THESIS COMPLETION CERTIFICATE

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THESIS COMPLETION CERTIFICATE This is to certify that the thesis on VALIDATING SUB-SEA GAS PIPELINE LEAKS DISCHARGE MODEL FOR ARABIAN SEA CONDITIONS by P.C.SRIDHER, SAP ID-500010363 in Partial completion of the requirements for the award of the Degree of Doctor of Philosophy (Engineering) is an original work carried out by him under our joint supervision and guidance. It is certified that the work has not been submitted anywhere else for the award of any other diploma or degree of this or any other University. External Guides Name : Dr. Vijaya Baskher Reddy Signature : Internal Guide: Name : Dr. Shrihari Signature : Centre for Continuing Education University of Petroleum & Energy Studies I

REVISION HISTORY Rev Description Date Author 0.0 Initial Draft prepared with guidance of Dr.V.B.Reddy 21.08.2011 P.C.Sridher 1.0 Initial Draft was reviewed and updated based on comments and feedback given by Dr.Shrihari during the review meeting held at UPES Campus on 04.12.2012 2.0 Final version. The literature survey results were validated with the results of IIT-M experimentation 3.0 Updated based on minor comments received from Faculty Research Committee (FRC) during the review on 04.05.2012 28.12.2012 P.C.Sridher 10.04.2012 P.C.Sridher 04.07.2012 P.C.Sridher Centre for Continuing Education University of Petroleum & Energy Studies II

EVALUATION Name of Faculty 1 Date Signature Remarks Outstanding Good Satisfactory Meets minimum standards Unsatisfactory Name of Faculty 2 Date Signature Remarks Outstanding Good Satisfactory Meets minimum standards Unsatisfactory Centre for Continuing Education University of Petroleum & Energy Studies III

ACKNOWLEDGEMENTS The satisfaction and elation that accompany the completion of my Dissertation would be incomplete without the mention of the people who have made it a possibility. It is a great privilege to express my gratitude and respect to all those who have guided me and inspired me during the course of my research work. First and foremost, I would like to express my sincere gratitude to my Research Guides Dr. Shrihari, the Dean, Centre for Continuing Education (CCE), UPES and Dr. Vijaya Baskher Reddy of Abu Dhabi Company for On-shore Oil Operations (ADCO), Abu Dhabi for their constant guidance and supervision during the period of my research work. Without their generous help and expert advice, I would not have been able to pursue my research into this rather uncharted topic. My most sincere and heartfelt thanks to Dr.S.Bhattacharya, Head of Ocean Eng. Dept., IIT- Madras and to Mr.M.Santhanam, Technical Officer, Gr.I for their valuable guidance and support in carrying out the experimentation in their world-class shallow water basin. My sincere thanks are due to Mr. Rajneesh Kumar, Head of Operations and Mr. R.Krishnan, Principal Process Engineer of M/s International Risk Control Asia (IRCA), the leading international safety consultancy firm in the field of Oil & Gas for sharing pertinent technical information for my research work. My profound thanks are due to the Management of TATA POWER, for providing moral support for my research work. Finally, but not the least, I would like to thank my colleagues, my friends and family for their steady stream of encouragement and unwavering support. It was their shadow during my most testing and doubtful moments that gave me the impetus to forge ahead with my research work. Centre for Continuing Education University of Petroleum & Energy Studies IV

