MATERIAL SAFETY DATA SHEET FOR COATINGS, RESINS & RELATED MATERIALS SECTION I PRODUCT IDENTIFICATION Manufacturer: Ennis Paint, Inc. Information Ph: 800-331-8118 P.O. Box 404 Emergency Ph: 800-424-9300 Ennis, Texas 75120 Revised: 3/17/04 Product Class: Solution of pigmented alkylsulfonic acid esters containing organic peroxides for polymer initiator in Road Markings. This MSDS covers Component B for the 4:1 ratio materials Duraset 2, 3, 4, and 5. Trade Name: C.A.S. Number: UN/ID Number: CLASS: PACKING GROUP: Duraset Part B 4:1 Mixture NOI (Paint Related Material) HAZARD RATINGS HMIS/NFPA: HEALTH 2 -EXTREME FIRE 2 0-4 PHYSICAL HAZARD 2 SECTION II HAZARDOUS INGREDIENTS WEIGHT--------------Exposure Limits ---------------- VP INGREDIENTS CAS # % ACGIH/TLV OSHA/PEL hpa Dibenzoyl peroxide 94-36-0 2-9 5.0 mg/m³ 5.0 mg/m³ not determined Dicyclohexyl phthalate 84-61-7 2-9 5.0 mg/m³ 5.0 mg/m³ not determined SECTION III PHYSICAL DATA BOILING RANGE: 392 F VAPOR DENSITY: Not Available EVAPORATION RATE: Not Available LIQUID DENSITY: 1.7-2.1 kg/l @ 20 C APPEARANCE: Colored Heavy Liquid V.O.C. <150 g/l / 1.3 lbs/gal MELTING POINT: < -15 C ODOR THRESHOLD: Odorless SECTION IV FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASS: ORGANIC PEROXIDE Lower Explosion Limit: FLASHPOINT: (ISO 2592) 210-240 C Upper Explosion Limit: Ignition Temp: 425 C Auto Ignition Temp: Page: 1
EXTINGUISHING MEDIA: WATER, FOG, FOAM, DRY CHEMICAL, OR CARBON DIOXIDE SPECIAL FIREFIGHTING PROCEDURES: EVACUATE ENCLOSED AND SURROUNDING AREAS. AS IN ANY FIRE, WEAR SELF- CONTAINED BREATHING APPARATUS PRESSURE DEMAND. MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR. USE WATER SPRAY TO COOL CONTAINERS EXPOSED TO FIRE AND DISPERSE VAPORS. KEEP SPILLS AWAY FROM SOURCES OF IGNITION. UNUSUAL FIRE & EXPLOSION HAZARDS: KEEP CONTAINERS TIGHTLY CLOSED TOXIC AND FLAMMABLE VAPOR MAY BE PRODUCED UNDER COMBUSTION. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. ISOLATE FROM HEAT, SPARKS AND OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. SECTION V HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE: SEVERE EYE AND RESPIRATORY IRRITATION MAY OCCUR. HEADACHES, DIZZINESS AND/OR NAUSEA. SKIN CONTACT MAY CAUSE IRRITATION. NO EXPECTED TOXIC EFFECTS BY INGESTION, INHALATION, OF FUMES OR VAPORS. NO CHRONIS (LONG TERM) EFFECTS ARE KNOWN TO HUMANS AGGRAVATED MEDICAL CONDITIONS ARE BUT NOT LIMITED TO CONJUNCTIVITIS OF THE EYE, DERMATITIS OF THE SKIN, ASTHMA, AND RESPIRATORY DISEASES. FIRST AID: EYES: FLUSH THOROUGHLY WITH WATER FOR AT LEAST 20 MINUTES, LIFTING UPPER AND LOWER LIDS OCCASIONALLY. GET IMMEDIATE MEDICAL ATTENTION. DO NOT ATTEMPT TO NEUTRALIZE WITH CHEMICAL AGENTS. DO NOT WEAR CONTACT LENSES WHILE USING THIS PRODUCT. SKIN: WASH EXPOSED AREAS WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. DO NOT ATTEMPT TO NEUTRALIZE WITH CHEMICAL AGENTS. OBTAIN MEDICAL ADVICE IF IRRITATION OCCURS. INHALATION: MOVE VICTIM AWAY FROM SOURCE OF EXPOSURE AND INTO FRESH AIR. IF SYMPTOMS OF EXPOSURE DEVELOP, GET MEDICAL ATTENTION. INGESTION: IF SWALLOWED, IMMEDIATELY GIVE SEVERAL GLASSES OF WATER. CALL POISON CONTROL CENTER OR DOCTOR IMMEDIATELY. DO NOT INDUCE VOMITING. IF VOMITING OCCURS< KEEP HEAD BELOW HIPS TO AVOID ASPIRATION, GIVE FLUIDS AGAIN. TOXICOLOGICAL INFORMATION: THERE IS NO DATA AVAILABLE FOR THE PRODUCT AS SUCH. AVOID ANY CONTACT WITH THE SKIN, EYES, AND INHALATION OF THE PRODUCT VAPORS. Page: 2
