Revised edition: 27.11.2012 1. 1. 1. Version: 1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Casein 1. 2. Article No.: 63200 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Preparation of adhesives, paints and varnishes 1. 3. Uses advised against: Details of the Supplier of the Safety Data Sheet Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 1. 4. Internet: EMail: Emergency No. www.kremer-pigmente.de info@kremer-pigmente.de 2. 2. 1. Emergency No.: +49 7565 914480 (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product is not classified as hazardous according to the CLP/GHS Directive. The material is not subject to classification according to EC lists. 2. 2. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: Signal word: Hazard designation: Safety designation: See Section 12. This product does not require classification and labelling as hazardous according to CLP/GHS. Not applicable. 2. 3. Hazardous components for labelling: Other Hazards 2
3. 3. 1. 3. 2. Composition/Information on Ingredients Substance Mixture Page 2 This product is a substance: see details under 3.2. Chemical Characterization: Casein. CAS No. 900-71-9; EINECS 232-555-1 Hazardous Ingredients: 4. 4. 1. Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Seek medical attention in case of complaints. Remove contaminated clothes. Supply fresh air. Wash off immediately with plenty of soap and water and rinse thoroughly. Rinse open eye for several minutes under running water. 4. 2. After ingestion: Most important Symptoms and Effects, both Acute and Delayed Immediately get medical help. Rinse mouth with water and give plenty of water to drink. Consult a physician. Never give anything by mouth to an unconscious person. Symptoms: No further information available. 4. 3. Effects: Indication of any Immediate Medical Attention and special Treatment needed 5. 5. 1. Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: No further information available. Foam, carbon dioxide (CO2), extinguishing powder, water jet. 5. 2. Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture Special hazards: In case of fire: formation of carbon oxides, toxic gases/vapors. 3
5. 3. Advice for Firefighters Page 3 Protective equipment: Wear self-contained respiratory protective device and protective clothing. 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures 6. 2. Personal precautions: Environmental Precautions Avoid formation of dust. Provide adequate ventilation. Keep away from sources of ignition. 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. For information for safe handling see Section 7. Protective clothing, see Section 8. Dispose of contaminated material according to Section 13. Avoid formation of dust. Provide adequate ventilation. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities No special measures required. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Store in tightly sealed containers in a dry and well ventilated location. No special measures necessary. Dust may form an explosive mixture with air. Take measures to prevent static electricity discharge. Keep away from sources of ignition - do not smoke. 10-13 Further Information: 4
7. 3. Specific End Use(s) Page 4 8. 8. 1. Further information: Exposure Controls/Personal Protection Parameters to be Controlled Does not contain substances with occupational exposure limits. Parameters to be controlled (DE): Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): 8. 2. Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation/exhaust system. Facilities storing or utilizing this material should be equipped with an eyewash and shower facility. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Required in case of insufficient ventilation (EN 143 or 149). Protective gloves (EN 374) Nitrile rubber (480 min, 0.35 mm) Natural rubber (> 240 min, 0.5 mm) Tightly fitting safety goggles (EN 166). Protective clothing. 9. 9. 1. Environmental precautions: No special measures required. Physical and Chemical Properties Information on Basic Physical and Chemical Properties Form: Color: Odor: powder white characteristic Odor threshold: 5
Page 5 ph-value: Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): 5 (20 C) not flammable 1.4 g/cm3 (20 C) insoluble Auto-ignition temperature: 450 C 9. 2. Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic no information available Burning class: 6
Solvent content: Page 6 10. 10.1. 10.2. 10.3. 10.4. 10.5. 10.6. 10.7. 11. 11. 1. Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: No further information. Stable if used according to specifications. Stable if used according to specifications. Unknown. Avoid humidity. Product is hydroscopic. No decomposition if used according to specifications. None known. No toxicity expected. Non irritating Non-irritating to eyes No information available Sensitization: 7
No sensitizing effects known. Page 7 12. 12. 1. 12. 2. 12. 3. 12. 4. 12. 5. 12. 6. 13. 13. 1. Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Moblity Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: Disposal Considerations Waste Treatment Methods Product: European Waste Code (EWC): No toxicity expected. Readily biodegradable. Not hazardous. Dispose of according to official national and local regulations. Uncleaned packaging: 8
Page 8 Uncontaminated packaging may be recycled. Completely empty packaging can be disposed of with the regular waste. 14. 14. 1. 14. 2. Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name 14. 3. 14. 4. ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. 14. 5. 14. 6. 14. 7. 14. 8. 15. 15. 1. IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 0, not hazardous Local regulations on chemical accidents: 9
Not listed. Page 9 15. 2. 15. 3. 16. Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information A Chemical Safety Assessment has not been carried out for this product. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.