EXECUTIVE SUMMARY A number of Gas leaks from subsea pipelines have been recorded in recent years. These occurrences highlight the need for better understanding of the way Gas leaks (plume) behave under water and the risks they present. This requirement was underlined by the submarine gas blowout on the Snorre, an offshore installation of Norway in 2004 and other similar incidents reported world-wide this decade. The effects of subsea hydrocarbon release depend on a number of factors, including whether the release is liquid or gas. For a liquid release, the buoyancy will result in the leaked material spreading on the surface to form either a polluting slick, or an expanding pool fire. For a gas release, although the buoyancy is rather greater, significant drag forces will cause the plume to break up and rise to the surface as a series of bubbles. On breaking surface, ignition of the gas plume would result in a sea surface fire with different characteristics to those incorporated into the usual pool and jet fire models. Alternatively, and more likely, the plume will begin to disperse in the atmosphere, and may be diluted to a concentration below the lower flammable limit before there is any possibility of encountering an ignition source. A further effect of a gas bubble plume is the reduction in the stability of floating vessels, due to either the loss of buoyancy, or, more likely, due to the radial outflow of water which has been entrained into the plume. Consequence models are used to predict the physical behaviour of hazardous incidents mainly flammable & toxic releases. Some models only calculate the effect of a limited number of physical processes, like discharge or radiation effects. More complex models interlink the various steps in consequence modelling into one package. The field of consequence modelling for hydrocarbon releases in open atmospheric is highly developed. The development of dispersion models for atmospheric leaks has emerged through three major stages over a period of time: Stage 1: Development/establishing the methodology (Calculation basis); Stage 2: Validation of results by experimentation and case histories; Stage 3: Refining of methodology/model based on the feedback from experimentation and case histories. Centre for Continuing Education University of Petroleum & Energy Studies V

Whereas, the understanding about the behaviour of a subsea gas release up through the water column (plume raise) is very limited from risk assessment point of view. The hydrodynamic basis for bubble-plume flows is reasonably well understood, but the solutions of the associated equations, depend on a large number of parameters that can only be evaluated by experimentation. In the recent years some research works are done in UK and Norway to study the sub-sea gas leaks plume behaviour for North Sea. However no such research work is carried out in India for Arabian Sea Conditions. Hence, this thesis is aimed at VALIDATING SUB- SEA GAS PIPELINE LEAKS DISCHARGE MODEL FOR ARABIAN SEA CONDITIONS. The outcome of this research will greatly benefit the Indian oil and gas industry by means of validating the accuracy of Risk Assessment (Consequence modelling part) of the sub-sea gas pipelines leaks so as to implement specific safety measures to protect the precious national assets. The discharge of the gas from the release point to the surface is considered in three zones Zone of Flow Establishment (ZOFE): The region between the release point and the height at which the dispersion appears to adopt a plume-like structure. At this height the effects of initial release momentum are considered to be secondary to the momentum induced by buoyancy. Zone of Established Flow (ZOEF): The plume-like region of dispersion which extends from the ZOFE to a depth beneath the free surface which is of the order of one plume diameter. Zone of Surface Flow (ZOSF): The region above the ZOEF where the plume interacts with the surface causing widening of the bubble plume and radial flow of water at the surface. Three approaches, of varying complexity, have been used in modelling the discharge of subsea releases in North Sea: a. Empirical/ Cone model b. Integral Model c. Computational Fluid Dynamic (CFD) model Centre for Continuing Education University of Petroleum & Energy Studies VI

The simplest are empirical models which consist of those that assume the plume radius to be proportional to the release depth or correlations that have been produced to fit the available experimental data. Integral models are based on local similarity i.e. the radial profiles of velocity and density defect are assumed to have a similar form at different heights within the plume. The plume properties can be represented, using for example Gaussian profiles, by their plume centreline values. Entrainment of water into the plume is described using a correlation relating the rate of increase of water flow to the plume centreline properties through the use of an entrainment coefficient, as is used in single phase plume modelling. Gas continuity, and equating the increase in momentum to the buoyancy forces, allows the plume properties to be calculated in a step-by-step manner as the height above the release is incremented. Separate models have been produced for the ZOEF and the ZOSF as described in integral models for initial release and integral models for the region of established flow respectively. The most complex models are represented by Computational Fluid Dynamics (CFD) or field codes which solve the Navier Stokes equations of fluid flow. Their advantage over integral models is that effects such as entrainment and turbulent transport of momentum are modelled directly and do not require the use of empirical constants. However, they still involve some modelling assumptions, as described in CFD models, and are more resource-intensive to run than integral or empirical models. The uncertainties exist in the models that include experimentation. The uncertainties for experimentation are, measuring velocity with two phase flow, need to take long time averages of the data and extrapolating the data for real time scenarios. In empirical models, the assumption of plume similarity through both the depth of the sea and over the range of release rates is considered. The flow above the surface is not considered for study. In Integral models, firstly there is a need for an established zone of plume-like behaviour, typical assumptions are entrainment, treatment of the bubble plume as a continuum etc. In CFD models, the main sources of uncertainties are the implementation of additional source terms in conventional codes, the need for very specific and detailed flow data for validation purposes. For CFD and integral models, uncertainty in their prediction increases with increasing flow rates and shallower or deeper water depths. Centre for Continuing Education University of Petroleum & Energy Studies VII

