Page 1 Issued: 15/05/2008 Revision No: 1 RS REACH MSDS Date 01/07/08 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING Product name: RS Superglue Gel - Activator 20ml Index number: 01-005-700 Product code: 473-439 Use of substance / preparation: Solvent-based activator for cyanoacrylate adhesives 2. HAZARDS IDENTIFICATION Main hazards: Other hazards: Highly flammable. Irritating to skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed. Vapours may cause drowsiness and dizziness. In use, may form flammable / explosive vapour-air mixture. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous ingredients: NAPHTHA (PETROLEUM), HYDROTREATED LIGHT >90% EINECS: 265-151-9 CAS: 64742-49-0 [F] R11; [Xi] R38; [N] R51/53; [Xn] R65; [-] R67 N,N-DIMETHYL-P-TOLUIDINE <1% EINECS: 202-805-4 CAS: 99-97-8 [T] R23/24/25; [Xn] R33; [-] R52/53 4. FIRST AID MEASURES (SYMPTOMS) Skin contact: There may be irritation and redness at the site of contact. Absorption through the skin may occur causing symptoms similar to those of inhalation. Absorption through the skin may occur causing symptoms similar to those of ingestion. Prolonged or repeated contact may cause defatting of the skin, which can lead to dermatitis. Eye contact: There may be irritation and redness. Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach pain may occur. Inhalation of fumes from the stomach may cause symptoms similar to direct inhalation. Aspiration into the lungs may cause chemical pneumonitis, which can be fatal.
Page 2 Inhalation: Drowsiness or mental confusion may occur. (ACTION) Skin contact: Eye contact: Ingestion: Inhalation: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash immediately with plenty of soap and water. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin. Bathe the eye with running water for 15 minutes. Do not induce vomiting. If unconscious, check for breathing and apply artificial respiration if necessary. Consult a doctor. Transfer to hospital as soon as possible. Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious, check for breathing and apply artificial respiration if necessary. Consult a doctor. 5. FIRE-FIGHTING MEASURES Extinguishing media: Exposure hazards: Protection of fire-fighters: Alcohol or polymer foam. Carbon dioxide. Dry chemical powder. Do not use water. Use water spray to cool containers. Highly flammable. Forms explosive air-vapour mixture. Vapour may travel considerable distance to source of ignition and flash back. In combustion emits toxic fumes of carbon dioxide / carbon monoxide. In combustion emits toxic fumes of nitrogen oxides. Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Environmental precautions: Clean-up procedures: Eliminate all sources of ignition. Refer to section 8 of SDS for personal protection details. Evacuate the area immediately. Mark out the contaminated area with signs and prevent access to unauthorised personnel. Turn leaking containers leak-side up to prevent the escape of liquid. Do not discharge into drains or rivers. Contain the spillage using bunding. Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for disposal by an appropriate method. Do not use equipment in clean-up procedure which may produce sparks. 7. HANDLING AND STORAGE Handling requirements: Storage conditions: Suitable packaging: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air. Smoking is forbidden. Earth any equipment used in handling. Use non-sparking tools. Store in cool, well ventilated area. Keep container tightly closed. Keep away from sources of ignition. Keep away from direct sunlight. Prevent the build up of electrostatic charge in the immediate area. Ensure lighting and electrical equipment are not a source of ignition. Stainless steel. Glass. Aluminium containers.
Page 3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Hazardous ingredients: Engineering measures: Respiratory protection: Hand protection: Eye protection: Skin protection: NAPHTHA (PETROLEUM), HYDROTREATED LIGHT WEL (8 hr TWA): 250ppm Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition. Self-contained breathing apparatus must be available in case of emergency. Gas/vapour filter, type A: organic vapours (EN141). Butyl gloves. Impermeable gloves. Safety glasses. Protective clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES State: Liquid Colour: Colourless Odour: Light, paraffinic Evaporation rate: Fast Oxidising: Non-oxidising (by EC criteria) Solubility in water: Insoluble Also soluble in: Petroleum ether. Viscosity: Non-viscous Viscosity value: 0.42 Viscosity test method: Kinematic viscosity in 10-6 m2/s at 40 C (ISO 3104/3105) Boiling point/range C: 94-99 Flammability limits %: lower: 1 upper: 7 Flash point C: -5 Part.coeff. n-octanol/water: ~4.7 Autoflammability C: 215 Vapour pressure: 5kPa @20C; 21kPa@50C Relative density: 0.71 ph: n/e 10. STABILITY AND REACTIVITY Stability: Conditions to avoid: Materials to avoid: Haz. decomp. products: Stable under normal conditions. Stable at room temperature. Sources of ignition. Flames. Heat. Hot surfaces. Direct sunlight. Strong oxidising agents. Strong acids. In combustion emits toxic fumes of carbon dioxide / carbon monoxide. In combustion emits toxic fumes of nitrogen oxides.
