Page n. 23 45 61 / 06 Safety Data Sheet 12.5. Precautionary of Initial 4. large Regulation Results boiling quantities of point. (EC) PBT statements: of 1272/2008 and fume. vpvb assessment. (CLP) of the European Not Parliament available. 5. Boiling Information Regulation P264range. not (EC) available. 790/2009 Wash..(I. Atp. thoroughly CLP) of after the handling. European Parliament P280 Wear protective gloves / protective clothing / eye protection / face protection. 6. Flash 6. Accidental Regulation point. release (EC) 453/2010 measures. of the European Parliament > 60 C. 1. Identification P305+P351+P338 of the IF IN substance/mixture EYES: Rinse cautiously and with of the water company/undertaking 12.6. 7. Evaporation The Other Merck adverse Rate Index. effects. - 10th Edition for several minutes. Remove contact lenses, if present and easy to do. Continue 6.1. rinsing. 1.1. 8. Information Flammability Personal Product Handling identifier precautions, not Chemical of available. solids Safety and protective gases equipment and Not emergency available. procedures. 9. Lower P337+P313 If eye irritation persists: Get medical advice / attention. Use Niosh breathing inflammability - Registry equipment of limit. Toxic Effects if fumes of Chemical or powders Substances are Not released available. into the air. These indications apply for both processing staff and those involved in 13. 10. Product Upper emergency Disposal INRS inflammability name - Fiche procedures. considerations. Toxicologique limit. (toxicological sheet) Not available. 2.3. 11. Other hazards. INDEX Lower Patty explosive number - Industrial limit. Hygiene and Toxicology Not - available. 13.1. 6.2. 12. EC Upper Environmental Waste number N.I. explosive Sax treatment - Dangerous limit. precautions. methods. properties of Industrial Materials-7, Not - available. 1989 Edition Information 13. not available. Reuse, CAS Vapour The ECHA product number pressure. when website must possible. not penetrate Product the residues sewers, surface should Not -be water, available. considered ground water special and hazardous neighbouring waste. areas. The hazard level of waste containing this product should Vapour be density evaluated according to applicable regulations. 1.2. 6.3. Disposal Specific Composition/information Relevant Methods gravity. must and identified be material performed uses of containment through the ingredients. substance authorised and cleaning mixture waste up. and management uses advised firm, against compliance with national and local regulations. Note CONTAMINATED Solubility Confine for users: using earth PACKAGING or inert material. Collect as Not much available. material as possible and eliminate the rest using jets of water. Contaminated material 3.1. The Substances. Intended Contaminated Partition should information be coefficient: use disposed packaging contained of n-octanol/water compliance must in be the recovered present with the or sheet provisions disposed are Not DSE set available. based of forth in EDGE compliance on in point PAINT our own 13. with - VERNICE knowledge national TINGOBORDO waste on the management date DSA of the regulations. last version. Users must verify the suitability Ignition temperature. and thoroughness of provided information Not according available. to each specific use of the product. Contains: 1.3. 6.4. This Decomposition Reference to temperature. other sections. 14. Transport Details document of the must information. supplier not be of regarded the safety as data a guarantee sheet on any specific product property. Any The Viscosity information use of this on product personal is protection not subject and to disposal our direct Not is control; given available. in therefore, sections 8 users and 13. must, under their own responsibility, comply with the current health and Identification. Reactive Properties Conc. %. Classification Not 67/548/EEC. available. Classification 1272/2008 (CLP). The safety product laws is and not regulations. dangerous The under producer current is provisions relieved from of the any Code liability of International arising from improper Carriage uses. of Dangerous Goods by Road (ADR) and by Rail 7. Name (RID), Handling of the and International storage. Maritime Dangerous Goods GIARDINI Code (IMDG), DI GIARDINI and of ANGELO the International & C. SNC Air Transport Association (IATA) regulations. 9.2. Changes ETHOXYLATED FATTY ALCOHOL, 5-20 EO Full Other address information. to previous review: Via Breda, scn CAS. - 7.1. The VOC Precautions (Directive 1999/13/EC) safe handling. : 0,83 % 15. District following EC. Regulatory and Country sections were modified: - information. 62012 Civitanova Marche (MC) 02 Before VOC / 03 (volatile handling / 04 / 08 carbon) / the 09 product, / 11 : / 13 consult / 15 / 16. all the other sections 0 of this ITALIA material safety data sheet. Do not eat, drink or smoke during use. INDEX. - Tel. +39 0733 897878 7.2. 15.1. 