22 APR 2010 <MSDS_ID>300106</MSDS_ID> MATERIAL SAFETY DATA SHEET <Product> ACE TOILET BOWL CLEANER </Product> Part#: MSDS SECTION I SUPPLIER INFORMATION Common Name : TOILET BOWL CLEANER Chemical Name/Chemical Family: NONE LISTED Formula/CAS : NONE LISTED <Supplier> SUMMIT BRANDS </Supplier>#:9506 Address : 1515 DIVIDEND ROAD City, St, Zip: FORT WAYNE IN 46808 Phone: 260-483-2519 *********************** EMERGENCY PHONE #: 800-424-9300 ************************ Date Issued: 10-10-2000 Date Entered: 11-21-2007 Date Revised: 03-05-2007 SECTION II INGREDIENT INFORMATION CAS#: 7775-14-6 HYDROCHLORIC ACID (9.5%) PEL: 7 MG/M3 (CEILING) TLV: NONE LISTED STEL: NONE LISTED NIOSH REL: 7 MG/M3 (CEILING) CAS#: 1643-20-5 LAURYLDIMETHYLAMINE OXIDE (0.5-3.0%) PEL: N/A TLV: NONE LISTED STEL: NONE LISTED NIOSH REL: N/A SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point : 216 F SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS continued on the next page. Page 1
22 APR 2010 MATERIAL SAFETY DATA SHEET Page 2 MSDS Id #: 300106 SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS continued from previous page. Specific Gravity (H2O = 1) : 1.04 G/CM3 Melting Point: NOT AVAILABLE Vapor Pressure (mm Hg): NOT AVAILABLE Vapor Density (Air=1): NOT AVAILABLE Evaporation Rate (Butyl Acetate=1): NOT AVAILABLE Solubility/Water: SOLUBLE **************************** APPEARANCE AND ODOR **************************** LIQUID, BLUE/CLEAR; WINTER GREEN ODOR ----------------------------------------------------------------------------- SECTION IV FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- Flash Point: NOT APPLICABLE Auto-Ignition: NONE LISTED LEL: NONE LISTED UEL: NONE LISTED ************************ HMIS HAZARD CLASSIFICATION SYSTEM ************************ Flammable:0 Health:2 Reactivity:0 Special:NONE LISTED ************************* EXTINGUISHING MEDIA ******************************* DRY CHEMICAL, FOAM, CARBON DIOXIDE, OR WATER. ********************* SPECIAL FIRE FIGHTING PROCEDURES ********************** FIREFIGHTERS MUST BE EQUIPPED WITH SELF-CONTAINED BREATHING APPARATUS. ******************** UNUSUAL FIRE AND EXPLOSION HAZARDS ********************* NONE FLAMMABILITY: NON-FLAMMABLE SECTION V REACTIVITY DATA Stability? STABLE SECTION V Page 2 REACTIVITY DATA is continued on the next page.
22 APR 2010 MATERIAL SAFETY DATA SHEET Page 3 MSDS Id #: 300106 SECTION V REACTIVITY DATA is continued from the previous page. Avoid: INCOMPATIBLE MATERIALS ******************* INCOMPATIBILITY (Materials to Avoid) ******************** CAUSTICS, BASICS, AND LYE ******************* HAZARDOUS DECOMPOSITION OR BY-PRODUCTS ****************** HYDROGEN CHLORIDE, CHLORINE, CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN GAS Polymerization? WILL NOT OCCUR Avoid: NONE LISTED SECTION VI HEALTH HAZARD DATA *************************** ADDITIONAL INFORMATION **************************** ADDITIONAL PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------- PH: ACIDIC ECOLOGICAL INFORMATION ---------------------- NO ECOLOGICAL INFORMATION IS AVAILABLE. TRANSPORTATION INFORMATION -------------------------- PROPER SHIPPING NAME: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROCHLORIC ACID) HAZARD CLASS: 8 (CORROSIVE) ID NUMBER: UN3264 PACKING GROUP: III NOTE: THIS PRODUCT MAY BE RECLASSIFIED AS A CONSUMER COMMODITY (ORM-D) IF APPLICABLE DOT REGULATIONS ARE MET. REGULATORY INFORMATION ---------------------- FOLLOW ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. SECTION VI Page 3 HEALTH HAZARD DATA is continued on the next page.