Page 4 11. TOXICOLOGICAL INFORMATION Hazardous ingredients: NAPHTHA (PETROLEUM), HYDROTREATED LIGHT IHL LC50 >5 mg/l ORL LD50 >2000 mg/kg SKN LD50 >2000 mg/kg N,N-DIMETHYL-P-TOLUIDINE IPR MUS LD50 212 mg/kg Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding symptoms. 12. ECOLOGICAL INFORMATION Hazardous ingredients: Mobility: Persistence and degradability: Bioaccumulative potential: Other adverse effects: NAPHTHA (PETROLEUM), HYDROTREATED LIGHT ALGAE 96H LC50 >1, <10 mg/l BACTERIA 96H LC50 >1, <10 mg/l DAPHNIA 96H LC50 >1, <10 mg/l FISH 96H LC50 >1, <10 mg/l Floats on water. Volatile. Readily absorbed into soil. Biodegradable. Bioaccumulation potential. Toxic to aquatic organisms. 13. DISPOSAL CONSIDERATIONS Disposal operations: Disposal of packaging: NB: D10 Incineration on land. R1 Solvent reclamation/regeneration. After draining, leave to vent in a safe place away from sources of ignition and heat. Beware of vapours remaining in empty drums that may ignite. Dispose of in a regulated landfill site or other method for hazardous or toxic wastes. The user's attention is drawn to the possible existence of regional or national regulations regarding disposal. 14. TRANSPORT INFORMATION ADR / RID UN no: 3295 ADR Class: 3 Packing group: II Classification code: F1 Shipping name: HYDROCARBONS, LIQUID, N.O.S. (NAPHTHA (PETROLEUM), HYDROTREATED LIGHT) Labelling: 3 Hazard ID no: 33
Page 5 IMDG / IMO UN no: 3295 Class: 3 Packing group: II EmS: F-E,S-D Marine pollutant:. Labelling: 3 IATA / ICAO UN no: 3295 Class: 3 Packing group: II Packing instructions: 305(P&CA); 307(CAO) Labelling: 3 15. REGULATORY INFORMATION Hazard symbols: Highly flammable. Dangerous for the environment. Harmful. Risk phrases: R11: Highly flammable. R38: Irritating to skin. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65: Harmful: may cause lung damage if swallowed. R67: Vapours may cause drowsiness and dizziness. Safety phrases: S9: Keep container in a well-ventilated place. S16: Keep away from sources of ignition - No smoking. S23: Do not breathe vapour. S33: Take precautionary measures against static discharges. S37: Wear suitable gloves. S61: Avoid release to the environment. Refer to special instructions / safety data sheets. S62: If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. Note: The naphtha (petroleum) hydrotreated, light, component of this product contains <0.1% benzene by weight, hence the classification as a carcinogen (R45) does not apply - see Note P in the Approved Supply List, which forms part of the CHIP3 Regulations. The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user's attention is drawn to the possible
Page 6 existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions. 16. OTHER INFORMATION Other information: Risk phrases used in s.3: Legal disclaimer: This Safety Data Sheet is compiled with reference to The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002 (CHIP3) which implement the Council Directives 67/548/EC (The Dangerous Substances Directive) and 99/45/EC (The Dangerous Preparations Directive) and subsequent amending regulations to both, and also the Safety Data Sheet Directive 91/155/EC and subsequent amending regulations. This safety data sheet is prepared in accordance with Regulation (EC) No 1907/2006. R11: Highly flammable. R38: Irritating to skin. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65: Harmful: may cause lung damage if swallowed. R67: Vapours may cause drowsiness and dizziness. R23/24/25: Toxic by inhalation, in contact with skin and if swallowed. R33: Danger of cumulative effects. R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The information contained in this safety data sheet was obtained from a variety of sources and is believed to be accurate and current at the stated issue date. RS Components and/or its agents cannot accept any liability for the use of information contained in this data sheet or for the use, application or processing of the product described in this data sheet. Users should note the possibility of hazards occurring due to improper uses of the product. [final page]