Revision Date 15/04/2011 Supersedes date 15/02/11 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identfer Product name Product No. JAN60O, JAN76V, JAN84U 1.2. Relevant identfed uses of the substance or mixture and uses advised against Identfed uses Detergent. 1.3. Details of the supplier of the safety data sheet Supplier 1.4. Emergency telephone number DEB Denby Hall Way Denby Derbyshire DE5 8JZ Main Tel. 01773855100 Technical Tel 01773855105 reach@deb.co.uk Natonal Poisons Informaton Service 0844 8920111 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classifcaton of the substance or mixture Classifcaton (1999/45/EEC) 2.2. Label elements Xi;R36. Detergent Labelling Labelling 5 - < 15% phosphates < 5% anionic surfactants non-ionic surfactants Risk Phrases Safety Phrases 2.3. Other hazards Irritant R36 S2 S25 S26 S46 S64 This product does not contain any PBT or vpvb substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Irritatng to eyes. Keep out of the reach of children. Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If swallowed, seek medical advice immediately and show this container or label. If swallowed, rinse mouth with water (only if the person is conscious). 1 / 6
3.2. Mixtures TETRAPOTASSIUM PYROPHOSPHATE 5-10% CAS-No.: 7320-34-5 EC No.: 230-785-7 Eye Irrit. 2 - H319 Xi;R36. BENZENE SULPHONIC ACID, C10-13-ALKYL DERIVS., SODIUM SALTS 1-5% CAS-No.: 68411-30-3 EC No.: 270-115-0 Acute Tox. 4 - H302 Skin Irrit. 2 - H315 Eye Dam. 1 - H318 Xn;R22. Xi;R38,R41. ISOTRIDECANOL, ETHOXYLATED 6.5 MOL EO 1-5% CAS-No.: 69011-36-5 EC No.: Acute Tox. 4 - H302 Eye Dam. 1 - H318 Xn;R22. Xi;R41. ARYL ETHER PHOSPHATE ESTER, POTASSIUM SALT 1-5% CAS-No.: 72283-31-9 EC No.: Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Xi;R36/38. The Full Text for all R-Phrases and Hazard Statements are Displayed in Secton 16. SECTION 4: FIRST AID MEASURES 4.1. Descripton of frst aid measures Inhalaton Not relevant Unlikely route of exposure as the product does not contain volatle substances. Ingeston Rinse mouth thoroughly. Get medical atenton if any discomfort contnues. Skin contact Eye contact Make sure to remove any contact lenses from the eyes before rinsing. Important! Immediately rinse with water for at least 15 minutes. Get medical atenton if any discomfort contnues. 4.2. Most important symptoms and efects, both acute and delayed Inhalaton. No specifc symptoms noted. Ingeston No specifc symptoms noted. Eye contact Irritaton of eyes and mucous membranes. 4.3. Indicaton of any immediate medical atenton and special treatment needed No specifc frst aid measures noted. 2 / 6
SECTION 5: FIREFIGHTING MEASURES 5.1. Extnguishing media Extnguishing media This product is not fammable. Use fre-extnguishing media appropriate for surrounding materials. 5.2. Special hazards arising from the substance or mixture Hazardous combuston products No hazardous decompositon products. 5.3. Advice for frefghters Special Fire Fightng Procedures No specifc fre fghtng procedure given. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautons, protectve equipment and emergency procedures Wear protectve clothing as described in Secton 8 of this safety data sheet. Avoid contact with eyes. 6.2. Environmental precautons Not relevant considering the small amounts used. 6.3. Methods and material for containment and cleaning up Flush away small spillages with plenty of water. Do not let washing down water contaminate ponds or waterways. Large quanttes should not be discharged into the drain but removed with absorbing material. 6.4. Reference to other sectons For waste disposal, see secton 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautons for safe handling Avoid contact with eyes. 7.2. Conditons for safe storage, including any incompatbilites Store in closed original container at temperatures between 0 C and 40 C. 7.3. Specifc end use(s) The identfed uses for this product are detailed in Secton 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Ingredient Comments None. 8.2. Exposure controls Protectve equipment Engineering measures Not relevant Respiratory equipment Not relevant Eye protecton Wear eye protecton if there is a risk of this product getng in the eyes Hygiene measures Wash hands afer contact. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Informaton on basic physical and chemical propertes 3 / 6