22 APR 2010 MATERIAL SAFETY DATA SHEET Page 4 MSDS Id #: 300106 SECTION VI HEALTH HAZARD DATA is continued from the previous page. ****************************** CARCINOGENICITY ****************************** NTP? N/A IARC? N/A OSHA? N/A CARCINOGENICITY: NO ADDITIONAL INFORMATION ********************* ACUTE AND CHRONIC HEALTH HAZARDS ********************** EMERGENCY OVERVIEW ------------------ DANGER: HARMFUL IF SWALLOWED. AVOID CONTACT WITH EYES. PRIMARY ROUTES OF EXPOSURE -------------------------- EYES, SKIN AND INHALATION EFFECTS OF ACUTE EXPOSURE ------------------------- EYES: MAY IRRITATE AND INJURE EYE TISSUE IF NOT REMOVED IMMEDIATELY. SYMPTOMS MAY INCLUDE INFLAMMATION OF THE EYE CHARACTERIZED BY REDNESS, WATERING AND ITCHING. SKIN: MAY CAUSE IRRITATION AND AGGRAVATE EXISTING DERMATITIS. SKIN IRRITATION IS CHARACTERIZED BY ITCHING, SCALING, REDDENING, OR OCCASIONALLY BLISTERING. INHALATION: MAY CAUSE IRRITATION TO LUNGS AND NASAL PASSAGES. SYMPTOMS MAY INCLUDE COUGHING OR SHORTNESS OF BREATH. INGESTION: MAY CAUSE IRRITATION TO THE MOUTH AND THROAT. SYMPTOMS MAY INCLUDE NAUSEA, AND VOMITING. ********************* SIGNS AND SYMPTOMS OF EXPOSURE ************************ SEE "ACUTE AND CHRONIC" HEALTH HAZARDS. SECTION VI Page 4 HEALTH HAZARD DATA is continued on the next page.
22 APR 2010 MATERIAL SAFETY DATA SHEET Page 5 MSDS Id #: 300106 SECTION VI HEALTH HAZARD DATA is continued from the previous page. ************ MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE ************* PREEXISTING SKIN, EYE AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE. ******************** EMERGENCY AND FIRST AID PROCEDURES *********************** INGESTION: DO NOT INDUCE VOMITING! GIVE 1-2 GLASSES OF WATER OR MILK. DO NOT GIVE LIQUIDS TO UNCONSCIOUS OR CONVULSING PERSON. SEEK MEDICAL ATTENTION. EYES: CHECK FOR AND REMOVE ANY CONTACT LENSES. IMMEDIATELY IRRIGATE EYES WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION. SKIN: WASH CONTAMINATED AREA WITH SOAP AND WATER WHILE REMOVING CONTAMINATED CLOTHING. IF IRRITATION OCCURS, SEEK MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. IF BREATHING BECOMES DIFFICULT, SEE MEDICAL ATTENTION. SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE DOT Classification: SEE "ADDITIONAL INFORMATION" ********* STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED ********* SMALL SPILLS: DILUTE WITH WATER AND MOP UP, OR ABSORB WITH AN INERT (NON-COMBUSTIBLE) DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. IF NECESSARY, NEUTRALIZE THE RESIDUE WITH A DILUTE SODIUM CARBONATE SOLUTION. DISPOSE OF SPILLED MATERIALS IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. LARGE SPILLS: IF POSSIBLE, STOP THE LEAK WITHOUT POSING RISK TO PERSONNEL. ENSURE THAT PERSONNEL WEAR APPROPRIATE PPE, ARE PROPERLY TRAINED AND THAT PERSONNEL ARE NOT EXPOSED TO SPILL VAPORS ABOVE THE OSHA PEL. DIKE SPILL WITH EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL TO PREVENT SPREAD AND ENTRY INTO SEWERS, BASEMENTS OR CONFINED AREAS. NEUTRALIZE THE RESIDUE WITH A DILUTE SODIUM BICARBONATE SOLUTION. SWEEP OR SCRAPE UP SPILLED MATERIALS AND PLACE IN AN APPROPRIATE WASTE CONTAINER. DISPOSE OF SPILLED MATERIALS IN SECTION VII Page 5 SAFE HANDLING AND USE is continued on the next page.
