SAFETY DATA SHEET 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING ALTERNATIVE PRODUCT NAME PRODUCT NO. APPLICATION SILICONE LUBRICANT SPRAY, VINOLEO SS 4S392, IL61312 Silicone Aerosol Lubricant MANUFACTURED FOR WAVIN PLASTICS LTD BY CONTACT PERSON MacDermid plc Palmer Street Bordesley Birmingham B9 4EU tel: +44 (0) 121 606 8100 sdsuk@macdermid.com EMERGENCY TELEPHONE 24 Hour Emergency Incident Number +44 (0)208 762 8322 2 HAZARDS IDENTIFICATION Extremely flammable. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. CLASSIFICATION F+;R12. R52/53, R66, R67. PHYSICAL AND CHEMICAL HAZARDS AEROSOLS : Contains highly flammable propellant. 3 COMPOSITION/INFORMATION ON INGREDIENTS Name EC No. CAS-No. Content Classification Naptha (petroleum) hydrotreated light 265-151-9 64742-49-0 10-30% Xn;R65. R66,R67. PROPANE 200-827-9 74-98-6 10-30% F+;R12 BUTANE 203-448-7 106-97-8 10-30% F+;R12 Naptha (petroleum) hydrotreated light 265-151-9 64742-49-0 10-30% Xn;R65. Xi;R38. F;R11. N;R51/53. R67. Polydimethylsiloxane 63148-62-9 5-10% - The Full Text for all R-Phrases are Displayed in Section 16 4 FIRST AID MEASURES GENERAL INFORMATION NOTE! Keep affected person away from heat, sparks and flames! NOTE! Effects may be delayed. Keep affected person under observation. INHALATION Move the exposed person to fresh air at once. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Keep the affected person warm and at rest. Get prompt medical attention. INGESTION Promptly get affected person to drink large volumes of water to dilute the swallowed chemical. Rinse mouth thoroughly. Do not induce vomiting. If vomiting occurs, the head should be kept low so that stomach vomit doesn't enter the lungs. Provide fresh air, warmth and rest, preferably in comfortable upright sitting position. Get medical attention immediately! SKIN CONTACT Remove affected person from source of contamination. Remove contaminated clothing. Wash skin thoroughly with soap and water. Get medical attention if irritation persists after washing.
EYE CONTACT Promptly wash eyes with plenty of water while lifting the eye lids. Make sure to remove any contact lenses from the eyes before rinsing. Continue to rinse for at least 15 minutes. Get medical attention. 5 FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog. SPECIAL FIRE FIGHTING PROCEDURES Avoid breathing fire vapours. Cool aerosol containers exposed to heat with water spray and remove container, if no risk is involved. Cool containers exposed to flames with water until well after the fire is out. Use water spray to reduce vapours. UNUSUAL FIRE & EXPLOSION HAZARDS Extremely flammable. Aerosol cans may explode in a fire. SPECIFIC HAZARDS May travel considerable distance to source of ignition and flash back. Vapours may be ignited by a spark, a hot surface or an ember. Vapours may form explosive air mixtures even at room temperature. During fire, toxic gases (CO, CO2) are formed. PROTECTIVE MEASURES IN FIRE Self contained breathing apparatus and full protective clothing must be worn in case of fire. 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation of vapours and aerosol spray. Avoid contact with eyes and prolonged skin contact. Do not smoke, use naked flames or other sources of ignition. When sprayed on a naked flame or any incandescent material the aerosol vapours can be ignited. ENVIRONMENTAL PRECAUTIONS Do not discharge into drains, water courses or onto the ground. SPILL CLEAN UP METHODS Wear necessary protective equipment. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. If leakage cannot be stopped, evacuate area. Absorb spillage with non-combustible, absorbent material. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Avoid inhalation of vapours/spray and contact with skin and eyes. Keep away from heat, sparks and open flame. Eliminate all sources of ignition. Protect electric equipment against sparking in case of risk of explosion. Static electricity and formation of sparks must be prevented. Contaminated rags and cloths must be put in fireproof containers for disposal. During application and drying, solvent vapours will be emitted. Do not use in confined spaces without adequate ventilation and/or respirator. STORAGE PRECAUTIONS Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50 C. Keep away from heat, sparks and open flame. STORAGE CLASS Flammable compressed gas storage. MIN. STORAGE TEMP ( C) 5 MAX. STORAGE TEMP ( C) 25 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Name Std LT - ppm LT - mg/m3 ST - ppm ST - mg/m3 BUTANE WEL 600 ppm 1450 mg/m3 750 ppm 1810 mg/m3 PROTECTIVE EQUIPMENT
