/7

2 H302+H332 Harmful if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. Precautionary statements P260 Do not breathe vapour/spray. P261 Avoid breathing vapour/spray. P264 Wash contaminated skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312 Call a POISON CENTER/doctor if you feel unwell. P321 Specific treatment (see medical advice on this label). P363 Wash contaminated clothing before reuse. P405 Store locked up. P501 Dispose of contents/container in accordance with national regulations. Contains HYDROGEN PEROXIDE SOLUTION... % 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.2. Mixtures HYDROGEN PEROXIDE SOLUTION... % 30-60% CAS number: EC number: Classification Ox. Liq. 1 - H271 Acute Tox. 3 - H301 Acute Tox. 4 - H332 Skin Corr. 1A - H314 Eye Dam. 1 - H318 Classification (67/548/EEC or 1999/45/EC) Xn;R20/22. C;R35. Xi;R37. O;R5,R8. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Move affected person to fresh air and keep warm and at rest in a position comfortable for breathing. If breathing stops, provide artificial respiration. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Get medical attention. Ingestion DO NOT induce vomiting. Get medical attention immediately. Never give anything by mouth to an unconscious person. Skin contact Rinse immediately with plenty of water. Remove contaminated clothing. Get medical attention if irritation persists after washing. Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide apart. Continue to rinse for at least 15 minutes. Get medical attention immediately. Continue to rinse. 2/7

3 4.2. Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependent on the concentration and the length of exposure. Inhalation Unlikely to occur Ingestion Burns can occur. Skin contact The product is irritating to eyes and skin. Eye contact The product is irritating to eyes and skin Indication of any immediate medical attention and special treatment needed Notes for the doctor If in doubt, get medical attention promptly. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray, foam, dry powder or carbon dioxide Special hazards arising from the substance or mixture Specific hazards Fire creates: Oxygen Advice for firefighters Protective actions during firefighting For large fires, flood area with water. Special protective equipment for firefighters Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots, clothing or apron, as appropriate. Use suitable respiratory protection if ventilation is inadequate Environmental precautions Environmental precautions Do not discharge into drains or watercourses or onto the ground Methods and material for containment and cleaning up Methods for cleaning up Wear suitable protective equipment, including gloves, goggles/face shield, respirator, boots, clothing or apron, as appropriate. Avoid the spillage or runoff entering drains, sewers or watercourses. Flush contaminated area with plenty of water Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Usage precautions Keep away from heat, sparks and open flame Conditions for safe storage, including any incompatibilities 3/7

4 Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place. Keep separate from food, feedstuffs, fertilisers and other sensitive material Specific end use(s) SECTION 8: Exposure Controls/personal protection 8.1. Control parameters Occupational exposure limits Long-term exposure limit (8-hour TWA): WEL 1 ppm 1.4 mg/m3 Short-term exposure limit (15-minute): WEL 2 ppm 2.8 mg/m3 HYDROGEN PEROXIDE SOLUTION... % Long-term exposure limit (8-hour TWA): WEL 1 ppm 1.4 mg/m3 Short-term exposure limit (15-minute): WEL 2 ppm 2.8 mg/m3 WEL = Workplace Exposure Limit 8.2. Exposure controls Protective equipment Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates eye contact is possible. The following protection should be worn: Dust-resistant, chemical splash goggles. Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if a risk assessment indicates skin contact is possible. Other skin and body protection Wear suitable protective clothing as protection against splashing or contamination. Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Appearance Colourless liquid. Odour No characteristic odour. ph ph (concentrated solution): Relative density 20 C 9.2. Other information Other information Not available. SECTION 10: Stability and reactivity Reactivity Chemical stability Stability 4/7

5 Stable at normal ambient temperatures and when used as recommended Possibility of hazardous reactions Conditions to avoid Avoid heat Incompatible materials Materials to avoid Strong reducing agents. Flammable/combustible materials. Metal oxides Hazardous decomposition products Vapours/gases/fumes of: Oxygen. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity - oral Acute toxicity oral (LD50 mg/kg) Species Rat ATE oral (mg/kg) Acute toxicity - dermal Acute toxicity dermal (LD50 mg/kg) 6500 Acute toxicity - inhalation Acute toxicity inhalation (LC50 vapours mg/l) 0.17 ATE inhalation (dusts/mists mg/l) Skin contact Liquid may irritate skin. Eye contact May cause severe eye irritation. SECTION 12: Ecological Information Ecotoxicity Not regarded as dangerous for the environment Toxicity Acute toxicity - fish LC₅₀, 96 hours: mg/l, Fish Acute toxicity - aquatic invertebrates EC₅₀, 48 hours: 2.4 mg/l, Daphnia magna Acute toxicity - aquatic plants IC₅₀, 72 hours: 2.5 mg/l, Algae Persistence and degradability Bioaccumulative potential Not expected to bioaccumulate Mobility in soil 5/7

6 12.5. Results of PBT and vpvb assessment Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the local Waste Disposal Authority. SECTION 14: Transport information UN number UN No. (ADR/RID) 2014 UN No. (IMDG) 2014 UN No. (ICAO) UN proper shipping name Proper shipping name (ADR/RID) Proper shipping name (IMDG) Proper shipping name (ICAO) Proper shipping name (ADN) Transport hazard class(es) ADR/RID class 5.1 IMDG class 5.1 ICAO class/division 5.1 ICAO subsidiary risk 8 Transport labels Packing group ADR/RID packing group IMDG packing group ICAO packing group II II I Environmental hazards Special precautions for user EmS F-H, S-Q Emergency Action Code 58 Tunnel restriction code (E) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical safety assessment SECTION 16: Other information 6/7

7 General information This information is given in good faith and is based upon current available data. The suitability of this product for any particular use is not suggested. The user must determine if the product is correct for any particular application. This document is not a specification. Conforms to 1907/2006/EC Revision date 12/02/2015 Revision 01 SDS number 116 Risk phrases in full Hazard statements in full R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes. H271 May cause fire or explosion; strong oxidiser. H301 Toxic if swallowed. H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H318 Causes serious eye damage. H332 Harmful if inhaled. H335 May cause respiratory irritation. 7/7