Page 1 of 8 Product Name: HM 4100 (84% Active Condensed 3-(trihydroxysilyl) propyldimethyl octadecyl ammonium chloride) MSDS Number: 4141 Revision Number: 7 Version Date: 06/04/2010 Section 1: Chemical Product and Company Identification. Telephone: 412-770-1302 100 Technology Drive FAX: 412-770-1638 Suite 400 Pittsburgh, PA 15219 Product Name: BIOSAFE Antimicrobial HM 4100 Generic Description: Organosilane Physical Form: Solid Color: White to pale yellow Odor: Slight amine odor NFPA Profile: Health 0 Flammability 1 Reactivity 0 NFPA = National Fire Protection Association Section 2: OSHA Hazardous Components CAS Number Wt % Component Exposure Limits 199111-50-7 82-86.5% Condensed Octadecyl aminodimethyltrihydroxysilyl propyl ammonium Chloride None Established 14.5-18% Inerts, Water
Section 3: Effects of Overexposure Page 2 of 8 Acute Effects Eye: Mildly irritating. Toxicity category III Skin: Not considered a sensitizer. Stimulation index <.3 Inhalation: Oral: Not considered a hazard category IV Not considered a hazard category IV Prolonged/Repeated Exposure Effects Skin: Inhalation: None known None known Signs and Symptoms of Overexposure No known applicable information Medical Conditions Aggravated by Exposure No known applicable information Section 4: First Aid Measures Eye: Skin: Inhalation: Oral: Immediately flush with water for 15 minutes. Get medical attention. Not considered a hazard. Wash with soap and water. Not considered a hazard. Remove to fresh air. Get medical attention if ill effects persist. Not considered a hazard. Get medical attention if ill effects persist.
Page 3 of 8 Section 5: Fire Fighting Measures Flash Point (closed cup): Auto ignition Temperature: Extinguishing Media: Fire Fighting Procedures: Above 200 O F Not Determined Water spray. Carbon Dioxide (CO2). Dry Chemical. Foam. Self-contained breathing apparatus and protective clothing should be used in fighting large fires involving chemicals. Evacuate area in case of overheating or fire. Use water spray to keep fire exposed containers cool. Hazardous Decomposition Products: Thermal breakdown of this product during fire or very high heat conditions may evolve hazardous decomposition products: Carbon oxides and traces of incompletely burned carbon compounds; Nitrogen oxides; Chlorine compounds; Silicon dioxide;. Section 6: Accidental Release Measures Containment/Cleanup: Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements. Dispose of saturated absorbent or cleaning materials appropriately, since spontaneous heating may occur. Determine whether to evacuate or isolate the area according to your local emergency plan. Clean up remaining materials from spill with suitable absorbent. Clean area as appropriate since some silicone materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents, or detergents. For large spills, provide dike or other appropriate containment to keep material from spreading. Store recovered material in appropriate container. Observe all personal protection equipment recommendations described in Sections 5 and 8. Local, state, and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state, and local laws and regulations are applicable. NOTE: See Section 8 for Personal Protective Equipment for Spills. Call. 1 412-770-1302 if additional information is needed.
Section 7: Handling and Storage Page 4 of 8 Use with adequate ventilation. Keep container closed. Do not get into eyes. Do not take internally. Avoid skin contact. Keep container closed and away from heat. Section 8: Exposure Controls/ Personal Protection Engineering Controls Local exhaust: Not required but recommended General ventilation: Recommended Personal Protective Equipment for Routine Handling Eyes: Skin: Suitable Gloves: Inhalation: Use safety glasses or goggles when handling Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed and thoroughly cleaned before reuse. Chemical protective gloves are recommended. Any protective glove is suitable. Not considered an inhalation hazard. However, a fabric face mask is recommended. Personal Protective Equipment for Spills Eyes: Skin: Use safety glasses or goggles when handling. Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed and thoroughly cleaned before reuse. Chemical protective gloves are recommended. Inhalation/Suitable Respirator: Precautionary Measures: Not considered a hazard. However, a fabric face mask is recommended. Do not get in eyes. Avoid skin contact. Do not breathe dust. Keep container closed. Do not take internally. Note: These precautions are for room temperature handling. Use at elevated temperature, or aerosol/spray applications may require added precautions.
Page 5 of 8 Section 9: Physical and Chemical Properties. Physical Form: Color: Odor: Melting point: solid white to pale yellow slight amine order no defined melt point, turns brown above 320 0 F Solubility in Water: <6.00 % ph: Volatile content: Not Applicable 5-15% (water) Note: The above information is not intended for use in preparing product specifications. Contact BIOSAFE before writing specifications. Section 10: Stability and Reactivity Chemical Stability: Hazardous Polymerization: Conditions to Avoid: Materials to Avoid: Stable Hazardous polymerization will not occur None None Section 11: Toxicological Information Acute Toxicology Data for Product Acute dermal irritation in rats: Acute dermal toxicity in rabbits: Acute eye irritation in rabbits: Acute inhalation toxicity in rats: Primary irritation index 0.3 Toxicity category IV LD 50 > 5050 mg/kg Mildly irritating, toxicity category III LC 50 > 2.19 mg/l Acute oral toxicity in rats: LD 50 > 5000 mg/kg
Page 6 of 8 Section 11 Continued Component Toxicological Information None known Special Hazard information on components Mutagens: None known Section 12: Ecological Information Environmental Fate and Distribution: Ecotoxicity: Persistence and Degradation: No specific information is available No specific information is available No specific information is available Section 13: Disposal Considerations RCRA Hazard Class (40 CFR 261) DO NOT DUMP INTO SEWERS< ON THE GROUND< OR INTO ANY BODY OF WATER. All disposal practices must be in compliance with all Federal/State and local laws and regulations. Regulations may vary in different locations. Waste characterization and compliance with applicable laws are the responsibility solely of the waste generator. Pesticide wastes are toxic. Improper disposal of excess pesticide, spray mixture or rinsate is a violation of federal law. BIOSAFE has no control over the management practices or manufacturing processes of parties handling or using this material. The information presented here pertains only to the product as shipped. For unused and uncontaminated product, the preferred options include sending to a licensed, permitted incinerator or an approved chemical waste landfill. Characteristic Waste: Corrosive: N/A Reactive: N/A TCLP: N/A Comments: State or local laws may impose additional regulatory requirements regarding disposal N/A = Not Applicable Section 14: Transport Information Not regulated under US Department of Transportation
Page 7 of 8 Section 15: Regulatory Information Contents of this MSDS comply with the OSHA Hazard Communication Standard 29CFR 1910.1200 TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA Inventory of Chemical Substances. EPA SARA Title III Chemical Listings: Section 302 Extremely Hazardous Substances: None Section 312 Hazard Class: Acute: N Chronic: N Fire: N Pressure: N Reactive: N Y =Yes N = No Section 313 Toxic Chemicals: None Supplemental State Compliance Information: CAS Number Wt.% Component New Jersey 199111507 >84% Octadecylaminodimethyl trihydroxysilylpropyl ammonium chloride Pennsylvania 199111507 >84% Octadecylaminodimethyl trihydroxysilylpropyl ammonium chloride Section 16: Other Information HM 4100 is FIFRA regulated antimicrobial EPA Registration Number 83019-1 Prepared by. This information is offered in good faith as typical values and not as product specifications. No warranty, either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review these recommendations in the specific context of the intended use and determine whether they are appropriate.
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