10. T+ Stability Conditions = Safety, Very Toxic(T+), health and for T reactivity. safe = and Toxic(T), storage, environmental Xn = Harmful(Xn), including regulations/legislation C = any Corrosive(C), incompatibilities. Fax Xi = Irritant(Xi), +39 specific 0733 O = Oxidizing(O), 897886 for the E substance = Explosive(E), or F+ mixture. = Extremely Flammable(F+), F = Highly Flammable(F), N = Dangerous Normal e-mail address storage for the Environment(N) of conditions the competent without person particular incompatibilities. 10.1. Seveso responsible Reactivity. category. for the Safety Data Sheet msds@giardinigroup.it 7.3. There Specific full are wording no end particular use(s). of the Risk risks (R) of reaction and hazard with (H) other phrases substances is given in in normal section conditions 16 of the of sheet. use. 1.4. Restrictions Information Emergency relating not telephone available. to the product number or contained substances pursuant to Annex XVII to EC Regulation 1907/2006. 10.2. 3.2. Mixtures. Chemical stability. The 8. For Exposure urgent product inquiries is stable controls/personal refer in normal to conditions of use and protection. +39 storage. 0733 897878 Information not relevant. 8.1. 10.3. 2. Substances Hazards Control Possibility parameters. identification. in Candidate of hazardous List (Art. reactions. 59 REACH). 4. Information hazardous First aid measures. not reactions available. are foreseeable in normal conditions of use and storage. 4.1. 8.2. 2.1. 10.4. Description Exposure Classification Conditions controls. of to of first avoid. the aid substance measures. or mixture. Substances EYES: None in Irrigate particular, subject copiously however to authorisarion with the clean, usual (Annex fresh precautions XIV water REACH). for used at least for chemical 15 minutes. products Seek medical should be advice. respected. As SKIN: The the product use Wash of is adequate immediately classified technical as hazardous with equipment plenty pursuant of must water. to always the Remove provisions take contaminated priority set forth over in personal clothing. Directives protection If 67/548/EEC irritation equipment, persists, and 1999/45/EC make seek sure medical and/or that attention. the EC workplace Regulation Wash is 10.5. 1272/2008 contaminated well Incompatible aired through (CLP) clothing materials. effective (and before subsequent local using aspiration. them amendments again. Personal and protection supplements). equipment The must product comply thus with requires the rules a in safety force indicated datasheet below. that complies with the provisions HAND INHALATION: Information PROTECTION of not Remove available. Regulation to open 1907/2006 air. If breathing and subsequent is irregular, amendments. seek medical advice. Healthcare controls. Any Protect INGESTION: additional hands Obtain information with category immediate concerning I (ref. medical the Directive risks attention. for 89/686/EEC health Induce and/or vomiting and the standard environment only if indicated 374) are given work by gloves, in the sections doctor. such 11 as and Never those 12 give of in latex, this anything sheet. PVC or by equivalent. mouth to The an 10.6. unconscious Workers following Hazardous exposed should person. decomposition be to considered this chemical products. when agent choosing must not work undergo glove material: health checks, degradation, provided breakage that available times and risk-assessment permeation. Work data prove glove that resistance the risks to related preparations In the event to the of should workers' thermal be health decomposition checked and before safety or use, are fire, modest as vapours it can and be potentially that unpredictable. the dangerous 98/24/EC Gloves directive to health limit is depends may respected. be released. on the duration of exposure. 2.1.1. 4.2. EYE Most Regulation PROTECTION important 1272/2008 symptoms (CLP) and and effects, following both amendments acute and delayed. and adjustments. 15.2. 11. For Wear Toxicological Chemical symptoms protective safety and airtight information. effects assessment. goggles caused (ref. by standard the contained 166). substances see chap. 11. Hazard SKIN PROTECTION classification and indication: 4.3. 11.1. No Wear Indication Information chemical category Eye Irrit. of safety any on I 2 professional toxicological assessment immediate H319medical long-sleeved has effects. been attention processed overalls and for and special the mixture safety treatment footwear and the needed. substances (ref. Directive it contains. 89/686/CEE and standard 344). Wash body with Acute soap Information and effects: water not stinging available. after removing eyes. Symptoms overalls. may include: rubescence, edema, pain and lachrymation. 2.1.2. 16. RESPIRATORY Vapour Other Directive inhalation information. 67/548/EEC PROTECTION may moderately and following irritate amendments the upper respiratory and adjustments. trait. Contact with skin may cause slight irritation. 