MATERIAL SAFETY DATA SHEET HMIS SYSTEM HEALTH 2 FLAMMABILITY 3 REACTIVITY 0 PROTECTION B (PREPARED IN ACCORDANCE WITH 29 CFR 1910, 1200) SECTION I DIVISION ADDRESS: TRADE NAME: ULTRA-SHIELD 3000 GENERAL COATINGS MANUFACTURING CORP. "COMPONENT A" 1220 E. NORTH AVE. CHEMICAL NAME: POLYURETHANE FRESNO, CA 93725 1- CHEMICAL FAMILY: POLYURETHANE 24-HR EMERGENCY NO. CHEMTREC: (800) 424-9300 FORMULA: COMPLEX CMIXTURE CUSTOMER INFORMATION : (559) 495-4004 FAX NUMBER: (559) 495-4009 SECTION II -- HAZARDOUS INGREDIENTS COMPONENT 3-Isocyanatomethyl 1-3.5.5- Tmethyl-cyclohexyl-isocyanate Prepolymer resin ID NUMBERS EEC-Nr.615-008-005 Trade Secret HAZARD DATA TLV (FRG): 0.01 ppm = 0.09mg/m3S LD 50 Oral rat:5490 ng/ LD 50 inhi.rat:123mg/m3/4h not established Aliphatic Solvent Mixture Mixture ACGIH TLV(TWA) = 150ppm SECTION III -- PHYSICAL DATA Boiling Point ( F): 284 Specific Gravity (H 2 0=1) 1.06 Vapor Pressure (mm hg.): 3.8 Percent Volatile By Volume (%): 17 Vapor Density (AIR=1): 4.6 Evaporation Rate: 0.3 Solubility in Water: Negligible APPEARANCE AND ODOR: DARK AROMATIC
SECTION IV--FIRE AND EXPLOSION HAZARD DATA FLASH POINT : 79 F FLAMMABLE LIMITS: Lower = 1.0 Upper = 7.0 EXTINGUISHING MEDIA: Use water spray, dry chemical, alcohol type foam or carbon dioxide. SPECIAL FIRE FIGHTING PROCEDURES: UNUSUAL FIRE AND EXPLOSION HAZARDS: Do not enter fire area without proper protection. Wear a NIOSH/ MSHA - approved (or equivalent) self-contained breathing apparatus. During a fire, irritating or highly toxic gases (see reactivity data) are present from decomposition/combustion products. Heated containers may build up pressure and rupture violently. Cool containers with water spray. SECTION V--HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: EFFECTS OF OVEREXPOSURE: TLV = 0.01 ppm. See Section II. Inhalation: May cause irritation to respiratory tract (dry throat, cough, shortness of breath, chest tightness), Sinusitic, bronchitic or resiratory sensitation may occur. Skin irritation and sensitization. Once sensitized, individual may react to airborne levels below TLV with itching and tingling of earlobes, neck, hives, swelling of the arms, legs or other symptoms common to allergic dermatitus. These symptoms may be immediate or delayed. Any individual sensitized to this material should be removed from exposure to isocyanate. EMERGENCY AND FIRST AID PROCEDURES: INHALATION: Remove to fresh air. If not breathing, give artificial respiration. Get immediate medical attention. EYES: In case of contact with eyes, immediately flush eyes with water for 15 minutes. Call Physician. SECTION VI -- REACTIVITY DATA STABILITY: Unstable: Stable: X CONDITIONS TO AVOID: HAZARDOUS DECOMPOSITION : Keep away from heat, sparks and open flames. Avoid contact with water, strong bases, and strong oxidizers. PRODUCTS: Thermal combustion will generate CO, CO 2,, NO X, traces of HCN and other toxic fumes. HAZARDOUS POLYMERIZATION: May Occur: Will Not Occur : X SECTION VII--SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Evacuate non-essential personnel. Absorb in absorbant material. Dike to contain the spill. Collect the absorbant and spilled material in open head drums. Dispose of waste promptly. Provide sufficient ventilation. WASTE DISPOSAL METHOD: Dispose waste according to local state and federal environmental control regulations.