SECTION VI REACTIVITY DATA STABILITY STABLE AT AMBIENT TEMPERATURES, BUT MAY DECOMPOSE IF EXPOSED TO TEMPERATURES ABOVE 131 F. OXIDES OF CARBON AND BIPHENYL ARE PRODUCED DURING THE DECOMPOSITION OF THIS PRODUCT. FLAMMABLE GASSES AND VAPORS MAY ALSO BE PRODUCED DURING THERMAL DECOMPOSITION. CONDITIONS TO AVOID THE SADT FOR THIS PRODUCT IS 140 F. THE SADT (SELF ACCELERATING DECOMPOSITION TEMPERATURE) IS AN EXPERIMENTALLY DERIVED TEMPERATURE AT WHICH A TYPICAL PACKAGE WILL UNDERGO SELF ACCELERATING DECOMPOSITION. DECOMPOSITION CAN BE UNCONTROLLABLE AND HAZARDOUS. INCOMPATIBILITY (MATERIALS TO AVOID) STRONG ACIDS, STRONG OXIDIZERS, STRONG BASES, METAL SALTS, REDUCING AGENTS AND ACCELERATORS. HAZARDOUS POLYMERIZATION MAY OCCUR WHEN EXPOSED TO EXCESSIVE HEATING OR CONTAMINATED WITH INCOMPATIBLE MATERIALS. SECTION VII SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: REMOVE SOURCES OF HEAT, SPARKS, FIRE OR OPEN FLAME. COLLECT IN A CLOSED CHEMICAL WASTE CONTAINER. ADSORB SPILL WITH INERT MATERIAL. AVOID HOT METAL SURFACES. WASTE DISPOSAL METHOD: Dispose of in accordance with local, state and federal regulations. Incineration if the preferred method. Empty containers must be handled with care due to product residue. DO NOT HEAT, WELD OR CUT THE EMPTY CONTAINERS WITH ELECTRIC OR GAS TORCH. DO NOT REUSE CONTAINERS. Avoid discharge to soil, waterways or wastewater. SECTION VIII SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: WEAR APPROPRIATE, PROPERLY FITTED RESPIRATOR (NIOSH/MSHA APPROVED) DURING SPRAYING APPLICATION TO PROTECT AGAINST OVERSPRAY. VENTILATION: ADEQUATE VENTILATION IS NECESSARY WHEN SPRAYING OR MIXING AND EXHAUST WITH PROPER AIRFLOW IS ALWAYS RECOMMENDED. AVOID ANY DIRECT INHALATION OF SPRAY MIST IF THIS PRODUCT IS SPRAYED. Page: 3
PROTECTION GLOVES: IN PERMEATION TESTS, BUTYL AND NITRILE RUBBER GLOVES PERFORM BETTER THAN LATEX. GLOVES SHOULD BE REPLACED FREQUENTLY. EYE PROTECTION: CLOSE FITTING SAFETY GOGGLES. OTHER PROTECTIVE EQUIPMENT: MAY ADHERE TO SKIN - GLOVES, LONG SLEEVES, HATS AND FACE SHIELDS ARE STRONGLY RECOMMENDED. TRAIN AND EDUCATE EMPLOYEES IN THE SAFE USE OF THE PRODUCT. SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: DO NOT STORE AT TEMPERATURES ABOVE 131 F UNDER ANY CIRCUMSTANCES. PROTECT CONTAINERS AGAINST PHYSICAL DAMAGE. GROUND ALL EQUIPMENT TO REDUCE STATIC ELECTRICITY HAZARD. DO NOT APPLY TO HOT SURFACES OR USE IN AREAS EXPOSED TO ELECTRIC SPARKS. KEEP AWAY FROM HEAT AND OPEN FLAMES. KEEP CONTAINERS CLOSED WHEN NOT IN USE. ENSURE AREA IS WELL VENTILATED SECTION X ADDITIONAL REGULATORY INFORMATION SARA TITLE III SECTION 313: THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW ACT OF 1986 AND OF 40 CFR 372: 94-36-0 Dibenzoyl peroxide 9 MAX PROP 65 (CARCINOGEN): TO CAUSE CANCER. PROP 65 (TERATOGEN): TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. PROP 65 (BOTH CARCINOGEN AND TERATOGEN): TO CAUSE CANCER OR BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. Page: 4
TSCA-U.S. TOXIC SUBSTANCES CONTROL ACT: ALL COMPONENTS OF THIS MIXTURE ARE IN COMPLIANCE WITH THE INVENTORY LISTING REQUIREMENTS OF THE U.S. TOXIC SUBSTANCES CONTROL ACT (TSCA) CHEMICAL SUBSTANCES INVENTORY. SECTION XI MISCELLANEOUS INFORMATION THE INFORMATION OFFERED HEREIN IS, TO THE BEST OF OUR KNOWLEDGE, TRUE AND ACCURATE, BUT ALL RECOMMENDATIONS ARE MADE WITHOUT WARRANTY, EXPRESS OR IMPLIED, SINCE THE CONDITIONS OF USE ARE BEYOND OUR CONTROL, NEITHER ENNIS PAINT, INC., NOR ITS AGENTS SHALL BE LIABLE FOR ANY INJURY, LOSS OR DAMAGE, DIRECT OR CONSEQUENTIAL, ARISING FROM THE USE OR THE INABILITY TO USE THE PRODUCT DESCRIBED HEREIN. NO PERSON IS AUTHORIZED TO MAKE ANY STATEMENT OR RECOMMENDATION NOT CONTAINED IN THE MATERIAL DATA SHEET, AND ANY SUCH STATEMENT OR RECOMMENDATION, IF MADE SHALL NOT BIND THE CORPORATION. Page: 5