Report from the SMHI monitoring cruise with R/V Aranda

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Lars Andersson Swedish Meteorological and Hydrological Institute Oceanographic Laboratory 2014-10-28 Dnr: S/GBG-2014-161 Report from the SMHI monitoring cruise with R/V Aranda Survey period: 2014-10-20-2014-10-28 Survey area: Skagerrak, Kattegat, the Sound and the Baltic Proper Principal: SMHI and the Swedish Agency for Marine and Water Management SUMMARY The expedition was part of the Swedish regular marine monitoring programme and covered Skagerrak, Kattegat, the Sound and the Baltic Proper. Data presented in this report have been subject to preliminary quality control procedures only. Water temperature in the surface layer was slightly above normal in the whole investigated area. Nutrients in the surface layer showed normal concentrations, except for elevated silicate concentrations in the western and eastern Gotland basin. In the western part of Skagerrak a thin layer containing very high concentrations of nutrients was detected. The Arkona Basin was well oxygenated, while in the Bornholm Basin and Hanö Bight acute hypoxia occurred from depths exceeding 60 to 70 metres. Oxygen conditions in the eastern Gotland basin had deteriorated in the central parts, where acute hypoxia ( < 2ml/l) was found from 70 to 80 metres depth and anoxia from 125 metres. Nevertheless, in the southern parts of the eastern Gotland basin bottom water containing relatively high oxygen content was registered. In the western Gotland basin hypoxia was found from 70 metres depth and anoxia from below 80 metres depth. The next cruise is planned for week 46 (10-17 Nov) and will cover Skagerrak, Kattegat, the Sound and the Baltic Proper. Address: Sven Källfelts gata 15 SE-426 71 Vastra Frolunda SWEDEN Telephone: +46 11 4958000 E-mail: Lars.S.Andersson@smhi.se WWW: http://www.smhi.se/

PRELIMINARY RESULTS The cruise was performed on board the Finnish research vessel Aranda, and began in Helsinki on 20 th October and ended in the same port on the 28 th. During the early part of the expedition winds were weak to moderate, coming mainly from east. After the first days the winds turned to westerly or south-westerly and increased to gale force. Air temperature varied between 10-13 C. In order to get a better picture of the oxygen situation in the Eastern Gotland Basin an extra station, apart from the ordinary ones, was visited. A bottom-mounted rig with a recording oxygen sensor was deployed northeast of Öland's Southern Ground. The system will measure the oxygen level at a depth of 58 m, every 10 minutes, for about 5 months, in order to give a better picture of how fast the oxygen levels vary close to the halocline. Two researchers from University of Helsinki took part in the expedition in order to study the formation of N 2 O in hypoxic waters, where this strong greenhouse gas is formed through a denitrification process. The goal was to study the formation of N 2 O following the inflow of water that took place in Feb-Mar 2014, and which oxygenated large parts of the Baltic Sea deep water this subsequently led to widespread hypoxic conditions. In constant anoxia the accumulation of N 2 O ends, which is why the current situation of hypoxia is interesting to study. The Skagerrak The thermocline was weakly developed close to the coast, while in the more central parts it was distinct and found at depths between 40 to 60 metres. Temperature in the upper layer was slightly above normal for the season, ca.13 degrees. The halocline was also weakly developed in the coastal areas, where the salinity was around 33 psu in the surface water, which is higher than normal, while it was more distinct further west, where it was found at 10-20 metres depth. Nutrient levels in the surface layer had increased slightly since the previous survey. Phosphate concentrations varied between 0.10 and 0.33 µmol/l, silicate from 0.6 to 3.4 µmol/l, while concentrations of inorganic nitrogen (nitrite + nitrate) ranged between 0.25 and 1.16 µmol/l. All values normal for the season. At 15 m depth at station Å17, furthest west, a thin layer of water with extremely high nutrient concentrations was found, probably originating from the southern North Sea. Some plankton activity, based on fluorescence measurements, was recorded in the central regions, while the activity was low near the coast. The lowest oxygen value encountered in the bottom water was found at station Släggö, in the mouth of the Gullmar fjord, at 3 ml/l. The Kattegat and the Sound The thermocline was located at a depth of about 15 metres, but was very weak. Temperature in the surface layer was slightly above normal, about 12.5 o C. Surface salinity was normal, ca. 22 psu, in Kattegat and 17.5 psu in the Sound. The halocline was found at 15 metres depth in the Kattegat and at 7 metres in the Sound. Nutrients showed normal concentrations for the season, phosphate between 0.13 and 0.18 µmol/l, nitrite + nitrate from below detection limit (< 0.10 µmol/l) to 0.17 µmol/l, and silicate in the range of 1.9 to 3.3 µmol/l. In the Sound levels were generally higher, phosphate was at 0.42 µmol/l and silicate at 11 µmol/l. Fluorescence measurements indicated some plankton activity in the surface layer in the whole area. Oxygen concentrations in the bottom water were typical for the season and varied between 2.8 and 4.1 ml/l, lowest in the Sound.