22 APR 2010 MATERIAL SAFETY DATA SHEET Page 6 MSDS Id #: 300106 SECTION VII SAFE HANDLING AND USE is continued from the previous page. ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. ************************** WASTE DISPOSAL METHOD **************************** DISPOSE OF ACCORDING TO LOCAL, STATE AND FEDERAL REGULATIONS. ************** PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE ************** AVOID CONTACT WITH EYES, SKIN OR CLOTHING. DO NOT BREATHE VAPORS. USE THIS PRODUCT WITH ADEQUATE VENTILATION AND APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER TIGHTLY CLOSED AND STORE IN A COOL, DRY AREA. STORE AWAY FROM INCOMPATIBLE MATERIALS (I.E. ALKALIS). KEEP OUT OF THE REACH OF CHILDREN. ***************************** OTHER PRECAUTIONS ***************************** NONE LISTED SECTION VIII CONTROL MEASURES ************************ RESPIRATORY PROTECTION ***************************** NIOSH APPROVED RESPIRATORS SHOULD BE USED IF AIRBORNE CONCENTRATIONS EXCEED RECOMMENDED AND PERMISSIBLE EXPOSURE LIMITS. ******************************** VENTILATION ******************************** Local Exhaust: USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP AIRBORNE CONCENTRATION BELOW PERMISSIBLE EXPOSURE LIMITS. Special Exhaust: NONE LISTED Mechanical Exhaust: SEE ABOVE "LOCAL" Other: NONE LISTED ****************************** OTHER PROTECTION ***************************** Gloves: WEAR IMPERVIOUS GLOVES (I.E. RUBBER, NEOPRENE) TO PREVENT SKIN CONTACT. Eye Protection: WEAR SAFETY GLASSES OR CHEMICAL SAFETY GOGGLES WHERE SPLASH POTENTIAL EXISTS. SECTION VIII CONTROL MEASURES is continued on the next page. Page 6
22 APR 2010 MATERIAL SAFETY DATA SHEET Page 7 MSDS Id #: 300106 SECTION VIII CONTROL MEASURES is continued from the previous page. ******************************* CLOTHING ************************************ IT IS RECOMMENDED TO WEAR AN IMPERVIOUS APRON OR COVERALLS. FACILITIES STORING OR UTILIZING THIS MATERIAL SHOULD BE EQUIPPED WITH AN EYEWASH FACILITY AND A SAFETY SHOWER. ************************** WORK/HYGIENE PRACTICES *************************** WASH THOROUGHLY AFTER HANDLING. ************************* MISCELLANEOUS INFORMATION ************************* DISCLAIMER: INFORMATION CONTAINED HEREIN WAS OBTAINED FROM SOURCES CONSIDERED TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY EFFORT HAS BEEN MADE TO ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME CASES DATA IS NOT AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL PRODUCT USE ARE BEYOND THE CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF THIS PRODUCT HAVE BEEN TRAINED ACCORDING TO THE REQUIREMENTS OF ALL APPLICABLE REGULATIONS. NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE AND THE SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES, INJURIES OR CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR RELIANCE ON ANY INFORMATION CONTAINED IN THIS DOCUMENT. CONSULT ORIGINAL MSDS FOR ADDITIONAL INFORMATION. THIS IS THE END OF THE MSDS Id #300106