SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: SYNONYMS: PRODUCT CODES: PrepStik Metal Cleaner MCA2ML MANUFACTURER: Clean Plus, Inc. DIVISION: ADDRESS: 138 East Main Street / PO Box 678 West Concord, MN 55985 EMERGENCY PHONE: 800-424-9300 - CHEMTREC OTHER CALLS: 1-507-527-2233 FAX PHONE: 1-507-527-2308 CHEMICAL FORMULA: PRODUCT USE: PREPARED BY: SECTION 1 NOTES: Proprietary Clean metal Technical Manager SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS CHEMICAL CLASSIFICATION: INGREDIENT: CAS NO. % OSHA PEL: ACGIH TLV: Other Limits Recommended 2-Butoxy Ethanol 111-76-2 5-10 S- 25 ppm 20 PPM Diethylene Glycol Monobutyl Ether 112-34-5 5-10 Not Estab. Not Estab. Phosphoric Acid 7664-38-2 10-30 1 mg/m 3 1 mg/m 3 SECTION 2 NOTES: SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: ROUTES OF ENTRY: POTENTIAL HEALTH EFFECTS EYES: SKIN: INGESTION: INHALATION: ACUTE HEALTH HAZARDS: CHRONIC HEALTH HAZARDS: Eyes, Inhalation This product contains a material which causes irreversible eye damage. Redness, itching, burning sensation and visual disturbances may indicate excessive eye contact May be corrosive. This product contains a material which causes skin burns. Dryness, itching, cracking, burning, redness, and swelling are conditions associated with excessive skin contact. Harmful or fatal if swallowed Vapor and/or spray mist harmful if inhaled. Vapor irritates eyes, nose and throat. Vapor generates at elevated temperatures irritates eyes, nose and throat Avoid long-term and repeated contact. This product contains elements that have been shown to cause adverse effects on the kidneys, liver, blood and blood forming tissue. Avoid long-term and repeated contact. This product contains elements that have been shown to cause adverse effects on the kidneys, liver, blood and blood forming tissue. Repeated exposer to the vapors above recommended exposure limits may cause irritation of the respiratory system and permanent brain and nervous system damage. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Not Applicable CARCINOGENICITY: Findings for humans unclear OSHA: ACGIH: NTP: IARC: OTHER: Not avail. Not avail. Not avail. Not avail. NONE KNOWN PAGE 1 OF 5
SECTION 3 NOTES: SECTION 4: FIRST AID MEASURES EYES: SKIN: INGESTION: INHALATION: Remove contact lenses and pour a gentle stream of warm water through the affected eye for at least 15 minutes. Contact poison control center, emergency room or physician immediately as further treatment will be necessary. Run a gentle stream of warm water over the affected area for 15 minutes. A mild soap may be used. Contact poison control center, emergency room, or physician immediately as further treatment will be necessary. Gently wipe or rinse the inside of the mouth with water. Sips of water may be given if he person is fully conscious. Contact poison control center, emergency room, or physician immediately as further treatment will be necessary. Remove from area to fresh air. If symptomatic, contact poison control center, emergency room, or physician immediately as further treatment will be necessary. NOTES TO PHYSICIANS OR FIRST AID PROVIDERS: SECTION 4 NOTES: SECTION 5: FIRE-FIGHTING MEASURES FLAMMABLE LIMITS IN AIR, UPPER: No Data (% BY VOLUME) LOWER: No Data FLASH POINT: F: >300 C: >149 METHOD USED: Pensky-Martens closed cup AUTOIGNITION TEMPERATURE: F: No Data C: No Data HMIS HAZARD CLASSIFICATION HEALTH: 0 FLAMMABILITY: 0 REACTIVITY: 0 PROTECTION: EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES: Use extinguishers appropriate for surrounding fire. Water spray may be ineffective. Water spray may be used to cool closed containers to prevent pressure build up and possible auto-ignition or explosion when exposed to high heat. If water is used, fog nozzles are preferable. Firefighters should wear self-contained breathing apparatus and full protective clothing. UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers may explode or burst (due to the build-up of steam pressure) when exposed to extreme heat. May produce hazardous decomposition products when exposed to extreme heat. Extreme heat includes, but is not limited to, flame cutting, brazing, and welding. HAZARDOUS DECOMPOSITION PRODUCTS: May produce the following hazardous decomposition products when exposed to extreme heat: carbon monoxide, carbon dioxide, phosphorus pentoxide. Extreme heat includes, but is not limited to flame cutting, brazing and welding. SECTION 5 NOTES: SECTION 6: ACCIDENTAL RELEASE MEASURES PAGE 2 OF 5
