SAFETY DATA SHEET according to 907/2006/EC, Article 3 Page /5 date SECTION : Identification of the substance/mixture and of the company/undertaking.. Product identifier Product name.3. Details of the supplier of the safety data sheet Company Address Granville Oil & Chemicals Ltd 29 Goldthorpe Industrial Estate Goldthorpe, Rotherham, S63 9BL ENGLAND Telephone +44 (0) 709 890099 Fax +44 (0) 709 892 SECTION 2: Hazards identification 2.. Classification of the substance or mixture 2... Classification - 999/45/ЕC Main hazards Xn; R65 R0-66 term adverse effects in the aquatic environment. Flammable. Harmful: may cause lung damage if swallowed. Repeated exposure may cause skin dryness or cracking. SECTION 3: Composition/information on ingredients 3.2. Mixtures 67/548/EEC / 999/45/EC Chemical Name Index No. CAS No. EINECS No. REACH Naphtha (Petroleum) Hydrotreated Heavy. Kerosine - unspecified - solvent naphtha (petroleum), heavy arom. Registration Number Conc. (%w/w) Classification 64742-48-9 265-50-3 80-90% Xn; R65 R66 649-424-00-3 64742-94-5 265-98-5-0% Xn; R65 Naphthalene (Naphtalene) 60-052-00-2 9-20-3 202-049-5 0-0.5% Carc. Cat. 3; R40 Xn; R22 N; R50/53 SECTION 4: First aid measures 4.. Description of first aid measures Inhalation Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. Move the exposed person to fresh air. Seek medical attention. In severe cases, may cause loss of consciousness. Eye contact May cause irritation to eyes. Rinse immediately with plenty of water for 5 minutes holding the eyelids open. Seek medical attention if irritation or symptoms persist. Contact lenses should be removed. Skin contact May cause irritation to skin. Wash off immediately with plenty of soap and water. Remove contaminated clothing. Seek medical attention if irritation or symptoms persist. Copyright 20 ChemSoft Limited. All rights reserved.
2/5 date 4.. Description of first aid measures Ingestion Ingestion may cause nausea and vomiting. Rinse mouth thoroughly. DO NOT INDUCE VOMITING. If swallowed, seek medical advice immediately and show this container or label. Danger of aspiration. In case of vomiting, keep head low so that the stomach content foes not reach the lungs. Immediate admittance to hospital. SECTION 5: Firefighting measures 5.. Extinguishing media Alcohol resistant foam. Carbon dioxide (CO2). Water spray. Dry chemical. Cool fire exposed containers with waterspray. Do NOT use water jet. 5.2. Special hazards arising from the substance or mixture. Burning produces irritating, toxic and obnoxious fumes. oxides of nitrogen; oxides of carbon; hydrocarbons; toxic pyrolysis products. explosive vapour/air mixture. dangerous vapours heavier than air. in case of spreading near the ground, flashback to distant sources of ignition is possible. may be formed in fire conditions. 5.3. Advice for firefighters Wear suitable respiratory equipment when necessary. In case of fire and/or explosion do not breathe fumes. Protective equipment. SECTION 6: Accidental release measures 6.. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation of the working area. Evacuate personnel to a safe area. Eliminate all sources of ignition. Wear suitable protective equipment. When using do not smoke. 6.2. Environmental precautions Do not allow product to enter drains. Prevent further spillage if safe. Do not flush into surface water. 6.3. Methods and material for containment and cleaning up Absorb with inert, absorbent material. Transfer to suitable, labelled containers for disposal. Clean spillage area thoroughly with plenty of water. SECTION 7: Handling and storage 7.. Precautions for safe handling Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Use explosion proof equipment. Keep away from sources of ignition - No smoking. 7.2. Conditions for safe storage, including any incompatibilities Keep in a cool, dry, well ventilated area. Keep containers tightly closed. Store in correctly labelled containers. SECTION 8: Exposure controls/personal protection 8.. Control parameters 8... Exposure Limit Values Naphthalene DIR: 9/322 8hTWA ppm: 0 8hTWA mg/m3: 50 STEL ppm: - STEL mg/m3: - NOT: - 8.2. Exposure controls 8.2.. Appropriate engineering controls Ensure adequate ventilation of the working area. 8.2.2. Individual protection measures Wear chemical protective clothing. Eye / face protection Approved safety goggles. Copyright 20 ChemSoft Limited. All rights reserved.
3/5 date 8.2. Exposure controls Skin protection - Handprotection Respiratory protection Chemical resistant gloves (PVC). Wear suitable respiratory equipment when necessary. SECTION 9: Physical and chemical properties 9.. Information on basic physical and chemical properties State Colour Odour Liquid Colourless Characteristic Flash point ~ 40 SECTION 0: Stability and reactivity 0.2. Chemical stability Stable under normal conditions. 0.3. Possibility of hazardous reactions Oxidising agents. 0.4. Conditions to avoid Heat, sparks and open flames. SECTION : Toxicological information.. Information on toxicological effects Respiratory or skin sensitisation Carcinogenicity Reproductive toxicity Repeated or prolonged exposure Irritant, defatting, skin. May cause dermatitis. Potential for aspiration if swallowed. Harmful: may cause lung damage if swallowed. SECTION 2: Ecological information 2.2. Persistence and degradability Readily biodegradable. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 2.3. Bioaccumulative potential Concentrations in organisms possible. 2.4. Mobility in soil Not available. SECTION 3: Disposal considerations General information Dispose of in compliance with all local and national regulations. Can be incinerated if in compliance with local and national regulations - do not dispose of with domestic waste. SECTION 4: Transport information Hazard pictograms Hazard pictograms 4.. UN number Copyright 20 ChemSoft Limited. All rights reserved.
4/5 date 4.. UN number UN3295 4.2. UN proper shipping name Proper Shipping Name HYDROCARBONS, LIQUID, N.O.S. 4.3. Transport hazard class(es) ADR/RID 3 IMDG 3 Subsidiary risk - IATA 3 Subsidiary risk - 4.4. Packing group Packing group III 4.5. Environmental hazards Environmental hazards Marine pollutant No No ADR/RID Hazard ID 30 Tunnel Category D/E IMDG EmS Code F-E S-D IATA Packing Instruction (Cargo) 30 Maximum quantity Packing Instruction (Passenger) Maximum quantity 220 L 309 60 L SECTION 5: Regulatory information Labelling Symbols The product is classified in accordance with 67/548/EEC. Xn: Harmful. Risk phrases Safety phrases R0 - Flammable. R65 - Harmful: may cause lung damage if swallowed. R66 - Repeated exposure may cause skin dryness or cracking. S62 - If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. SECTION 6: Other information Other information This document differs from the previous version in the following areas:. 9-9.. information on basic physical and chemical properties. 9-9.2. other information. 4 - adr/rid. 4 - imdg. 4 - iata. Copyright 20 ChemSoft Limited. All rights reserved.
5/5 date Other information Text of risk phrases in Section 3 R0 - Flammable R22 - Harmful if swallowed. R40 - Limited evidence of a carcinogenic effect. R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 - Harmful: may cause lung damage if swallowed. R66 - Repeated exposure may cause skin dryness or cracking. Further information The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication however no guarantee is made to its accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process. Copyright 20 ChemSoft Limited. All rights reserved.