5. If Ingestion Firefighting the threshold may cause measures. value health (if available) problems, for including one or stomach more pain of the and substances sting, nausea present and sickness. in the preparation for daily exposure in the workplace or to a Danger Text fraction of hazard Symbols: established (H) indications by the company s mentioned -- in prevention section 2-3 and of the protection sheet: service is exceeded, wear a mask with an A or universal filter, the class (1, 2 5.1. R Information Extinguishing phrases: 3) of which not must available. media. be chosen according -- to the limit concentration of use (ref. standard 141). SUITABLE The Acute use Tox. of EXTINGUISHING respiratory 4 Acute tract toxicity, MEDIA protection category equipment, 4 such as masks like that indicated above, is necessary to reduce worker exposure in the Eye Dam. 1 2.2. 12. The absence Ecological Label extinction elements. of technical Serious equipment measures. eye should The damage, be of protection category the conventional provided 1 information. kind: by masks carbon is dioxide, in any case foam, limited. powder and nebulised water. Eye Irrit. 2 Eye irritation, category 2 EXTINGUISHING If the substance MEDIA in question WHICH is SHALL odourless NOT or BE its USED olfactory FOR threshold SAFETY is higher REASONS than the relative exposure limit and in the event of an emergency, H302 Harmful if swallowed. Use or None Hazard when this in labelling particular. exposure product pursuant according levels to are EC to unknown Regulation good working 1272/2008 the practices. concentration (CLP) Avoid and littering. of subsequent oxygen Inform in amendments the competent workplace and authorities, is supplements. less than should 17% the volume, product wear reach self-contained, waterways or H318 Causes serious eye damage. open-circuit sewers H319 or contaminate compressed Causes soil air or serious vegetation. breathing eye apparatus irritation. (ref. standard 137) or fresh air hose breathing apparatus for use with full face mask, half 5.2. mask Hazard Special or pictograms: mouthpiece hazards arising (ref. standard from the substance 138). or mixture. 12.1. Text HAZARDS Toxicity. of risk CAUSED (R) phrases BY mentioned EXPOSURE in section IN THE 2-3 EVT of the OF sheet: FIRE 9. Do Information Physical not breathe and not combustion available. chemical properties. products (carbon oxide, toxic pyrolysis products, etc). R22 HARMFUL IF SWALLOWED. 5.3. 9.1. 12.2. Advice Information Persistence R41 firefighters. on and basic degradability. RISK physical OF SERIOUS and chemical DAMAGE properties. TO EYES. Appearance GERAL Information INFORMATION not available. liquid Use Colour jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for 12.3. GERAL health. Odour Bioaccumulative Always BIBLIOGRAPHY wear potential. full fire prevention gear. Collect odourless extinguishing water to prevent it from draining into the sewer system. Dispose of Signal 1. contaminated Odour Information Directive threshold. words: 1999/45/EC not water available. used Warning and for following extinction amendments and the remains Not of available. the fire according to applicable regulations. SPECIAL 2. ph. Directive PROTECTIVE 67/548/EEC and EQUIPMT following amendments FOR FIRE-FIGHTERS Not and available. adjustments 12.4. Hardhat Hazard 3. Melting Regulation Mobility statements: or with freezing (EC) soil. visor, point. 1907/2006 fireproof (REACH) clothing (fireproof of the European jacket Parliament and trousers with straps around arms, legs and waist), work gloves (fireproof, cut proof and Information H319 antistatic), not available. a depressurised Causes serious mask eye irritation. with facemask covering the whole of the operator s face or a self-respirator (self-protector) in the event
Page n. 2 / 6 Precautionary statements: P264 Wash... thoroughly after handling. P280 Wear protective gloves / protective clothing / eye protection / face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 If eye irritation persists: Get medical advice / attention. 2.3. Other hazards. 3. Composition/information on ingredients. 3.1. Substances. Contains: Identification. Conc. %. Classification 67/548/EEC. Classification 1272/2008 (CLP). ETHOXYLATED FATTY ALCOHOL, 5-20 EO CAS. - EC. - INDEX. - T+ = Very Toxic(T+), T = Toxic(T), Xn = Harmful(Xn), C = Corrosive(C), Xi = Irritant(Xi), O = Oxidizing(O), E = Explosive(E), F+ = Extremely Flammable(F+), F = Highly Flammable(F), N = Dangerous for the Environment(N) The full wording of the Risk (R) and hazard (H) phrases is given in section 16 of the sheet. 3.2. Mixtures. Information not relevant. 4. First aid measures. 