Material Safety Data Sheet (MSDS) One Part DutriGel Powder Chemical Product One Part DutriGel Powder 1. Manufacturer Identification Duka Production Ltd. at Facility Duka #2 2. Composition / Ingredients - Chemical characterization: The powder contains active ingredient Sodium Chlorite (CAS 7758-19-2) and additives 231-836-6 - EINECS-Nr./EC-Nr/ELINCS-Nr. - Danger Symbol: O (oxidizing) C (corrosive) 3. Hazards Identification - Harmful if swallowed - Contact with combustible material may cause fire - Contact with acids liberates toxic gas - Risk of serious damage to eyes - Irritating to eyes and respiratory system - Skin eruptions may occur after direct contact - Cause corrosion injuries - Toxic to aquatic organism, may cause long-term adverse effects in the aquatic environment 4. First Aid Measures -General indications: - Body and eye protection - Bring person out of danger area - After inhalation: - Move affected person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Flush mouth with water - After skin contact: - Immediately wipe off the excess material from skin. Wash with soap and water. Remove contaminated clothing and launder before reuse. Get medical attention if irritation persists - After eye contact: - With open eyelid, instantly flush with plenty of lukewarm water for at least 15 minutes and get immediate medical attention - After ingestion: - If person is conscious and able to swallow, give huge amounts of water to dilute. Never give anything by mouth to an unconscious person. If vomiting occurs, keep head lower than hips to prevent aspiration. Get medical attention immediately - Directions for the doctor - Stomach flush with gastroscope
5. Fire Fighting Procedures - Extinguishing Media: - Unsuitable extinguishing Media: - Fire Fighting Instructions: - Unusual Fire and Explosion Hazards: - Hazardous combustion products: 6. Accidental Spill or Release Procedures - Methods for cleaning up - Personal precautions: - Environmental precautions: - Flooding amounts of water - Foam - Positive pressure, self-contained breathing apparatus. Wear full protective clothing. A fire breakout may cause dangerous smoke gas. In case of fire flood with huge amounts of water. Apply water from a protected location or from a safe distance - Product is an oxidizer. Oxidizers decompose, especially when heated, to yield oxygen or other gases which will enhance the burning rate of combustible matter. Contact with moisture or humidity will generate chlorine dioxide gas. The lower explosive limit (LEL) for chlorine dioxide is 10%. If huge amounts of the products are involved in the fire, it is possible that the application of water mist or fog could release enough chlorine dioxide gas in a confined space to present an explosion hazard. The chlorine dioxide gas will dissolve harmlessly in flooding amounts of water - Not applicable - Contain spillage. Scoop up or vacuum into a container for reclamation or disposal. Avoid dusting. Soak up spill matter using an absorbent. Flush residual material and down drain with an excess of water, in accordance with local regulations. If a solution of the product is spilled, take up as much as possible and place in a suitable container for disposal in compliance with local regulations - Wear protective clothing and respiratory equipment. Avoid dust formation - Prevent contamination of soil, surface waters and sanitary sewer system. Avoid releases to the environment
7. Handing and Storage - Handing: - Fire and explosion protection indications: - Storage: - Storage Room: - Combined Storage: 8. Exposure Controls / Personal Protection - General: - Skin protection: - Personal protection: - Respiratory protection: - Ventilation: 9. Physical / Chemical properties - Physical state / appearance: - Color: - Odor: - Solubility: - ph-value: - Flash Point, o C: - Lower Explosive Limit, %: - Store only in original packing - Only use content of packaging in one shot. NO partial use - Wear protection gloves and respiratory equipment - Avoid contact with eyes, skin and clothing - Avoid generating or breathing dust - Wash thoroughly after handing - Avoid direct sunlight - Avoid contact with heat, sparks, open flame and static discharge - Protect against moisture or humidity - Keep away from acids, and combustible materials - Store in a cool, dry location away from incompatible materials - Cool, dry, clean and locked. Well ventilated - Keep away from metal, metal salts, bases, reducing agents and combustible materials. - Keep away from food and beverages - When touching clothing immediately rinse with water - Avoid generating dust - Do not smoke - Avoid skin contact. Wear clean, body protection clothing - Wear goggles and PVC protective gloves. Wash hands before breaks and immediately after handing the product - Use approved respiratory protection if exposure limits are exceeded, or overexposure is likely. Respirator with combination filter for vapor/particulate - According Local Standards; exhaust ventilation is recommended to control exposure to within applicable limits. - Powder/Granulate - White - Odorless to slight chlorine odor - Reacts with water to form firm gel - 6 approx. 100g/L water
