Date Printed: 05/13/2004 Date Updated: 03/06/2004 Version METHYL-2-PROPENE-1,1-DIOL DIACETATE,98% Product Number

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SIGMA-ALDRICH MATERIAL SAFETY DATA SHEET Date Printed: 05/13/2004 Date Updated: 03/06/2004 Version 1.3 Section 1 - Product and Company Information Product Name 2-METHYL-2-PROPENE-1,1-DIOL DIACETATE,98% Product Number 156795 Brand ALDRICH Company Sigma-Aldrich Street Address 3050 Spruce Street City, State, Zip, Country SAINT LOUIS MO 63103 US Technical Phone: 314 771 5765 Emergency Phone: 414 273 3850 Ext. 5996 Fax: 800 325 5052 Section 2 - Composition/Information on Ingredient Substance Name CAS # SARA 313 2-METHYL-2-PROPENE-1,1-DIOL 10476-95-6 Yes DIACETATE,98% Formula Synonyms RTECS Number: C8H12O4 Acetic acid, 2-methyl-2-propene-1,1-diol diester * 2-Methyl-2-propene-1,1-diol diacetate UC9800000 Section 3 - Hazards Identification EMERGENCY OVERVIEW Highly Toxic (USA) Very Toxic (EU). Very toxic by inhalation, in contact with skin and if swallowed. Readily absorbed through skin. Causes severe irritation. Combustible. For additional information on toxicity, please refer to Section 11. Section 4 - First Aid Measures ORAL EXPOSURE If swallowed, wash out mouth with water provided person is conscious. Call a physician immediately. INHALATION EXPOSURE If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. EYE EXPOSURE Assure adequate flushing of the eyes by separating the eyelids with fingers. Section 5 - Fire Fighting Measures FLASH POINT

182 F 83 C Method: closed cup AUTOIGNITION TEMP FLAMMABILITY EXTINGUISHING MEDIA Suitable: Water spray. Carbon dioxide, dry chemical powder, or appropriate foam. FIREFIGHTING Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. Specific Hazard(s): Emits toxic fumes under fire conditions. Combustible liquid. EXPOSURE HAZARD(S) Material: Severe irritant. Section 6 - Accidental Release Measures PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL Evacuate area. PROCEDURE(S) OF PERSONAL PRECAUTION(S) Wear self-contained breathing apparatus, rubber boots, and heavy rubber gloves. METHODS FOR CLEANING UP Absorb on sand or vermiculite and place in closed containers for disposal. Ventilate area and wash spill site after material pickup is complete. Section 7 - Handling and Storage HANDLING User Exposure: Do not breathe vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure. STORAGE Suitable: Keep tightly closed. Keep away from heat and open flame. Store in a cool dry place. Store under nitrogen. Section 8 - Exposure Controls / PPE ENGINEERING CONTROLS Safety shower and eye bath. Use only in a chemical fume hood. PERSONAL PROTECTIVE EQUIPMENT Other: Wear appropriate government approved respirator, chemical-resistant gloves, safety goggles, other protective clothing. GENERAL HYGIENE MEASURES Wash contaminated clothing before reuse. Wash thoroughly after handling. Section 9 - Physical/Chemical Properties Appearance Color: Faintly yellow ALDRICH - 156795 www.sigma-aldrich.com Page 2

Form: Clear liquid Property Value At Temperature or Pressure Molecular Weight 172.18 AMU ph BP/BP Range 190-192 C MP/MP Range -15 C Freezing Point Vapor Pressure 760 mmhg 191 C Vapor Density Saturated Vapor Conc. SG/Density 1.048 g/cm3 Bulk Density Odor Threshold Volatile% VOC Content Water Content Solvent Content Evaporation Rate Viscosity Surface Tension Partition Coefficient Decomposition Temp. Flash Point 182 F 83 C Method: closed cup Explosion Limits Flammability Autoignition Temp Refractive Index 1.426 Optical Rotation Miscellaneous Data Solubility = not available Section 10 - Stability and Reactivity STABILITY Materials to Avoid: Strong oxidizing agents, Strong acids, Strong bases. HAZARDOUS DECOMPOSITION PRODUCTS Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide. Section 11 - Toxicological Information ROUTE OF EXPOSURE Multiple Routes: May be fatal if inhaled, swallowed, or absorbed through skin. High concentrations are extremely destructive to tissues of the mucous membranes and upper respiratory tract, eyes, and skin. SIGNS AND SYMPTOMS OF EXPOSURE Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. TOXICITY DATA Oral ALDRICH - 156795 www.sigma-aldrich.com Page 3

Rat 440 UL/KG LD50 Skin Rabbit 44 UL/KG LD50 Section 12 - Ecological Information Section 13 - Disposal Considerations APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION This combustible material may be burned in a chemical incinerator equipped with an afterburner and scrubber. Observe all federal, state, and local environmental regulations. Section 14 - Transport Information DOT Proper Shipping Name: Toxic, liquids, organic, n.o.s. UN#: 2810 Class: 6.1 Packing Group: Packing Group II Hazard Label: Toxic substances. PIH: Not PIH IATA Proper Shipping Name: Toxic liquid, organic, n.o.s. IATA UN Number: 2810 Hazard Class: 6.1 Packing Group: II Section 15 - Regulatory Information EU ADDITIONAL CLASSIFICATION Symbol of Danger: T+ Indication of Danger: Very toxic. R: 26/27/28 Risk Statements: Very toxic by inhalation, in contact with skin and if swallowed. S: 23 26 27 36/37/39 45 Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US CLASSIFICATION AND LABEL TEXT Indication of Danger: Highly Toxic (USA) Very Toxic (EU). Risk Statements: Very toxic by inhalation, in contact with skin and if swallowed. Safety Statements: Do not breathe vapor. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Take off immediately all contaminated clothing. Wear suitable protective clothing, gloves, and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). US Statements: Readily absorbed through skin. Causes severe ALDRICH - 156795 www.sigma-aldrich.com Page 4

irritation. Combustible. UNITED STATES REGULATORY INFORMATION SARA LISTED: Yes NOTES: This product is subject to SARA section 313 reporting requirements. TSCA INVENTORY ITEM: Yes CANADA REGULATORY INFORMATION WHMIS Classification: This product has been classified in accordance with the hazard criteria of the CPR, and the MSDS contains all the information required by the CPR. DSL: No NDSL: Yes Section 16 - Other Information DISCLAIMER For R&D use only. Not for drug, household or other uses. WARRANTY The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Sigma-Aldrich Inc., shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale. Copyright 2004 Sigma-Aldrich Co. License granted to make unlimited paper copies for internal use only. ALDRICH - 156795 www.sigma-aldrich.com Page 5