4.1. Description of first aid measures. EYES: Irrigate copiously with clean, fresh water for at least 15 minutes. Seek medical advice. SKIN: Wash immediately with plenty of water. Remove contaminated clothing. If irritation persists, seek medical attention. Wash contaminated clothing before using them again. INHALATION: Remove to open air. If breathing is irregular, seek medical advice. INGESTION: Obtain immediate medical attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects, both acute and delayed. For symptoms and effects caused by the contained substances see chap. 11. 4.3. Indication of any immediate medical attention and special treatment needed. 5. Firefighting measures. 5.1. Extinguishing media. SUITABLE EXTINGUISHING MEDIA The extinction equipment should be of the conventional kind: carbon dioxide, foam, powder and nebulised water. EXTINGUISHING MEDIA WHICH SHALL NOT BE USED FOR SAFETY REASONS None in particular. 5.2. Special hazards arising from the substance or mixture. HAZARDS CAUSED BY EXPOSURE IN THE EVT OF FIRE Do not breathe combustion products (carbon oxide, toxic pyrolysis products, etc). 5.3. Advice for firefighters. GERAL INFORMATION Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health. Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water used for extinction and the remains of the fire according to applicable regulations. SPECIAL PROTECTIVE EQUIPMT FOR FIRE-FIGHTERS Hardhat with visor, fireproof clothing (fireproof jacket and trousers with straps around arms, legs and waist), work gloves (fireproof, cut proof and antistatic), a depressurised mask with facemask covering the whole of the operator s face or a self-respirator (self-protector) in the event
Page n. 3 / 6 of large quantities of fume. 6. Accidental release measures. 6.1. Personal precautions, protective equipment and emergency procedures. Use breathing equipment if fumes or powders are released into the air. These indications apply for both processing staff and those involved in emergency procedures. 6.2. Environmental precautions. The product must not penetrate the sewers, surface water, ground water and neighbouring areas. 6.3. Methods and material for containment and cleaning up. Confine using earth or inert material. Collect as much material as possible and eliminate the rest using jets of water. Contaminated material should be disposed of in compliance with the provisions set forth in point 13. 6.4. Reference to other sections. Any information on personal protection and disposal is given in sections 8 and 13. 7. Handling and storage. 7.1. Precautions for safe handling. Before handling the product, consult all the other sections of this material safety data sheet. Do not eat, drink or smoke during use. 7.2. Conditions for safe storage, including any incompatibilities. Normal storage conditions without particular incompatibilities. 7.3. Specific end use(s). 8. Exposure controls/personal protection. 8.1. Control parameters. 8.2. Exposure controls. As the use of adequate technical equipment must always take priority over personal protection equipment, make sure that the workplace is well aired through effective local aspiration. Personal protection equipment must comply with the rules in force indicated below. HAND PROTECTION Protect hands with category I (ref. Directive 89/686/EEC and standard 374) work gloves, such as those in latex, PVC or equivalent. The following should be considered when choosing work glove material: degradation, breakage times and permeation. Work glove resistance to preparations should be checked before use, as it can be unpredictable. Gloves limit depends on the duration of exposure. EYE PROTECTION Wear protective airtight goggles (ref. standard 166). SKIN PROTECTION Wear category I professional long-sleeved overalls and safety footwear (ref. Directive 89/686/CEE and standard 344). Wash body with soap and water after removing overalls. RESPIRATORY PROTECTION If the threshold value (if available) for one or more of the substances present in the preparation for daily exposure in the workplace or to a fraction established by the company s prevention and protection service is exceeded, wear a mask with an A or universal filter, the class (1, 2 or 3) of which must be chosen according to the limit concentration of use (ref. standard 141). The use of respiratory tract protection equipment, such as masks like that indicated above, is necessary to reduce worker exposure in the absence of technical measures. The protection provided by masks is in any case limited. If the substance in question is odourless or its olfactory threshold is higher than the relative exposure limit and in the event of an emergency, or when exposure levels are unknown or the concentration of oxygen in the workplace is less than 17% volume, wear self-contained, open-circuit compressed air breathing apparatus (ref. standard 137) or fresh air hose breathing apparatus for use with full face mask, half mask or mouthpiece (ref. standard 138). 9. Physical and chemical properties. 9.1. Information on basic physical and chemical properties. Appearance liquid Colour Odour odourless Odour threshold. ph. Melting or freezing point.
