1 MATERIAL SAFETY DATA SHEET According to Regulation (EC) No 1907/2006 1 IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY PRODUCT NAME REWELL FOR WOMAN OBSESSION DEODORANT BADY SPRAY APPLICATION Men deodorant DISTRIBUTOR: Well Done Kft. 2900 Komárom, Mártírok u. 92. CONTACT PERSON: welldone@welldone.eu TELEPHONE : +36 34 340 312 2 HAZARDS IDENTIFICATION Indications of danger ( symbols ) : F+ Risk phrases : Extremely flammable. (R12) 3 COMPOSITION/INFORMATION ON INGREDIENTS Name EC No Cas No % Weight Symbol R-Phrases Propan,Butan,Isopropane,Isobutane 270-705-8 68476 86 8 50-60 F+ R12 (LPG-Liquid Petroleum Gas) ETHANOL 200-578-6 64-17-5 40-50 F R11 The full Text for all R-Phrases are Displayed in Section 16. 4 FIRST-AID MEASURES EYE CONTACT : Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. SKIN CONTACT : Wash off promptly and flush contamined skin with water. Get medical attention, if any discomfort continues. INGESTION : Not relevant INHALATION discomfort continues. : Move the exposed person to fresh air at once. Get medical attention if any
2 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Use: Powder. Dry chemicals, sand, dolomite etc. Water spray, fog or mist. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE Hazardous combustion products During fire, toxic gases (CO, CO2) are formed. Unusual Fire & Explosion Hazards Aerosol cans may explode in a fire. Specific hazards Containers can burst violently when heated, due to excess pressure build-up. Special Fire Fighting Procedures Containers close to fire should be removed or cooled with water. Use water to keep fire exposed containers cool and disperse vapours. Be aware of danger of explosion. Keep run-off water out of sewers and water sources. Dike for water control. Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. 6 ACCIDENTAL RELEASE MEASURES Wear protective clothing as described in Section 8 of this safety data sheet. Take precautionary measures against static discharges. Do not smoke, use open fire or other sources of ignition. Avoid inhalation of spray mist and contact with skin and eyes. ENVIRONMENTAL PRECAUTIONS Do not discharge into drains, water courses or onto the ground. SPILL CLEAN UP METHODS Wear necessary protective equipment. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb in vermiculite, dry sand or earth and place into containers. Let evaporate. Keep out of confined spaces because of explosion risk. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Use explosion proof electric equipment. Keep away from heat, sparks and open flame. Eye wash facilities and emergency shower must be available when handling this product. USAGE DESCRIPTION Shelf life : 2 yıl (minimum) STORAGE PRECAUTIONS Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50 C. Keep away from heat, sparks and open flame. Keep away from food, drink and animal feeding stuffs. Keep in original container. Keep out of the reach of children. STORAGE CLASS Flammable liquid storage.
3 8 EXPOSURE CONTROLS/PERSONAL PROTECTION PETROLEUMLPG/ GASES, LIQUEFIED, SWEETENED; PETROLEUM GAS TWA - 8 Hrs : 1000 ppm STEL - 15 Min : 1000 ppm ETHANOL WEL TWA - 8 Hrs : 1000 ppm ; 12920 mg/m 3 Ingredient Comments WEL = Workplace Exposure Limits PROTECTIVE EQUIPMENT PROCESS CONDITIONS Provide eyewash station. ENGINEERING MEASURES Provide adequate general and local exhaust ventilation. RESPIRATORY EQUIPMENT No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. HAND PROTECTION Use protective gloves. EYE PROTECTION Use eye protection. OTHER PROTECTION Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. HYGIENE MEASURES DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. Wash contaminated clothing before reuse. When using do not eat, drink or smoke.
4 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Aerosol. Colour Colourless. Odour Perfume. Solubility Soluble in water. Bulk Density Not applicable. Vapour pressure Not available. ph-value, Conc. Solution Not available. Odour Threshold, Lower Not available. Melting point ( C) Not available. Flash point Not available. Auto Ignition Temperature ( C) Not available. Partition Coefficient (N-Octanol/Water) Not available. Oxidising properties Not available. 10 STABILITY AND REACTIVITY STABILITY Stable under normal temperature conditions and recommended use. CONDITIONS TO AVOID Avoid heat, flames and other sources of ignition. Avoid contact with: Strong oxidising agents. Strong alkalis. Strong mineral acids. MATERIALS TO AVOID Flammable/combustible material. HAZARDOUS DECOMPOSITION PRODUCTS Fire creates: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). 11 TOXICOLOGICAL INFORMATION INHALATION No specific health warnings noted. TOXICOLOGIAI INFOREMATION Any product-specific data is not recorded. SKIN CONTACT Skin irritation is not anticipated when used normally. EYE CONTACT May cause temporary eye irritation. OTHER HEALTH EFFECTS This substance has no evidence of carcinogenic properties. ROUTE OF ENTRY Inhalation.
5 12 ECOLOGICAL INFORMATION ECOTOXICITY Not regarded as dangerous for the environment. TOXICITY No data available. PERSISTENCE AND DEGRADABILITY There are no data on the degradability of this product. Bioaccumulative potential No data available on bioaccumulation. Partition coefficient Not available. MOBILITY The product is partly soluble in water. May spread in the aquatic environment. RESULTS OF PBT AND VPVB ASSESMENT This product does not contain any PBT or vpvb substances. OTHER ANDVERSE EFFECT None known. 13 DISPOSAL CONSIDERATIONS GENERAL INFORMATION The packaging must be empty (drop-free, when inverted) Do not puncture or incinerate even when empty. DISPOSAL METHODS Empty containers must not be burned because of explosion hazard. Dispose of waste and residues in accordance with local authority requirements. Do not allow runoff to sewer, waterway or ground. Make sure containers are empty before discarding (explosion risk). Do not re-use empty containers. Please recycle empty packaging 14 TRANSPORT INFORMATION UK ROAD CLASS 2 PROPER SHIPPING NAME AEROSOLS UN NO. ROAD 1950 UK ROAD PACK GR. N/A ADR CLASS NO. 2 ADR CLASS Class 2: Gases ADR PACK GROUP 5 0 F TUNNEL RESTRICTION ( D ) CODE ADR LABEL NO. 2.1 CEFIC TEC(R) NO. 20G5F RID CLASS NO. 2 RID PACK GROUP N/A UN NO. SEA 1950 IMDG CLASS 2.1 IMDG PACK GR. N/A EMS F-D, S-U MFAG. See Subsection 4.2 of UN NO. AIR 1950 AIR CLASS 2.1 AIR PACK GR. N/A
6 15 REGULATORY INFORMATION LABELLING F + Extremely Flammable RISK PHRASES R12 Extremely flammable. SAFETY PHRASES S2 Keep out of the reach of children. S16 Keep away from sources of ignition - No smoking. S23 Do not breathe vapour/spray. S51 Use only in well ventilated areas. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. APPROVED CODE OF PRACTICE Classification and Labelling of Substances and Preparations Dangerous for Supply. GUIDANCE NOTES Workplace Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37. CHIP for everyone HSG(108). 16 OTHER INFORMATION RISK PHRASES IN FULL R12 Extremely flammable. R11 Highly flammable H224 Extremely flammable liquid and vapour. R50 Very toxic to aquatic organisms. H225 Highly flammable liquid and vapour. DATE 07.12.2012