Material Safety Data Sheet Revision Number: 001.0 Issue date: 08/29/2011 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Product type: Company address: Henkel Corporation One Henkel Way Rocky Hill, Connecticut 06067 DURO Aluminum Jelly Cleaner & Brightener Rust dissolver Region: United States Contact information: Telephone: 860.571.5100 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkelna.com 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Liquid HEALTH: *3 Color: blue FLAMMABILITY: 1 Odor: Grape PHYSICAL HAZARD: 0 Personal Protection: See MSDS Section 8 DANGER: MAY CAUSE RESPIRATORY TRACT IRRITATION. CAUSES EYE AND SKIN BURNS. MAY BE HARMFUL IF SWALLOWED. MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS. Relevant routes of exposure: Ingestion, Eye contact, Skin, Lungs Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: May cause respiratory tract irritation. Prolonged inhalation of large concentrations can be irritating to lungs, and mucous membranes of nose and throat. Causes skin burns. May cause skin irritation. Redness. Tearing. Redness. May cause irritation. Causes eye burns. Stinging. May cause central nervous system effects, such as headache, nausea, vomiting, abdominal pain, dizziness, confusion, and breathing difficulties. May be harmful if swallowed. Kidney disease. Respiratory disorders. Liver disease. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % 7664-38-2 10-30 Diethyleneglycol monoethyl ether 111-90-0 1-5 Alkylphenol ethoxylate C9 9.5EO 9016-45-9 1-5 2-Propanol 67-63-0 1-5 Page 1 of 1
4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Get medical attention. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Move to fresh air. Immediately flush skin with plenty of water (using soap, if available). If symptoms develop and persist, get medical attention. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Get immediate medical attention. Never give anything by mouth to an unconscious person. DO NOT induce vomiting unless directed to do so by medical personnel. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Not determinable. Foam, dry chemical or carbon dioxide. Not flammable, however Hydrogen gas may be liberated if product contacts powdered metals or metals above 185 F. known 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Ensure adequate ventilation. Neutralize acid using lime or a lime based agent compatible with the product. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Flush with water. Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Handling: Storage: Wash thoroughly after handling. Do not get in eyes. Do not get on skin or clothing. Do not taste or swallow. Avoid breathing vapors or mists of this product. Keep container closed. Use only with adequate ventilation. Keep from freezing. Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Page 2 of 2
Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER 1 mg/m3 TWA 3 mg/m3 STEL 1 mg/m3 TWA Diethyleneglycol monoethyl ether 25 ppm (140 mg/m3) TWA Alkylphenol ethoxylate C9 9.5EO 2-Propanol 200 ppm TWA 400 ppm (980 400 ppm STEL mg/m3) TWA Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Safety goggles or safety glasses with side shields. Chemical resistant, impermeable gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: blue Odor: Grape Odor threshold: ph: 1.5-2.5 Vapor pressure: Boiling point/range: 212 F (100 C) Approximately Melting point/ range: Specific gravity: 1.05 Vapor density: Flash point: Not determinable. Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Soluble Partition coefficient (n-octanol/water): VOC content: 2.23 %; 23.73 g/l 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable Will not occur. Hydrogen, by reaction with metals. Sulfites. Ethylene oxide. Reactive isocyanates. Chlorine. Strong bases. Sulfides. Reducing agents. Strong oxidizing agents. Extremes of temperature and direct sunlight. Store away from incompatible materials. 11. TOXICOLOGICAL INFORMATION Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) No No No Diethyleneglycol monoethyl ether No No No Alkylphenol ethoxylate C9 9.5EO No No No 2-Propanol No No No Page 3 of 3
Hazardous components Diethyleneglycol monoethyl ether Alkylphenol ethoxylate C9 9.5EO 2-Propanol Health Effects/Target Organs Irritant, Corrosive Blood, Central nervous system, Irritant, Kidney Irritant, Allergen Allergen, Blood, Brain, Central nervous system, Irritant, Kidney, Liver, Spleen 12. ECOLOGICAL INFORMATION Ecological information: 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. D002: Corrosive. 14. TRANSPORT INFORMATION U.S. Department of Transportation Ground (49 CFR) solution DOT Reportable quantity: Exceptions: ORM-D, Consumer Commodity, (Not more than 4 L) International Air Transportation (ICAO/IATA), solution Water Transportation (IMO/IMDG) PHOSPHORIC ACID SOLUTION United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. above reporting de minimus CERCLA/SARA Section 302 EHS: Sulfuric acid (CAS# 7664-93-9). Propylene oxide (CAS# 75-56-9). CERCLA/SARA Section 311/312: Delayed Health, Immediate Health CERCLA/SARA 313: This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Diethyleneglycol monoethyl ether (CAS# 111-90-0). California Proposition 65: This product contains a chemical known in the State of California to cause cancer. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. D.2.A, D.2.B, E Page 4 of 4
16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format. Prepared by: For Safety and Regulatory information contact: Regulatory Affairs Rocky Hill, CT 860-571-5204 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 5 of 5