The Baltic Proper The water temperatures were above normal in the whole area, varying from 11.4 to 14.3 C, and the thermocline was found at 30 metres depth. The salinity in the surface layer was normal in the major part of the area, at between 6.5 and 7.9 psu. In the Eastern Gotland Basin, however, surface salinity was clearly below normal, ca. 6.6 psu. The halocline was found at depths between 60 and 70 metres in the western and eastern Gotland Basins, while it was shallower located, between 35 and 50 metres, in the southern parts. All nutrients in the surface layer showed normal values for the season, silicate between 9-12 µmol/l, phosphate in the interval 0.15 to 0.30 µmol/l, while inorganic nitrogen (nitrite + nitrate) varied from below detection limit up to 0.6 µmol/l, highest in the Western Gotland Basin. Effects of the inflow (25 km 3 ) through the Sound that occurred in August were still obvious in the southern parts. In addition, during September and October two new inflows of ~20 km3 and ~8 km3 were registered through the Sound. The Arkona Basin was now well oxygenated, while acute hypoxia was present in the Bornholm Basin and Hanö Bight, at depths exceeding 60-70 metres. In the northern and central parts of the Eastern Gotland Basin acute hypoxia occurred from 70-80 metres, and hydrogen sulphide was found at depths exceeding 125-135 metres. In the southern parts of the basin (BY10 and BY9 W) an oxygen minimum (~1 ml/l) was detected at 90 to 100 metres, while oxygen concentrations close to the bottom, at 143 and 124 metres respectively, were about 2 ml/l. At station BCSIII-10 in the southeast an oxygen minimum (0.6 ml/l) was encountered at 80 metres, while at 90 metres depth the concentration was 2.4 ml/l. In the western Gotland basin the oxygen situation was severe, as acute hypoxia was found from depths exceeding 70 metres and hydrogen sulphide from below 80 to 90 metres depths. PARTICIPANTS Name Institute Lars Andersson Chief Scientist SMHI Kristin Andreasson Quality responsible SMHI Daniel Bergman-Sjöstrand SMHI Örjan Bäck SMHI Sofia Carlsson (Lysekil Helsingfors) SMHI Martin Hansson (Helsingfors Lysekil) SMHI Mikael Krysell (Lysekil Helsingfors) SMHI Vivi Månsson SMHI Susanna Hietanen University of Helsinki Petra Tallberg University of Helsinki APPENDICES - Track chart - Table over stations, parameters and sampling depths - Map showing bottom oxygen concentrations - Monthly average surface water plots for selected stations - Vertical profiles for selected stations

