Date of issue: 02/10/2016 Supersedes: 05/01/2015 SECTION 1: Identification 1.1. Identification Product form : Mixture Product name : Ladlelock 90 PB All Summer Grades CAS No : Mixture Product code : 3091, 3092, 3292, 3778 Other means of identification : Alumina-Silicate Wet Chemically Bonded Mortar-Slurry 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Refractory 1.3. Details of the supplier of the safety data sheet Resco Products, Inc. One Robinson Plaza, Suite 300 6600 Steubenville Pike Pittsburgh, PA 15205 - United States 412-494-4491 WWW.RescoProducts.com 1.4. Emergency telephone number Emergency number : EMERGENCY ONLY (CHEMTREC) USA & Canada 1-800-424-9300 Outside USA & Canada +1 703-741-5970 SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Skin Irrit. 2 H315 - Causes skin irritation Eye Irrit. 2B H320 - Causes eye irritation Carc. 1A H350 - May cause cancer (After drying or heating, Inhalation) Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS08 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) SECTION 3: Composition/Information on ingredients 3.1. Substance 3.2. Mixture GHS07 : Danger : H315 - Causes skin irritation H319 - Causes serious eye irritation H350 - May cause cancer (After drying or heating, Inhalation) : P202 - Do not handle until all safety precautions have been read and understood P280 - Wear eye protection, protective gloves, protective clothing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention Name Product identifier % GHS-US classification aluminium oxide, non-fibrous (CAS No) 1344-28-1 50-75 Not classified phosphoric acid, conc=75%, aqueous solution (CAS No) 7664-38-2 5-10 Not classified quartz (CAS No) 14808-60-7 1-5 Carc. 1A, H350 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Gently wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 02/10/2016 EN (English US) Page 1
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : After drying or heating. May cause cancer by inhalation. Danger of serious damage to health by prolonged exposure through inhalation. Symptoms/injuries after skin contact Symptoms/injuries after eye contact : Causes serious eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Use extinguishing media appropriate for surrounding fire. : No unsuitable extinguishing media known. 5.2. Special hazards arising from the substance or mixture Fire hazard : Not flammable. Reactivity : Air Setting. 5.3. Advice for firefighters Firefighting instructions : Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : If spilled, may cause the floor to be slippery. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Stop release. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Plug the leak, cut off the supply. Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. 7.1. Precautions for safe handling Precautions for safe handling : Avoid contact with eyes. Avoid contact with skin. Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in original container. Keep container closed when not in use. Incompatible products : Strong bases. Avoid contact with materials: such as sulfides and sulfites which could release toxic gases, mixing with strong bases because high heat of reaction can generate steam, and metals which could liberate hydrogen, a flammable gas. SECTION 8: Exposure controls/personal protection 8.1. Control parameters ACGIH ACGIH TWA (mg/m³) 0.025 mg/m³ OSHA OSHA PEL (TWA) (mg/m³) 0.1 mg/m³ ACGIH ACGIH TWA (mg/m³) 1 mg/m³ (Aluminium, insoluble compounds; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value; Respirable fraction) 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : After air drying or heating. Dust when sawing or tear out. Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance Color Odor : Slurry. : white : Acid Odor 02/10/2016 EN (English US) 2/5
Odor threshold ph : Melting point : > 2500 F Freezing point : 32 F Boiling point Critical temperature Critical pressure Flash point Relative evaporation rate (butyl acetate=1) Relative evaporation rate (ether=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure : : : : : : : None : : Vapor pressure at 50 C : Relative density : 2.4 Relative vapor density at 20 C Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic : 9.2. SECTION 10: Stability and reactivity 10.1. Reactivity Air Setting. 10.2. Chemical stability 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid 10.5. Incompatible materials Strong bases. Avoid contact with materials: such as sulfides and sulfites which could release toxic gases, mixing with strong bases because high heat of reaction can generate steam, and metals which could liberate hydrogen, a flammable gas. 10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity LD50 oral rat LD50 oral rat ATE US (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) > 15900 mg/kg body weight (Rat; Equivalent or similar to OECD 401; Experimental value) 4400 mg/kg (Rat) 4400.000 mg/kg body weight : Causes eye irritation. : May cause cancer (After drying or heating, Inhalation). 1 - Carcinogenic to humans 02/10/2016 EN (English US) 3/5
Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact SECTION 12: Ecological information 12.1. Toxicity LC50 fish 1 EC50 Daphnia 1 Threshold limit algae 1 LC50 fish 1 138 mg/l (LC50) 12.2. : Based on available data, the classification criteria are not met. : After drying or heating. May cause cancer by inhalation. Danger of serious damage to health by prolonged exposure through inhalation. : Causes serious eye irritation. > 100 mg/l (NOEC; OECD 203: Fish, Acute Toxicity Test; 96 h; Salmo trutta; Flow-through system; Fresh water; Experimental value) > 100 mg/l (NOEC; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna) > 100 mg/l (NOEC; OECD 201: Alga, Growth Inhibition Test; 72 h; Selenastrum capricornutum) Biodegradability: not applicable. Biodegradability: not applicable. No (test) data on mobility of the substance available. 12.3. Biodegradability: not applicable. No (test) data on mobility of the components available. No bioaccumulation data available. Log Pow -0.77 (Estimated value) 12.4. Mobility in soil 12.5. Other adverse effects Effect on the global warming Bioaccumulation: not applicable. : No known ecological damage caused by this product. None known : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated for transport 02/10/2016 EN (English US) 4/6
TDG Transport by sea Air transport SECTION 15: Regulatory information 15.1. US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA WHMIS Classification EU-Regulations National regulations D2A Listed on IARC (International Agency for Research on Cancer) 15.3. US State regulations Other information Carcinogens List Developmental Toxicity This product contains crystalline silica, a chemical known to the state of California to cause cancer. Reproductive Toxicity - Female Yes No No No U.S. - New Jersey - Right to Know Hazardous Substance List Reproductive Toxicity - Male Non-significant risk level (NSRL) SECTION 16: : None. Full text of H-phrases: ------ Carc. 1A Carcinogenicity Category 1A ------ Eye Irrit. 2B Serious eye damage/eye irritation Category 2B ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ H315 Causes skin irritation ------ H320 Causes eye irritation ------ H350 May cause cancer SDS US (GHS HazCom 2012) This information and recommendations set forth herein are taken from sources believed to be accurate as of the date herein, however, Resco Products, Inc. makes no warranty with respect to the accuracy of the information or the suitability of the recommendations, and assumes no liability to any user thereof. 02/10/2016 EN (English US) 5/5