Lab-scale experimentation was held at Department of Ocean Engineering, Indian Institute of Technology, Madras (IIT-M) for validating the Empirical/ Cone gas discharge plume model established by T.K.Fannelop & M.Bettelini [8] in North Sea for Arabian Sea. Striking a right balance between accuracy, uncertainty, cost effectiveness and userfriendliness, clearly, the simple empirical model remains most favoured for use in risk assessments. In this study the available information on the bubble plumes, both theory and experiments was reviewed for the purpose of improving our prediction capabilities of small to medium releases which are common. Simple cone models assume either that the bubble plume occupies a cone of angle, or, equivalently, that the radius at the surface is a fixed proportion of the depth: i.e. b (z) =z tan ( /2). This cone angle is defined as that of the subsea plume and does not include the effect of radial flow, which is known to occur near the sea surface. a. It is assumed that, and hence tan /2, are fixed parameters which do not vary with release rate or depth. b. The value of the model constants used varies significantly. The cone angle is established as between 10-12. Lower values closely match that of 10 there by validating the results established by Wilson, 1988 [37] and Milgram and Erb, 1984 [19] for North Sea. c. The boil area, where the bubbles break through the surface, has approximately twice the diameter of the bubble plume as determined in the absence of surface interaction. This observation is confirmed by detailed measurements and justifies the use of cone angles even up to 23 0 as established by Billeter and Fanne1op 1989 [2] for North Sea. The gas discharge plume model established for Arabian Sea very well matches with the plume model for North Sea sub-sea gas releases established by Fannelop T.K. & Bettelini M.[8] The simple empirical model is the least resource-intensive, user-friendly and, reasonably accurate, is most favoured for use in risk assessments. Centre for Continuing Education University of Petroleum & Energy Studies VIII

CONTENTS S.No Topic Page no. 1 Introduction 1 1.1 Chapter Overview 1 1.2 Definitions & Abbreviations 1 1.3 Research motivation 4 1.4 Overview of research model 6 1.5 Overview of research approach 7 1.6 Contribution of research 7 1.7 Outline of thesis chapters 7 2 Literature survey 9 2.1 Chapter overview 9 2.2 Chronological order of research done and researcher(s) and contribution 9 2.3 Chapter summary 13 3 Research problem 14 3.1 Chapter overview 14 3.2 Introduction to research problem 14 3.3 Implications of research problem 15 3.4 Influence of research problem on Indian Oil & Gas industry 17 3.5 Chapter summary 17 4 Research outline 18 4.1 Chapter overview 18 4.2 Objectives 18 4.3 Chapter summary 18 5 Validation of discharge model for Arabian Sea Conditions by 19 experimentation 5.1 Chapter overview 19 5.2 Operationalization of research model s competence 19 5.3 Scale refinement 19 5.4 Empirical validation of constructs 19 5.5 Plume behaviour in Test tank (water depth 1m) 24 5.6 Measurement of plume characteristics 26 5.7 Comparing empirical plume model established in North Sea with IIT-M 28 Centre for Continuing Education University of Petroleum & Energy Studies IX

experimentation for Arabian Sea 5.8 Chapter summary 33 6 Models for research problem s competence 34 6.1 Chapter overview 34 6.2 Competing model for research problem 34 6.3 Most optimal model 45 6.4 Methodology 45 6.5 Chapter summary 54 7 Conclusions and future research 55 7.1 Chapter overview 55 7.2 Summary of research findings 55 7.3 Contributions of this research 56 7.4 Limitations and future research 56 8 References 58 9 Appendices 62 Appendix A 62 10 Index 65 11 Brief bio-data of the author 66 Centre for Continuing Education University of Petroleum & Energy Studies X