SMHI ***** Hydrographic Ship: 01-Aranda ****** Date: 2014-10-27 Ocean enh ***** series Year: 2014 ****** Time: 14:05 Ser Stat P Station----------------- Lat----- Lon----- Date Time Bottom Secchi Wind Air Air WCSI C PPCPZZT No T S P O H P T N N N T A S H L P P T C no code r yyyymmdd hhmm depth depth di ve temp pres elec t Hrhhoor de e a h x 2 o o o o h o l i u i O O O o o utc m m C hpa aoae d Cilyooa m l y S 4 t 2 3 4 t k O m g N C C m j tu motpbw p i g P P N N N N a 3 u n m hd PrP l n l s i 0720 BPEX26BAS BY20 FÅRÖDJ N5800 E1953 20141021 0520 195 03 4 8.1 1004 2730 x --x---- 17 x x - x x x x x x x x - x - - - - - x 0721 BPEX21BAS BY15 GOTLANDSDJ N5720 E2003 20141021 1030 239 11 08 3 10.0 1004 2740 x -xxxx-- 19 x x x x x x x x x x x x x x - - - - x 0722 BPEX21EXT BY15 GOTLANDSDJ N5720 E2003 20141021 1215 239 11 08 3 10.0 1004 2740 x ------- 5 x x - x x x x x x x x - x - - - - - x 0723 BPEX13BAS BY10 N5638 E1935 20141021 1730 144 12 9 10.3 1003 9990 x --x---- 15 x x - x x x x x x x x - x - - - - - x 0724 BPSE00BAS BY9W N5607.20 E1901.00 20141021 2240 125 11 12 10.8 1002 9990 x ------- 14 x x - x - - - - - - - - - - - - - - x 0725 BPSE11BAS BCS III-10 N5533.3 E1824 20141022 0350 91 13 10 12.4 1001 9990 x --xx--- 12 x x - x - x x x x x x - x x - - - - - 0726 BPSB07BAS BY5 BORNHOLMSDJ N5515 E1559 20141022 1230 90 9 09 10 12.7 1006 2840 x -xxxx-- 12 x x x x - x x x x x x x x x - - - - x 0727 BPSB06BAS BY4 CHRISTIANSÖ N5523 E1520 20141022 1605 93 07 11 11.8 1011 9990 x --x---- 12 x x - x - x x x x x x - x - - - - - - 0728 BPSA03BAS BY2 ARKONA N5500 E1405 20141022 2300 46 07 9 12.0 1016 9990 x --xxx-- 8 x x - x - x x x x x x - x x - - - - x 0729 BPSA02BAS BY1 N5500 E1318 20141023 0325 46 09 8 11.9 1017 9990 x --x---- 8 x x - x - x x x x x x - x - - - - - - 0730 SOCX39BAS W LANDSKRONA N5552.0 E1245.0 20141023 0945 51 4.5 14 10 11.3 1021 2830 x --x---- 9 x x - x - x x x x x x - x - - - - - x 0731 KAEX29BAS ANHOLT E N5640.0 E1207.0 20141023 1440 62 7 16 14 11.0 1020 2840 x -xxx--- 10 x x x x - x x x x x x x x x - - - - x 0732 KANX50BAS N14 FALKENBERG N5656.40 E1212.70 20141023 1730 31 15 16 10.6 1020 9990 x -xxx--- 7 x x x x - x x x x x x x x - - - - - x 0733 KANX25BAS FLADEN N5711.5 E1140 20141023 2050 84 18 15 11.2 1019 9990 x --x---- 12 x x - x - x x x x x x - x - - - - - - 0734 SKEX23BAS P2 N5752 E1118 20141024 0100 94 19 15 11.8 1016 9990 x --x---- 10 x x - x - x x x x x x - x - - - - - - 0735 SKEX18BAS Å17 N5816.5 E1030.8 20141024 0540 350 19 14 12.2 1012 4850 x --xx--- 14 x x x x - x x x x x x x x - - - - - x 0736 SKEX17BAS Å16 N5816 E1043.5 20141024 0720 204 14 17 12.1 1013 2850 x ------- 13 - - - - - - - - - - - - - - - - - - - 0737 SKEX16BAS Å15 N5817.7 E1051 20141024 0835 136 18 16 12.7 1012 5850 x --x---- 12 x x - x - x x x x x x - x - - - - - - 0738 SKEX15BAS Å14 N5819 E1056.5 20141024 0935 110 17 16 12.4 1013 5850 x ------- 11 - - - - - - - - - - - - - - - - - - - 0739 SKEX14BAS Å13 N5820.2 E1102 20141024 1040 100 18 15 13.0 1013 2850 x --x---- 10 x x - x - x x x x x x - x - - - - - - 0740 FIBG27BAS SLÄGGÖ N5815.5 E1126.0 20141024 1245 73 17 11 12.4 1013 2820 x --xxx-- 9 x x - x - x x x x x x - x - - - - - - 0741 KAEX29BAS ANHOLT E N5640.0 E1207.0 20141025 0540 62 20 14 10.5 1013 9990 x -xxx--- 10 x x x x - x x x x x x x x x - - - - x 0742 BPSH05BAS HANÖBUKTEN N5537 E1452 20141025 2320 80 24 9 12.4 1019 9990 x --x---- 11 x x - x - x x x x x x - x - - - - - - 0743 BPWK01BAS REF M1V1 N5622.25 E1612.1 20141026 0650 20 3 20 7 12.3 1020 1620 x -xxxx-- 5 x x x x - x x x x x x x x - - - - - - 0744 BPWX00EXT 4.5 NO BY39 N5610.06 E1638.64 20141026 1040 58 23 10 12.1 1020 1240 x ------- 8 - - - - - - - - - - - - - - - - - - x 0745 BPWX45BAS BY38 KARLSÖDJ N5707 E1740 20141026 1900 110 22 15 12.1 1018 9990 x --x---- 14 x x - x x x x x x x x - x - - - - - x 0746 BPWX38BAS BY32 NORRKÖPINGSDJ N5801 E1759 20141027 0030 200 22 16 11.9 1013 9990 x --x---- 17 x x - x x x x x x x x - x - - - - - -

Bottom water oxygen concentration (ml/l) Country: Finland Ship : Aranda Date : 20141021-20141027 Series : 0720-0746 H2S H2S H2S H2S 4.13 4.28 4.27 2.01 6.98 1.96 2.77 0.97 2.36 0.73 0.29 3.17 3.10