SECTION VIII--SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: VENTILATION: PROTECTIVE GLOVES: EYE PROTECTION: OTHER PROTECTIVE EQUIPMENT: Wear NIOSH/MSHA approved self-contained breathing apparatus. Local exhaust: required at the location of operation. Chemical resistant gloves. Goggles. Safety showers and eye wash stations should be available. Educate and train employees in the safe use of the product. Proper ventilation is extremely important due to the low TLV (See Section II). SECTION IX--SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN WHEN HANDLING AND STORING: This product is Hygroscopic and containers should be tightly closed to prevent contamination with foreign materials and moisture. Store at temperatures above 50 F and below 75 F (10-24 C). Avoid contact with skin and eyes. May cause eye irritation. Wash thoroughly after handling. Wear safety glasses when handling Do not expose containers to heat or direct sunlight. Open containers slowly to relieve possible excess pressure. This information is furnished without warranty, representation, inducement or license of any kind, except that it is accurate to the best of General Coatings Manufacturing Corp.'s knowledge, or obtained from sources believed by General Coatings Manufacturing Corp. to be accurate, and General Coatings Manufacturing Corp. does not assume any legal responsibility for use or reliance upon same. Customers are encouraged to conduct their own tests. Before using any product, read its label. The information contained herein is for purposes of identifying the product and does not constitute a warranty that the product will conform to that description. Product specifications and performance will vary depending on application methodologies, raw materials and other factors. PREPARED: 12/90 REVISED: 02/13
MATERIAL SAFETY DATA SHEET HMIS SYSTEM HEALTH.1 FLAMMABILITY 2 REACTIVITY 0 PROTECTION B (PREPARED IN ACCORDANCE WITH 29 CFR 1910, 1200) SECTION 1 DIVISION ADDRESS: TRADE NAME: ULTRA-SHIELD 3000 GENERAL COATINGS MANUFACTURING CORP. "COMPONENT B" 1220 E. NORTH AVE. CHEMICAL NAME: POLYURETHANE FRESNO, CA 93725 1- "COMPONENT 1-2 CHEMICAL FAMILY: POLYURETHANE 1-2 24-HR EMERGENCY NO. FORMULA: COMPLEX MIXTURE CEMTREC: (800) 424-93001- CUSTOMER INFORMATION: (559) 495-4004 SECTION II -- HAZARDOUS INGREDIENTS COMPONENT ID NUMBERS HAZA RD DATA Organotin Catalyst Trade Secret OSHA PEL (TWA) 100Ug (Sn)/m 3 A CGHI TLV (STEL) 200Ug(Sn)m Oral (rat) LD 50 50mg/kg Xylene CAS #1330-20-7 OSHA PEL (TWA) = 100ppm ACGIH TLV (STEL) = 150ppm INH L (rat) LC 50 = 6700ppm/4 hrs SECTION III -- PHYSICAL DATA Boiling Point ( F): 281-282 Specific Gravity (H 2 0=1) 1.80 Vapor Pressure (mm Hg.): 21 @ 100 F Percent Volatile By Volume (%):23.0 Vapor Density (AIR=1): 1 Evaporation Rate : Unknown Solubility in Water: Negligible APPEARANCE AND ODOR: White colored viscous liquid with an aromatic odor.
SECTION IV--FIRE AND EXPLOSION HAZARD DATA FLASH POINT : FLAMMABLE LIMITS: EXTINGUISHING MEDIA: 79 F Not established Use water spray, dry chemical, alcohol type foam or carbon dioxide. SPECIAL FIRE FIGHTING PROCEDURES: Do not enter fire area without proper protection. Wear a NIOSH/ MSHA - approved (or equivalent) self-contained breathing apparatus. During a fire, irritating or highly toxic gases (see reactivity data) are present from decomposition/combustion products. UNUSUAL FIRE AND EXPLOSION HAZARDS: Heated containers may build up pressure and rupture violently. Cool containers with water spray. SECTION V--HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: TLV =100 ppm. EFFECTS OF OVEREXPOSURE: Inhalation: Irritation of mucous membranes, coughing. Skin: Irritation, swelling. Eyes: Irritation, iachrymation. EMERGENCY AND FIRST AID PROCEDURES: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Flush skin with water. If swallowed, give milk or water if patient is conscious. Call a physician. SECTION VI -- REACTIVITY DATA STABILITY: Unstable: Stable: X CONDITIONS TO AVOID: HAZARDOUS DECOMPOSITION PRODUCTS: Keep away from heat, sparks and open flames. Avoid contact with water, strong bases, and strong oxidizers. Thermal combustion will generate CO, CO 2, and other toxic fumes. HAZARDOUS POLYMERIZATION: May Occur: Will Not Occur : X SECTION VII--SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Absorb in absorbant material. Dike to contain the spill. Collect the absorbant and spilled material in open head drums. Dispose of waste promptly. WASTE DISPOSAL METHOD: Dispose waste according to local state and federal environmental control regulations.
SECTION VIII--SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: VENTILATION: PROTECTIVE GLOVES: EYE PROTECTION: OTHER PROTECTIVE EQUIPMENT: Wear NIOSH approved respirators with organic vapor cartridges or Grade D air supplied self-contained breathing apparatus. Local exhaust: Where vapors collect. Mechanical: NEMA Class 1, Group D (explosionproof) Chemical resistant gloves. Goggles. Eye wash stations should be available. SECTION IX--SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN WHEN HANDLING AND STORING: This product is Hygroscopic and containers should be tightly closed to prevent contamination with foreign materials and moisture. Store at temperatures above 50 F and below 75 F (10-24 C). Avoid contact with skin and eyes. May cause eye irritation. Wash thoroughly after handling. Wear safety glasses when handling. Do not expose containers to heat or direct sunlight. Open containers slowly to relieve possible excess pressure. This information is furnished without warranty, representation, inducement or license of any kind, except that it is accurate to the best of General Coatings Manufacturing Corp.'s knowledge, or obtained from sources believed by General Coatings Manufacturing Corp. to be accurate, and General Coatings Manufacturing Corp. does not assume any legal responsibility for use or reliance upon same. Customers are encouraged to conduct their own tests. Before using any product, read its label. The information contained herein is for purposes of identifying the product and does not constitute a warranty that the product will conform to that description. Product specifications and performance will vary depending on application methodologies, raw materials and other factors. PREPARED: 12/90 REVISED: 02/13