ACCIDENTAL RELEASE MEASURES: Provide maximum ventilation. Only personnel equipped with proper respiratory, skin, and eye protection should be permitted in the area. Remove all sources of ignition, Take up spilled material with sand, vermiculite, or other noncombustible absorbent material and place in the clean, empty containers for disposal. Only the spilled material and the absorbent should be placed in this container. SECTION 6 NOTES: SECTION 7: HANDLING AND STORAGE HANDLING AND STORAGE: If this material is part of a multiple component system, read the Material Safety Data Sheet(s) for the other component or components before blending as the resulting mixture may have the hazards of all of its parts. Protect from freezing OTHER PRECAUTIONS: SECTION 7 NOTES: Wear protective gloves. Wash hands after use. Wear goggles or face shield. Wear protective clothing. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: VENTILATION: RESPIRATORY PROTECTION: EYE PROTECTION: SKIN PROTECTION: OTHER PROTECTIVE CLOTHING OR EQUIPMENT: WORK HYGIENIC PRACTICES: EXPOSURE GUIDELINES: SECTION 8 NOTES: Provide general dilution or local exhaust ventilation in volume and pattern to keep the concentration of ingredients listed in Section 2 below the lowest suggested exposure limits, the LEL below the stated limit, and to remove decomposition products during welding or flame cutting. Overexposure to vapors may be prevented by providing proper ventilation, vapor exhaust or fresh air entry. A NIOSH approved air purifying respirator with appropriate chemical cartridges may also be used. Overexposure to vapors may be prevented by providing proper ventilation, vapor exhaust or fresh air entry. A NIOSH approved air purifying respirator with appropriate chemical cartridges may also be used. Wear chemical-type splash goggles or full face shield. Use medical grade nitrile protective gloves Wear protection sufficient to cover exposed skin. Avoid eye or skin contact. Avoid inhaling vapors. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Viscous liquid ODOR: Characteristic of the chemical family and solvents listed in Section 2. PHYSICAL STATE: ph AS SUPPLIED: BOILING POINT: MELTING POINT: FREEZING POINT: Liquid 212-446 Degrees F PAGE 3 OF 5
VAPOR PRESSURE (mmhg): 16.6 mmhg VAPOR DENSITY (AIR = 1): Heavier than air SPECIFIC GRAVITY @25 C(H2O = 1): 1.153 EVAPORATION RATE: 26 SOLUBILITY IN WATER: 99.1% PERCENT SOLIDS BY WEIGHT: 30.96 PERCENT VOLATILE: 81.450 SECTION 9 NOTES: SECTION 10: STABILITY AND REACTIVITY STABILITY: CONDITIONS TO AVOID (STABILITY): INCOMPATIBILITY (MATERIAL TO AVOID): This product is normally stable but may undergo hazardous reactions at extremely high temperatures and pressures Known Avoid contact with strong alkalis, strong mineral acids, or strong oxidizing agents. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: May produce the following hazardous decomposition products when exposed to extreme heat: carbon monoxide, phosphorous pentoxide. Extreme heat includes, but is not limited to flame cutting, brazing and welding HAZARDOUS POLYMERIZATION: Known CONDITIONS TO AVOID (POLYMERIZATION): Extreme Heat SECTION 10 NOTES: SECTION 11: TOXICOLOGICAL INFORMATION ACUTE TOXICITY: Material Percent Oral Dermal Inhalation CAS Number LD50 (g/kg) LD50 (g/kg) LC50 (mg/l) Phosphoric acid 10-30 1.53 g/kg 2.74 g/kg Not Available 7664-38-2 2-Butoxy Ethanol 5-10.47 g/kg.22 g/kg 2.18 mg/l 4 hr 111.76.2 Diethylene Glycol 5-10 6.56 g/kg 4.12 g/kg Not Available Monobutyl Ether 112-34-5 CHRONIC TOXICITY: SECTION 11 NOTES: Ingredient Target Organ/Chronic Effects: - Bone marrow and blood tissue - Blood Carcinogen - Brain Central nervous system Lung Kidney Liver - Spleen SECTION 12: ECOLOGICAL INFORMATION ECOLOGICAL INFORMATION: SECTION 12 NOTES: Known PAGE 4 OF 5
SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: RCRA HAZARD CLASS: SECTION 13 NOTES: Waste material must be disposed of in accordance with all environmental control regulations SECTION 14: TRANSPORT INFORMATION PROPER SHIPPING NAME: Phosphoric Acid Liquid Solution HAZARD CLASS: 8 ID NUMBER: UN1805 PACKING GROUP: III LABEL STATEMENT: USA RQ Hazardous Substances: USA RQ Hazardous Substance Threshold Ship Weight: Marine Pollutant Name: US A Shipment only RQ Threshold Ship Weight: Phosphoric Acid Phosporic Acid > 16666.69 Pounds This is the total weight of this product that must be shipped to exceed the RQ quantity. SECTION 14 NOTES: SECTION 15: REGULATORY INFORMATION U.S. FEDERAL REGULATIONS TSCA (TOXIC SUBSTANCE CONTROL ACT): CERCLA (COMPREHENSIVE RESPONSE COMPENSATION, AND LIABILITY ACT): SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT): 311/312 HAZARD CATEGORIES: 313 REPORTABLE INGREDIENTS: STATE REGULATIONS: INTERNATIONAL REGULATIONS: Known SECTION 15 NOTES: SECTION 16: OTHER INFORMATION OTHER INFORMATION: PREPARATION INFORMATION: Prepared 01-01-2016 DISCLAIMER: Some of the information presented is from sources other than direct test data on the product itself. The information in this SDS was obtained from sources, which are believed to be reliable. However, the information is provided without any warranty, expressed or implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond the control and knowledge of the manufacturer. For this and other reasons, the manufacturer assumes no responsibility and expressly disclaims liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for the product listed above. If the product is used as a component in another product, this SDS may not be applicable. END OF SDS PAGE 5 OF 5