Page n. 4 / 6 Initial boiling point. Boiling range. Flash point. > 60 C. Evaporation Rate Flammability of solids and gases Lower inflammability limit. Upper inflammability limit. Lower explosive limit. Upper explosive limit. Vapour pressure. Vapour density Specific gravity. Solubility Partition coefficient: n-octanol/water Ignition temperature. Decomposition temperature. Viscosity Reactive Properties 9.2. Other information. VOC (Directive 1999/13/EC) : 0,83 % VOC (volatile carbon) : 0 10. Stability and reactivity. 10.1. Reactivity. There are no particular risks of reaction with other substances in normal conditions of use. 10.2. Chemical stability. The product is stable in normal conditions of use and storage. 10.3. Possibility of hazardous reactions. No hazardous reactions are foreseeable in normal conditions of use and storage. 10.4. Conditions to avoid. None in particular, however the usual precautions used for chemical products should be respected. 10.5. Incompatible materials. 10.6. Hazardous decomposition products. In the event of thermal decomposition or fire, vapours potentially dangerous to health may be released. 11. Toxicological information. 11.1. Information on toxicological effects. Acute effects: stinging eyes. Symptoms may include: rubescence, edema, pain and lachrymation. Vapour inhalation may moderately irritate the upper respiratory trait. Contact with skin may cause slight irritation. Ingestion may cause health problems, including stomach pain and sting, nausea and sickness. 12. Ecological information. Use this product according to good working practices. Avoid littering. Inform the competent authorities, should the product reach waterways or sewers or contaminate soil or vegetation. 12.1. Toxicity. 12.2. Persistence and degradability. 12.3. Bioaccumulative potential. 12.4. Mobility in soil.
Page n. 5 / 6 12.5. Results of PBT and vpvb assessment. 12.6. Other adverse effects. 13. Disposal considerations. 13.1. Waste treatment methods. Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should be evaluated according to applicable regulations. Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations. CONTAMINATED PACKAGING Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations. 14. Transport information. The product is not dangerous under current provisions of the Code of International Carriage of Dangerous Goods by Road (ADR) and by Rail (RID), of the International Maritime Dangerous Goods Code (IMDG), and of the International Air Transport Association (IATA) regulations. 15. Regulatory information. 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture. Seveso category. Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006. Substances in Candidate List (Art. 59 REACH). Substances subject to authorisarion (Annex XIV REACH). Healthcare controls. Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks related to the workers' health and safety are modest and that the 98/24/EC directive is respected. 15.2. Chemical safety assessment. No chemical safety assessment has been processed for the mixture and the substances it contains. 16. Other information. Text of hazard (H) indications mentioned in section 2-3 of the sheet: Acute Tox. 4 Acute toxicity, category 4 Eye Dam. 1 Serious eye damage, category 1 Eye Irrit. 2 Eye irritation, category 2 H302 Harmful if swallowed. H318 Causes serious eye damage. H319 Causes serious eye irritation. Text of risk (R) phrases mentioned in section 2-3 of the sheet: R22 R41 HARMFUL IF SWALLOWED. RISK OF SERIOUS DAMAGE TO EYES. GERAL BIBLIOGRAPHY 1. Directive 1999/45/EC and following amendments 2. Directive 67/548/EEC and following amendments and adjustments 3. Regulation (EC) 1907/2006 (REACH) of the European Parliament
Page n. 6 / 6 4. Regulation (EC) 1272/2008 (CLP) of the European Parliament 5. Regulation (EC) 790/2009 (I Atp. CLP) of the European Parliament 6. Regulation (EC) 453/2010 of the European Parliament 7. The Merck Index. - 10th Edition 8. Handling Chemical Safety 9. Niosh - Registry of Toxic Effects of Chemical Substances 10. INRS - Fiche Toxicologique (toxicological sheet) 11. Patty - Industrial Hygiene and Toxicology 12. N.I. Sax - Dangerous properties of Industrial Materials-7, 1989 Edition 13. ECHA website Note for users: The information contained in the present sheet are based on our own knowledge on the date of the last version. Users must verify the suitability and thoroughness of provided information according to each specific use of the product. This document must not be regarded as a guarantee on any specific product property. The use of this product is not subject to our direct control; therefore, users must, under their own responsibility, comply with the current health and safety laws and regulations. The producer is relieved from any liability arising from improper uses. Changes to previous review: The following sections were modified: 02 / 03 / 04 / 08 / 09 / 11 / 13 / 15 / 16.