Seite 1 von 6 Material Safety Data Sheet According to 91/155 EC Printing date 24.10.2002 Reviewed on 05.10.1999 * 1 Identification of substance Product details Trade name CARAMBA Rasant(Aerosol) Article number: 6007 Manufacturer/Supplier: CARAMBA CHEMIE GMBH & Co.KG WANHEIMERSTR. 334/336 47055 DUISBURG Tel.: 0203/77 86 01 Informing department: Laboratory, tel.: 0203 / 77 86 165 Emergency information: Landesberatungsstelle für Vergiftungserscheinungen, Berlin, tel: 030-19240 * 2 Composition/Data on components: Chemical characterization Description: Active substance with propellant. Preparation of paraffinic and naphthenic hydrcarbons and glycol Propellent gas: air Dangerous components: Glycol % Xn; R 20/21/22-36/38 5-12 Benzinkohlenwasserstoff Xn; R 65-66 20-60 % * 3 Hazards identification Hazard designation: Xi Irritant Information pertaining to particular dangers for man and environment R 36 Irritating to eyes. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use.
Seite 2 von 6 Classification system The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies. 4 First aid measures General information No special measures required. After inhalation Supply fresh air; consult doctor in case of symptoms. After skin contact Instantly wash with water and soap and rinse thoroughly. After eye contact Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor. After swallowing Do not induce vomiting; instantly call for medical help. 5 Fire fighting measures Suitable extinguishing agents CO2, extinguishing powder, waterspray or foam. For safety reasons unsuitable extinguishing agents Water with a full water jet. Protective equipment: No special measures required. 6 Accidental release measures Person-related safety precautions: Not required. Measures for environmental protection: No special measures required. Measures for cleaning/collecting: Ensure adequate ventilation. Additional information: No dangerous materials are released. 7 Handling and storage Handling Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Information about protection against explosions and fires: Keep breathing equipment ready. Storage Requirements to be met by storerooms and containers: Only store in heated containers. Information about storage in one common storage facility: Not required. Further information about storage conditions: Protect from heat and direct sunlight. Storage class Class according to regulation on inflammable liquids: Void * 8 Exposure controls and personal protection
Seite 3 von 6 Additional information about design of technical systems: No further data; see item 7. Components with critical values that require monitoring at the workplace: hydrocarbon (20-50%) TRGS 404: 200 ml/m3 Additional information: The lists that were valid during the compilation were used as basis. Personal protective equipment General protective and hygienic measures The usual precautionary measures should be adhered to in handling the chemicals. Breathing equipment: Use breathing protection in case of insufficient ventilation. Eye protection: Safety glasses 9 Physical and chemical properties: General Information Form: Aerosol Colour: Clear Smell: Characteristic Value/Range Unit Method Change in condition Melting point/melting range: Not determined Boiling point/boiling range: 180-220 C DIN 51 751 Flash point: 67 C DIN 51 755 Ignition temperature: Self-inflammability: selfigniting. Product is not 230 C Danger of explosion: Product is not explosive. However, formation of explosive air/steam mixtures is possible. Critical values for explosion: Lower: 0.9 Vol % Upper: 10.6 Vol % Steam pressure: at 20 C 1.3 mbar Density at 20 C 0.842 g/cm3 DIN
Seite 4 von 6 51 757 Solubility in / Miscibility with Water: to mix 10 Stability and reactivity Not miscible or difficult Conditions to be avoided: No decomposition if used according to specifications. Dangerous reactions No dangerous reactions known Dangerous products of composition: None 11 Toxicological information Acute toxicity: LD/LC50 values that are relevant for classification: Glycol Oral: LD50: 1480 mg/kg (rat) Dermal: LD50: 400 mg/kg (rab) Inhalative: LC50/4 h: 450 mg/l (rat) Primary irritant effect: on the skin: Irritant for skin and mucous membranes. on the eye: Irritant effect. Sensitization: No sensitizing effect known. Additional toxicological information: Irritant The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for Preparations as issued in the latest version: 12 Ecological information: General notes: Do not allow product to reach ground water, water bodies or sewage system. *13 Disposal considerations Product: Recommendation Smaller quantities can be disposed with household garbage. European waste catalogue 07 00 00: Wastes from organic chemical processes 07 06 00: waste from the MFSU of fats, grease, soaps, detergents disinfectants and cosmetics 07 06 04: other organic solvents, washing liquids and mother liquors Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. *14 Transport information
Seite 5 von 6 Land transport ADR/RID and GGVS/GGVE (cross-border/domestic) ADR/RID-GGVS/E Class: 2 Gases. Number/Letter: 5 F UN-Number: 1950 Label 3 Designation of goods: Druckgaspackungen Remarks: transport after a-border nummber possible Maritime transport IMDG/GGVSea: IMDG/GGVSea Class: 2 Page: 2102 UN Number: 1950 Packaging group: II EMS Number: 2-13 MFAG: 620 Correct technical name: Aerosols, limited quantities Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: 2.1 UN/ID Number: 1950 Packaging group: II Correct technical name: Aerosols, flammable,n.o.s. *15 Regulatory information Designation according to EC guidelines: Observe the normal safety regulations when handling chemicals The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV) Code letter and hazard designation of product: Xi Irritant Risk phrases: 36 Irritating to eyes. Safety phrases: 2 Keep out of the reach of children. 23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). 25 Avoid contact with eyes. 36 Wear suitable protective clothing. 51 Use only in well-ventilated areas. Special designation of certain preparations: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. National regulations Classification according to VbF: Void
Seite 6 von 6 Water hazard class: Water hazard class 2 (Self-assessment): hazardous for water. 16 Other information: These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant R-phrases 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. 36/38 Irritating to eyes and skin. 65 Harmful: may cause lung damage if swallowed. 66 Repeated exposure may cause skin dryness or cracking. Department issuing data specification sheet: Abteilung Labor Contact: Herr DI Otte