LIST OF FIGURES Fig. No. Title Page no. 1.1 Gas dispersion model 6 5.4.1 World-class wave basin facility at IIT-M. 30mx30mx3m deep 22 equipped with Multi-Element Wave Maker (MEWM), 52 paddles capable of producing short and Long Crested Waves Maker (LCWM) capable of producing regular and random waves. 5.4.2 Test tank 2mx1.5mx1.25m height with graduation scales fitted for 22 measuring plume height and diameter. 5.4.3 Pespex pipe of 2inch diameter and12inches length with 1inch 23 aperture with 3/4th inch brass gas inlet nozzle. 5.4.4 Pespex pipe assembly connected to 3/4th inch air hose with rope and 23 mounting arrangement with dead weight. 5.4.5 Vertical graduation scale attached to test tank 23 5.4.6 Horizontal graduation scale attached to test tank 23 5.5.1 Plume behaviour at Depth : 1m & Flow Rate : 0.00253m 3 /s 24 5.5.2 Plume behaviour at Depth : 1m & Flow Rate : 0.00505m 3 /s 24 5.5.3 Plume behaviour at Depth : 1m & Flow Rate : 0.00758m 3 /s 25 5.5.4 Plume behaviour at Depth : 1m & Flow Rate : 0.0112m 3 /s 25 5.6.1 Plume behaviour at Depth : 0.5m & Flow Rate : 0.0112m 3 /s 26 5.6.2 Plume behaviour at Depth : 0.75m & Flow Rate : 0.0112m 3 /s 26 5.6.3 Plume behaviour at Depth :1m & Flow Rate : 0.0112m 3 /s 27 5.6.4 Plume behaviour at Depth : 1.5m & Flow Rate : 0.0112m 3 /s 27 5.7.1 Gas flow rate vs Centerline velocity for Arabian Sea 28 5.7.2 Gas flow rate vs Plume radius for Arabian Sea 29 5.7.3 Ocean depth vs Centerline velocity for Arabian Sea 30 5.7.4 Ocean depth vs Plume radius for Arabian Sea 31 6.1 Subsea discharge based on simple cone model 35 6.2 Idealised subsea bubble plume 36 6.3 Steady-state bubble plumes with surface flow 37 6.4 Cross section of the grid used in the coupled DPM-VOF simulation 43 6.5 Gas flow rate vs Centerline velocity for North Sea 46 6.6 Gas flow rate vs Centerline velocity for Arabian Sea 47 Centre for Continuing Education University of Petroleum & Energy Studies XI

6.7 Gas flow rate vs Plume diameter North Sea 48 6.8 Gas flow rate vs Plume radius for Arabian Sea 49 6.9 Ocean depth vs centerline velocity for North Sea 50 6.10 Ocean depth vs centerline velocity for Arabian Sea 51 6.11 Ocean depth vs Plume diameter for North Sea 52 6.12 Ocean depth vs Plume diameter for Arabian Sea 53 Centre for Continuing Education University of Petroleum & Energy Studies XII

LIST OF TABLES Tab.No. Title Page no. 2.1 Research done and researcher(s) and contribution 9 5.1 Comparison between Fannelop et al and IIT-M experimentation 20 5.2 Gas flow rate and centreline velocity for various depths for Arabian 28 Sea 5.3 Gas flow rate and plume diameter for various depths for Arabian Sea 29 5.4 Ocean depth and centreline velocity for various flow rates for Arabian 30 Sea 5.5 Ocean depth and plume radius for various flow rates for Arabian Sea 31 5.6 Experimental results 32 6.1 Recommended Values for empirical parameters for application 39 6.2 Comparison of Models 45 6.3 Gas flow rate and centreline velocity for various depths for North Sea 46 6.4 Gas flow rate and centreline velocity for various depths for Arabian 47 Sea 6.5 Gas flow rate and plume diameter for various depths for North Sea 48 6.6 Gas flow rate and plume diameter for various depths for Arabian Sea 49 6.7 Ocean depth and centreline velocity for various flow rates for North 50 Sea 6.8 Ocean depth and centreline velocity for various flow rates for Arabian 51 Sea 6.9 Ocean depth and plume diameter for various flow rates for North Sea 52 6.10 Ocean depth and plume radius for various flow rates for Arabian Sea 53 Centre for Continuing Education University of Petroleum & Energy Studies XIII