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Material Safety Data Sheet Sodium bromide MSDS Name: Catalog Numbers: Synonyms: Section 1 - Chemical Product and Company Identification Sodium bromide 20513-0000, 20513-0010, 20513-1000, 24690-0000, 24690-1000, 24690-5000 Acros Organics BVBA Company Identification: Janssen Pharmaceuticalaan 3a 2440 Geel, Belgium Acros Organics Company Identification: (USA) One Reagent Lane Fair Lawn, NJ 07410 For information in the US, call: 800-ACROS-01 For information in Europe, call: +32 14 57 52 11 Emergency Number, Europe: +32 14 57 52 99 Emergency Number US: 201-796-7100 CHEMTREC Phone Number, US: 800-424-9300 CHEMTREC Phone Number, Europe: 703-527-3887 Hazard Symbols: Risk Phrases: Potential Health Effects Section 2 - Composition, Information on Ingredients CAS# Chemical Name: % EINECS# 7647-15-6 Sodium bromide >99% 231-599-9 None listed None listed Section 3 - Hazards Identification EMERGENCY OVERVIEW Not available Eye: Causes mild eye irritation. Skin: May cause skin irritation. May be harmful if absorbed through the skin. May cause irritation of the digestive tract. Symptoms may include: headache, Ingestion: excitement, fatigue, nausea, vomiting, stupor, and coma. May be harmful if swallowed. Inhalation: Inhalation of high concentrations may cause central nervous system effects

Chronic: Eyes: Skin: Ingestion: Inhalation: Notes to Physician: General Information: Extinguishing Media: General Information: Spills/Leaks: characterized by nausea, headache, dizziness, unconsciousness and coma. May cause respiratory tract irritation. May be harmful if inhaled. Chronic ingestion may cause central nervous system failure. Section 4 - First Aid Measures Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid. Wash mouth out with water. Remove from exposure and move to fresh air immediately. Treat symptomatically and supportively. Section 5 - Fire Fighting Measures As in any fire, wear a self-contained breathing apparatus in pressuredemand, MSHA/NIOSH (approved or equivalent), and full protective gear. Substance is noncombustible. Use extinguishing media most appropriate for the surrounding fire. Section 6 - Accidental Release Measures Use proper personal protective equipment as indicated in Section 8. Vacuum or sweep up material and place into a suitable disposal container. Section 7 - Handling and Storage Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 7647-15-6:

Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 Respirators: approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - Physical and Chemical Properties Physical State: Crystalline powder Color: white Odor: Not available ph: 5-8.8 (5% aq. solution) Vapor Pressure: Not available Viscosity: Not available Boiling Point: 1390 deg C ( 2,534.00 F) Freezing/Melting Point: 755 deg C ( 1,391.00 F) Autoignition Temperature: Not available Flash Point: Not available Explosion Limits: Lower: Not available Explosion Limits: Upper: Not available Decomposition Temperature: Solubility in water: 905 g/l (20 C) Specific Gravity/Density: Molecular Formula: BrNa Molecular Weight: 102.89 Section 10 - Stability and Reactivity Chemical Stability: Stable under normal temperatures and pressures. Hygroscopic: absorbs moisture or water from the air. Conditions to Avoid: Incompatible materials, heating to decomposition, exposure to moist air or water. Incompatibilities with Other Strong oxidizing agents, strong acids. Materials Hazardous Decomposition Products Hydrogen bromide, sodium oxide, bromine fumes.

Hazardous Polymerization RTECS#: Will not occur. Section 11 - Toxicological Information CAS# 7647-15-6: VZ3150000 RTECS: CAS# 7647-15-6: Oral, mouse: LD50 = 7 gm/kg; LD50/LC50: Oral, rat: LD50 = 3500 mg/kg;. Other: Skin, rabbit: LD50 > 2000 mg/kg Sodium bromide - Not listed as a carcinogen by ACGIH, IARC, NTP, or Carcinogenicity: CA Prop 65. Other: Ecotoxicity: The toxicological properties have not been fully investigated. See actual entry in RTECS for complete information. Section 12 - Ecological Information Fish: Bluegill/Sunfish: LC50 > 1000 mg/l; 96h;. Daphnia: Daphnia: LC50 > 1000 mg/l; 48h;. Section 13 - Disposal Considerations Dispose of in a manner consistent with federal, state, and local regulations. Shipping Name: Hazard Class: UN Number: Packing Group: Section 14 - Transport Information IATA IMO RID/ADR Not regulated as a Not regulated as a Not regulated as a hazardous material hazardous material hazardous material European/International Regulations Section 15 - Regulatory Information European Labeling in Accordance with EC Directives Hazard Symbols:Not available Risk Phrases: Safety Phrases: S 24/25 Avoid contact with skin and eyes. WGK (Water Danger/Protection)

CAS# 7647-15-6: 1 Canada CAS# 7647-15-6 is listed on Canada's DSL List </ TD> US Federal TSCA CAS# 7647-15-6 is listed on the TSCA Inventory. Section 16 - Other Information MSDS Creation Date: 7/16/1996 Revision #1 Date 5/17/2004 Revisions were made in Sections: General revision. The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantibility or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential, or exemplary damages howsoever arising, even if the company has been advised of the possibility of such damages. --------------------------------------------------------------------------------