SAFETY DATA SHEET SECTION 1. COMPANY AND PRODUCT IDENTIFICATION Product Identifier Company Name LC0101 Liquiblack Concrete Chemicals 1065 Terminal Way San Carlos, CA 94070 Emergency Telephone Number (888) 867-5701 Product Use Pigment for Concrete and/or Pool Plaster SECTION 2. HAZARDS IDENTIFICATION Classification(s) Signal Word Hazard Statement(s) Hazard Pictograms Precautionary Statement(s) -Prevention Not hazardous. None, not hazardous. None, not hazardous. None, nor hazardous. Wash face, hands and any exposed skin thoroughly after handling. Precautionary Statement(s) -Response IF SWALLOWED: Rinse Mouth. Call a doctor if nauseous. Precautionary Statement(s) -Storage Store in a dry, well-ventilated area away from heat and direct sunlight. Store in a closed, properly labeled container. Keep out of reach of children and pets.
Precautionary Statement(s) -Disposal Dispose of contents/container to an approved waste disposal plant. SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS Ingredient CAS Number % Carbon Black 1333-86-4 20-40 Dispersant 1-20 There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. The specific chemical identity of this composition is being withheld as a trade secret. SECTION 4. FIRST AID MEASURES First Aid Measures Eye Contact Inhalation Skin Contact Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Most Important Symptoms and Effect, both Acute and Delayed Symptoms Irritation of eyes and mucous membranes. Irritation of nose and throat. Exposed individuals may experience eye tearing, redness, and discomfort. Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. May cause redness and pain. Indication of any Immediate Medical Attention and Special Treatment Needed Notes to Physician Treat Symptomatically. SECTION 5. FIRE FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Use an extinguishing agent suitable for the surrounding fire. None known. Special protective equipment and precautions for firefighters Isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fireexposed containers cool. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures Personal Precautions Use personal protective equipment as required. For Emergency Responders Restrict access to spill area. Ventilate area. Environmental Precautions Prevent entry into waterways, sewers, basements or confined areas. See section 12 for additional ecological information.
Methods and Material for Containment and Cleaning Up Methods for Containment Methods for Cleaning Up Prevent further leakage or spillage if safe to do so. For liquids, dyke and allow to dry then shovel into approved container for disposal. Powders may be swept or vacuumed. SECTION 7. HANDLING AND STORAGE Precautions on Safe Handling Advice on Safe Handling Wash face, hands, and any exposed skin thoroughly after handling. Do not eat, drink, or smoke when using this product. Avoid breathing vapors, mist or dust. Keep out of reach of children and pets. Conditions for Safe Storage, Including any Incompatibilities Storage Conditions Packaging Materials Incompatible Materials Keep containers closed in a dry, cool and well ventilated place. Protect from direct sunlight. Keep away from heat. Store away from incompatible materials. Keep in properly labeled containers. Keep out of reach of children and pets. Keep in original container. None known. SECTION 8. EXPOSURE CONTROLS / PERSOL PROTECTION Exposure Guidelines Chemical Name OSHA PEL mg/m³ ACGIH TLV mg/ m³ Carbon Black 3.5 3.0 Dispersant N/A 0.3 Appropriate Engineering Controls Engineering Controls Apply technical measures to comply with the occupational exposure limits.
Individual Protection Measures, such as Personal Protective Equipment Eye/Face Protection Skin/Body Protection Respiratory Protection General Hygiene Considerations Wear goggles or chemical safety glasses. Face protection shield. Wear water resistant gloves. Wear appropriate clothing to prevent repeated or prolonged skin contact. Wear dust mask or respirator. If acid present, use acid respirator. Handle in accordance with good industrial hygiene and safety procedures. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Information on Basic Physical and Chemical Properties Appearance Black Liquid Upper/lower flammability or explosive limits Will not explode and non-flammable Odor No odor Vapor Pressure (mmhg) Not determined Odor Threshold (ppm) Vapor Density (air = 1) Not determined PH 5.0 8.5 Relative Density 1.12 (H2O= 1) Melting Point ºC Freezing Point ºC 0 C Solubility in Water Soluble Initial boiling point and boiling range 100 C Flash point >110 C Evaporation Rate Not determined Flammability Non-flammable Partition coefficient: n-octanol/water Not Available Auto-ignition temperature Not Available Decomposition temperature See Melting Point Viscosity Not Available SECTION 10. STABILITY AND REACTIVITY Reactivity No specific test data related to reactivity available for this product or its ingredients.
Chemical Stability Possibility of Hazardous Reactions Hazardous Polymerization Conditions to Avoid Incompatible Materials Hazardous Decomposition Products The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous reactions will not occur. No specific data. Under normal conditions of storage and use, there are no incompatible materials. Under normal conditions of storage and use, there are no hazardous decomposition products. SECTION 11. TOXICOLOGICAL INFORMATION Information on Likely Routes of Exposure Ingestion Inhalation Skin Contact Eye Contact Single dose oral toxicity is considered to be extremely low. Swallowing large amounts may cause injury. Inhalation may result in lung irritation. No adverse affects. Contact with eyes causes eye irritation. Delayed and Immediate Effects as well as Chronic Effects from Short and Long-term Exposure Carcenogenicity IARC concludes that Carbon Black is possibly carcinogenic to humans (Group 2A). Numerical Measures of Toxicity Chemical Name Oral LD50mg/kg Dermal LD50mg/kg Inhalation LD50mg/kg Carbon Black >8,000 (Rat) Not Tested Not Tested Dispersant >5,000 (Rat) Not Tested Not Tested
SECTION 12. ECOLOGICAL INFORMATION Aquatic Toxicity Not anticipated to cause any adverse effects to plants or animals. SECTION 13. DISPOSAL CONSIDERATIONS Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. SECTION 14. TRANSPORT INFORMATION Special Shipping Information PIN TDG DOT IMO ICAO ERAP SECTION 15. REGULATORY INFORMATION WHMIS Classification Not Controlled OSHA See section 2 Other TSCA DSL / TOSCA
SECTION 16. OTHER INFORMATION Regulatory Information SARA & WHMIS SARA Section 313 Listed Ingredients These products are not considered as a hazardous substance as defined by SARA title 111 regulations (40 CFR 372). These products do not contain any substance that is subject to the reporting requirements of 40 CFR 372. SARA Classification: Listed. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. It is provided solely for the customer s consideration, and verification. Hereby specifically claims. It shall not be held liable for any damage resulting from handling or from contact with the above products.