ENGINEERING MEASURES Observe workplace exposure limits and minimise the risk of inhalation of vapours and mist. Provide explosion proof ventilation for high concentrations. RESPIRATORY EQUIPMENT If ventilation is insufficient, suitable respiratory protection must be provided. At work in confined or poorly ventilated spaces, respiratory protection with air supply must be used. Seek advice from supervisor on the companies' respiratory protection standards. HAND PROTECTION For prolonged or repeated skin contact use suitable protective gloves. Neoprene or PVC gloves are recommended. EYE PROTECTION Wear approved chemical safety goggles where eye exposure is reasonably probable. OTHER PROTECTION Wear appropriate clothing to prevent repeated or prolonged skin contact. HYGIENE MEASURES DO NOT SMOKE IN WORK AREA! When using do not eat, drink or smoke. Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove non-impervious clothing that becomes contaminated. Contaminated clothing to be placed in closed container until disposal or decontamination. Warn cleaning personnel of chemical's hazardous properties. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Aerosol COLOUR Colourless ODOUR Hydrocarbon PHYSICAL DATA COMMENTS Information given relates to total aerosol container contents SOLUBILITY Insoluble in water BOILING POINT ( C) > 65 FLASH POINT ( C) -20 Not noted. 10 STABILITY AND REACTIVITY STABILITY Stable under normal temperature conditions and recommended use. CONDITIONS TO AVOID Avoid heat, flames and other sources of ignition. Avoid exposing aerosol containers to high temperatures or direct sunlight. MATERIALS TO AVOID Flammable/combustible material. HAZARDOUS DECOMPOSITION PRODUCTS By fire, toxic gases (CO, CO2, NOx) may be formed. 11 TOXICOLOGICAL INFORMATION INHALATION Vapours may cause drowsiness and dizziness. High concentrations of vapours may irritate respiratory system and lead to headache, fatigue, nausea and vomiting. Gas or vapour displaces oxygen available for breathing (asphyxiant). Unconsciousness. INGESTION May cause nausea, headache, dizziness and intoxication. Ingestion of large amounts may cause unconsciousness. SKIN CONTACT Repeated exposure may cause skin dryness or cracking. Product has a defatting effect on skin. EYE CONTACT Spray and vapour in the eyes may cause irritation and smarting. HEALTH WARNINGS Contains organic solvents which in case of overexposure may depress the central nervous system causing dizziness and intoxication. Prolonged and repeated contact with solvents over a long period may lead to permanent health problems.
12 ECOLOGICAL INFORMATION ECOTOXICITY The product contains a substance which is toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment. MOBILITY The product is insoluble in water and will spread on the water surface. BIOACCUMULATION The product contains potentially bioaccumulating substances. WATER HAZARD CLASSIFICATION WGK 2 13 DISPOSAL CONSIDERATIONS GENERAL INFORMATION Waste is classified as hazardous waste. Disposal to licensed waste disposal site in accordance with the local Waste Disposal Authority. Do not puncture or incinerate even when empty. Aerosol cans may explode in a fire. DISPOSAL METHODS Empty containers must not be burned because of explosion hazard. Dispose of waste and residues in accordance with local authority requirements. 14 TRANSPORT INFORMATION UK ROAD CLASS PROPER SHIPPING NAME AEROSOLS, FLAMMABLE UN NO. ROAD ADR CLASS IMDG CLASS MARINE POLLUTANT AIR CLASS UN1950 Class : Flammable gases. No. ADR CLASS NO. UN NO. SEA EMS UN NO. AIR UN1950 F-D, S-U UN1950 15 REGULATORY INFORMATION LABELLING Extremely Flammable RISK PHRASES R12 Extremely flammable. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness.
SAFETY PHRASES S2 S9 S16 S23 S37 S51 S56 Keep out of the reach of children Keep container in a well-ventilated place. Keep away from sources of ignition - No smoking. Do not breathe vapour/spray. Wear suitable gloves. Use only in well-ventilated areas. Dispose of this material and its container to hazardous or special waste collection point. EU DIRECTIVES Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC. Regulation (EC) No 1907/2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH). STATUTORY INSTRUMENTS Chemicals (Hazard Information and Packaging) Regulations. Control of Substances Hazardous to Health. APPROVED CODE OF PRACTICE Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. GUIDANCE NOTES Workplace Exposure Limits EH40. 16 OTHER INFORMATION REVISION DATE 29/05/2008 SAFETY DATA SHEET STATUS SIGNATURE SIGNATURE 2 Approved. SB BH RISK PHRASES IN FULL NC Not classified R11 Highly flammable R12.. Extremely flammable R38 Irritating to skin. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed R66 Repeated exposure may cause skin dryness or cracking R67 Vapours may cause drowsiness and dizziness. DISCLAIMER This information relates only to the specific material as supplied and may not be valid for such material if used in combination with any other material(s) or in any other process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. The data should not be construed as guaranteeing specific properties of the product described or its suitability for a particular application, nor does it make any warranty, either express or implied of merchantability for the product itself. It is the user's responsibilty to satisfy himself as to the suitability and completeness of such information for his own particular use.