1 REVISION DATE: March 2006 SDS No.: 16167 SAFETY DATA SHEET 1 IDENTIFICATION OF THE SUBSTANCEPREPARATION AND COMPANYUNDERTAKING PRODUCT NAME PRODUCT NO. 0289 SUPPLIER BOSTIK LIMITED COMMON ROAD STAFFORD STAFFORDSHIRE ST16 EH +44 178 2141 +44 178 27260 EMERGENCY TELEPHONE +44 178 2141 +44 178 27260 2 COMPOSITIONINFORMATION ON INGREDIENTS Name EC No. CAS-No. Content Classification 2- (2-HEPTADEC-8-ENYL-2-IMIDAZOLIN-1-YL)ETHAN OL BUTANONE 201-19-0 9-8- < 1% 78-9- 60-100% Xn;R22. C;R4. N;R0. F;R11 Xi;R6 R66 R67 ETHANOL 200-78-6 64-17- < 1% F;R11 The Full Text for all R-Phrases are Displayed in Section 16 HAZARDS IDENTIFICATION Highly flammable. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. CLASSIFICATION Xi;R6. F;R11. R2, R66, R67. 4 FIRST-AID MEASURES INHALATION Remove victim immediately from source of exposure. Move the exposed person to fresh air at once. Get medical attention. INGESTION DO NOT induce vomiting. Get medical attention immediately. SKIN CONTACT Promptly flush contaminated skin with water. Promptly remove clothing if soaked through and flush the skin with water. Get medical attention if irritation persists after washing. EYE CONTACT Rinse the eye with water immediately. Continue to rinse for at least 1 minutes and get medical attention. FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Fire can be extinguished using: Foam, carbon dioxide or dry powder. SPECIFIC HAZARDS Toxic gasesvapoursfumes of Carbon dioxide (CO2). Carbon monoxide (CO). PROTECTIVE MEASURES IN FIRE Wear self contained breathing apparatus
6 ACCIDENTAL RELEASE MEASURES 2 PERSONAL PRECAUTIONS Avoid skin and eye contact. Ensure adequate ventilation. Wear personal protective equipment. Wear self contained breathing apparatus. ENVIRONMENTAL PRECAUTIONS Prevent entry into drains and water courses. SPILL CLEAN UP METHODS Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Provide ventilation and confine spill. Do not allow runoff to sewer. Clean-up personnel should use respiratory andor liquid contact protection. Wash thoroughly after dealing with a spillage. Absorb onto sand, earth or abosorbent granules.pick up with non-sparking tools and place into metal containers with sealable lids.mark containers with details of hazards and store in designated area ready for disposal. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. STORAGE PRECAUTIONS Flammablecombustible - Keep away from oxidisers, heat and flames. Ground container and transfer equipment to eliminate static electric sparks. Store at moderate temperatures in dry, well ventilated area. STORAGE CLASS Flammable liquid storage. 8 EXPOSURE CONTROLSPERSONAL PROTECTION Name BUTANONE Std LT - ppm LT - mgm ST - ppm ST - mgm WEL 200 ppm(sk) 600 mgm(sk) 00 ppm(sk) 899 mgm(sk) ETHANOL WEL 1000 ppm 1920 mgm PROTECTIVE EQUIPMENT ENGINEERING MEASURES Explosion-proof general and local exhaust ventilation. RESPIRATORY EQUIPMENT Respiratory protection must be used if air contamination exceeds acceptable level. Wear mask supplied with: Gas cartridge suitable for organic substances. HAND PROTECTION Protective gloves must be used if there is a risk of direct contact or splash. Use protective gloves made of: Nitrile. EYE PROTECTION Wear splash-proof eye goggles to prevent any possibility of eye contact. OTHER PROTECTION Wear appropriate clothing to prevent repeated or prolonged skin contact. HYGIENE MEASURES Wash promptly if skin becomes contaminated. Wash at the end of each work shift and before eating, smoking and using the toilet. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE COLOUR ODOUR Liquid Clear Solvent.
REVISION DATE: March 2006 SDS No.: 16167 SOLUBILITY Slightly soluble in water. RELATIVE DENSITY 0.87 @ 2 c 10 STABILITY AND REACTIVITY STABILITY Avoid: Heat, sparks, flames. MATERIALS TO AVOID Oxidising agents. HAZARDOUS DECOMPOSITION PRODUCTS Fire or high temperatures create: Toxic gasesvapoursfumes of: Carbon dioxide (CO2). Carbon monoxide (CO). 11 TOXICOLOGICAL INFORMATION INHALATION Drowsiness, dizziness, disorientation, vertigo. SKIN CONTACT Prolonged contact may cause dryness of the skin. EYE CONTACT 12 ECOLOGICAL INFORMATION ECOTOXICITY The product contains a substance which is harmful to aquatic organisms and which may cause long term adverse effects in the aquatic environment. 1 DISPOSAL CONSIDERATIONS DISPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements. 14 TRANSPORT INFORMATION UK ROAD CLASS PROPER SHIPPING NAME UN NO. ROAD ADR CLASS NO. ADHESIVES 11 UK ROAD PACK GR. ADR CLASS ADR PACK GROUP HAZARD No. (ADR) 0 ADR LABEL NO. HAZCHEM CODE CEFIC TEC(R) NO. 0GF1-, 0GF1-sp RID CLASS NO. RID PACK GROUP UN NO. SEA 11 IMDG CLASS EMS F-E, S-D IMDG PACK GR. MFAG MARINE POLLUTANT No. UN NO. AIR 11 AIR CLASS 1 REGULATORY INFORMATION AIR PACK GR. Class : Flammable liquids. Y See Guide
LABELLING 4 RISK PHRASES Irritant R11 R6 Highly Flammable Highly flammable. R2 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R66 Repeated exposure may cause skin dryness or cracking. SAFETY PHRASES R67 S2 S9 S28 S S679 S8 S46 S1 S6 S60 Vapours may cause drowsiness and dizziness. Keep out of the reach of children Keep container in a well-ventilated place. After contact with skin, wash immediately with plenty of water. Take precautionary measures against static discharges. Wear suitable protective clothing, gloves and eyeface protection. In case of insufficient ventilation, wear suitable respiratory equipment. If swallowed, seek medical advice immediately and show this container or label. Use only in well-ventilated areas. Dispose of this material and its container to hazardous or special waste collection point. This material and its container must be disposed of as hazardous waste. STATUTORY INSTRUMENTS Chemicals (Hazard Information and Packaging) Regulations. Control of Substances Hazardous to Health. APPROVED CODE OF PRACTICE Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. GUIDANCE NOTES Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)7. CHIP for everyone HSG(108). 16 OTHER INFORMATION GENERAL INFORMATION This product should be used as directed by Bostik Ltd. For further information consult the product data sheet or contact Technical Services. INFORMATION SOURCES This safety data sheet was compiled using current safety information supplied by distributor of raw materials. REVISION COMMENTS This safety data sheet supersedes all previous issues and users are cautioned to ensure that it is current. Destroy all previous data sheets and if in doubt contact Bostik Limited. ISSUED BY Approved EC REVISION DATE March 2006 REV. NO.REPL. SDS GENERATED DATE May 200
RISK PHRASES IN FULL R11 R22 R4 R6 R0 R66 R67 Highly flammable. Harmful if swallowed. Causes burns. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and dizziness.