- Upper Explosive Limit, %: 10. Stability and Reactivity - Stability date: - Conditions/Hazards to avoid: - Incompatibility (materials to avoid): - Hazardous reactions: - Hazardous decomposition product: - Polymerization: - Polymerization Avoid: 11. Toxicological and Health information - Acute Toxicity - Dermal: - Stable - Heat. Exposure to light - Metal salts (transformation) - Reducing Agents (Transformation) - Acids (gas formation) - Oxidizers (gas formation) - Combustibles materials (fire danger) - Upon exposure to water vapor, ClO released - Chlorine - Will not occur - None anticipated 2 gas is - Acute Toxicity - Inhalation: - Skin irritation: - Eye irritation: - Sensitization: - Other information: - Potential Health effects: - NOTE: Upon exposure to moisture, this product releases chlorine dioxide gas. The oral LD50 in rats for chlorine dioxide has been reported as 292 mg/kg - Inhalation: exposure to dust particles from this product causes irritation of the respiratory tract. May result in coughing, difficult breathing and sore throat. Exposure to high concentrations may result in burns of the mucous membranes,bronchospasm and delayed pulmonary edema - Ingestion: harmful if swallowed. May cause pain, nausea, vomit and diarrhea. May cause burns of the mouth, throat and stomach. Cause severe tissue damage
- Chronic Health Hazards: 12. Ecological information - Fish toxicity: - Bacteria toxicity: - Environmental Fate: - Ecotoxicological information: 13. Disposal indications - Disposal of waste product: - Waste key number: - Waste name: - Original Packaging: - Skin contact: cause skin irritation. Contact with moist skin causes burns. Prolonged contact may cause dermatitis. - Eye contact: cause severe eye irritation. May cause eye burns and damage - Other effects: NOTE: Upon exposure to moisture, this product releases chlorine dioxide gas. Inhalation of ClO2 gas may cause irritation, coughing, wheezing and burns of the mucous membranes. Inhalation of large amounts may lead to pulmonary edema and bronchitis. Direct contact with ClO2 gas causes eye and skin irritation and may cause burns. - Prolonged or repeated exposure to dust may cause pulmonary problem - LD 50 (96 h)= 100-2000 mg/l (Brachydanoio rerio, OECD 203) - EC 50 = 100 800 mg/l (OECD 209) - May cause long-term adverse effects in the aquatic environment - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment - All waste materials should be reviewed to determine the applicable hazards. National and local disposal laws and regulations will determine the proper waste disposal / recycling / reclamation procedure. Dispose in accordance with official local regulations - 060714 - Inorganically chemical compound - Do not reuse original packaging. Clear empty packaging with copious amounts of water and dispose in accordance with local regulations
14. Transport information - Transport by land ADR/RID classes: - UN-number: - Product type indicator: - Remarks: 15. Regulations - Labeling EC-directives 67/548/EECs: - Recognition numbers and hazard symbols and signs: - R-Phases: - S-Phases: 16. Other Information Dangerous product described by transport regulations (GGVS/GGVE/RID/ADR/IMDG-Code/ICAO-TI) - Class 5.1 / II - UN 1479 - Oxidizing solid, n.o.s. - Store in a cool and dry place, keep away from direct light, protect against fire, keep away from children and visitors on premise The product is classified and marked O: Oxidizing Xi: Irritant 8: Contact with combustible material may cause fire 32: Contact with acids liberates very toxic gas 41: Risk of serious damage to eyes 36/37: Irritating to eyes and respiratory system 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment 1/2: Keep locked up and out of the reach of children or visitors 8: Keep packaging dry, avoid moisture and humidity 22: Do not breathe dust 24: Avoid contact with the skin 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 36/37/39: Wear suitable protective clothes, gloves, eye/face protection 45: In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) This information in this Safety Date Sheet should be provided to all who will use, handle, store, transport or otherwise be exposed to this product. This information is based on our present state of knowledge and is intended to describe our product with respect to possible safety demands. We believe this information is reliable and up-to-date as of the date of publication, but make no warranty that it is. We provide no guarantee of properties or description of qualities.
Manufacturer: Duka Production Ltd. Vermeerstraat 1 7730 AA, Ommen The Netherlands Phone: +31 529 712520