Appearance Liquid Colour Yellow. Odour Characteristc. Solubility Soluble in water. ph-value, Conc. Soluton 10-10.5 9.2. Other informaton SECTION 10: STABILITY AND REACTIVITY 10.1. Reactvity No specifc reactvity hazards associated with this product. 10.2. Chemical stability Stable under normal temperature conditons. 10.3. Possibility of hazardous reactons Not known. 10.4. Conditons to avoid There are no known conditons that are likely to result in a hazardous situaton. 10.5. Incompatble materials Materials To Avoid No incompatble groups noted. 10.6. Hazardous decompositon products There are no antcipated hazardous decompositon products associated with this material. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Informaton on toxicological efects Inhalaton No specifc health warnings noted. Ingeston May cause discomfort if swallowed. Skin contact Skin irritaton is not antcipated when used normally. Eye contact Irritatng to eyes. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Not regarded as dangerous for the environment. 12.1. Toxicity Acute Fish Toxicity Not considered toxic to fsh. 12.2. Persistence and degradability Degradability The surfactant(s) contained in this preparaton complies(comply) with the biodegradability criteria as laid down in Regulaton (EC) No.648/2004 on detergents. Data to support this asserton are held at the disposal of the competent authorites of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. 12.3. Bioaccumulatve potental Bioaccumulatve potental No data available on bioaccumulaton. 12.4. Mobility in soil Mobility: The product is soluble in water. 12.5. Results of PBT and vpvb assessment 4 / 6
This product does not contain any PBT or vpvb substances. 12.6. Other adverse efects None known. SECTION 13: DISPOSAL CONSIDERATIONS General informaton When handling waste, consideraton should be made to the safety precautons applying to handling of the product. 13.1. Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION Road Transport Notes Rail Transport Notes Sea Transport Notes Air Transport Notes 14.1. UN number 14.2. UN proper shipping name 14.3. Transport hazard class(es) 14.4. Packing group 14.5. Environmental hazards Not Classifed Not classifed. Not classifed. Not classifed. Environmentally Hazardous Substance/Marine Pollutant No. 14.6. Special precautons for user 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION 15.1. Safety, health and environmental regulatons/legislaton specifc for the substance or mixture EU Legislaton Regulaton (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registraton, Evaluaton, Authorisaton and Restricton of Chemicals (REACH), establishing a European Chemicals Agency, amending Directve 1999/45/EC and repealing Council Regulaton (EEC) No 793/93 and Commission Regulaton (EC) No 1488/94 as well as Council Directve 76/769/EEC and Commission Directves 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulaton (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classifcaton, labelling and packaging of substances and mixtures, amending and repealing Directves 67/548/EEC and 1999/45/EC, and amending Regulaton (EC) No 1907/2006 with amendments. 15.2. Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Revision Comments New REACH Annex 2 Compliant MSDS Revision Date 15/04/2011 Supersedes date 15/02/11 5 / 6
Risk Phrases In Full R22 Harmful if swallowed. R36/38 Irritatng to eyes and skin. R36 Irritatng to eyes. R38 Irritatng to skin. R41 Risk of serious damage to eyes. Hazard Statements In Full H318 Causes serious eye damage. H319 Causes serious eye irritaton. H315 Causes skin irritaton. H302 Harmful if swallowed. Notes for Risk Phrases and Hazard Statements in Full The full text for Risk Phrases and Hazard Statements in secton 16 relates to the reference numbers in sectons 2 and 3 and not necessarily the fnished product classifcaton. Disclaimer This informaton relates only to the specifc material designated and may not be valid for such material used in combinaton with any other materials or in any process. Such informaton is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representaton is made to its accuracy, reliability or completeness. It is the user's responsibility to satsfy himself as to the suitability of such informaton for his own partcular use. 6 / 6