Appendix A COMPARISON OF DRAINAGE ALGORITHMS UNDER GRAVITY- DRIVEN FLOW DURING GAS INJECTION

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ppendix COMPRISON OF DRINGE LGORITHMS UNDER GRVITY- DRIVEN FLOW DURING GS INJECTION.1 Introduction ll the simulations of gas injection discussed in this thesis were performed using a modified invasion percolation (MIP) algorithm. MIP has been fully described in Chapter 3. It incorporates a time-dependent interface tracking, partial pore filling, and dynamically coupled viscous pressure gradient during both stable and migratory flow. We now compare some of these results with another set of results obtained using identical model input parameters but simulated with a model that incorporates a classic invasion percolation (CIP) algorithm during stable gas flow. CIP assumes binary pore occupancy in which a pore is at any instance completely filled with one phase or another. lthough CIP is simple and fast, the time independent binary pore filling that it assumes does not account for the effect of viscosity on flow and it is therefore unsuited to studying rate effects. The following discussions compares the features of gravity-driven regimes obtained using MIP and CIP drainage algorithms under varying network parameters R mean, σ 2 and Z. Note that the movement of the interface during migratory flow is governed by the same dynamic time-dependent algorithm regardless of the type of gas growth (stable flow) algorithm selected..2 MIP vs. CIP: Effect of R mean on Regimes The pore occupancy graphics corresponding to results obtained using MIP and CIP are compared side by side in Figure -1. The comparison shows that if no transition to migratory flow occurs (Figure -1[α: a, b, c, d, e, i; β: a, b, c, d, e, i ), then the results of CIP and MIP will be identical. This means that under capillary and gravity biased regimes the predictions of CIP and MIP are the same. Since CIP is orders of magnitudes more CPU efficient than MIP, we can build larger networks in order to examine the effects of macroscopic features of porous media on regime transitions so long as it precludes 367

ppendix - Comparison of Drainage lgorithms under Gravity-Driven Flow during Gas Injection migratory flow. The flow of gas through tight rocks like shales or chalks presents good examples. s clusters begin to migrate, however, the results of the two algorithms diverged (Figure -1[α: f, g, h, j, k, i; β: f, g, h, j, k, i ] although the degree of divergence was dependent on the nature of the migratory flow regime as explained below. raided migratory regimes: The multi-channel braided regimes generated by MIP models (Figure -1[α: f, g, j, k]) were not produced by the corresponding CIP models single channels of residual gas developed instead (Figure -1[β: f, g, j, k ]). Dramatic differences in profiles between corresponding CIP and MIP models then resulted (Figure -2). Multiple gravity fingers formed in MIP models because of the stronger irregularities in the phase saturation and trapping patterns after each migration event (created by the partial pore filling and multi-pore meniscus tracking) compared to CIP models. These irregularities gave newly injected gas more alternative flow pathways (menisci exist in more pores) than would be the case if only binary pore occupancy were possible (as in CIP). Furthermore, since the invasion mechanism during migration uses an MIP-like algorithm, there was a smoother transition from stable to migratory flow in the MIP models compared to the CIP models. In CIP models, injected gas always reconnected the residual bubbles in almost identical locations, forming a gravity finger with the exact pore configuration as the fingers which migrated previously. On reaching the critical height for migration (as o>1), the finger migrates and fragments. In CIP models, cycles of growthmigration-growth repeated indefinitely with barely any change in from one cycle to the next (see Figure -2). Dispersive migratory regimes: Corresponding MIP and CIP models generated broadly similar saturation patterns under dispersive migratory regime (Figure -1[α: h, l; β: h, l ]). However, in MIP models there was more lateral gas movement in the early phase of displacement, subsequently injected gas retraced this path and this ultimately led to higher profiles compared to corresponding CIP models (Figure -3). 368

ppendix - Comparison of Drainage lgorithms under Gravity-Driven Flow during Gas Injection.3 MIP Vs. CIP: Effect of σ 2 on Regimes Stable regimes (Figure -4[α: a h; β: a h ]) were insensitive to the choice of algorithm. The braided regimes again showed the strongest sensitivity to algorithm choice (Figure -4[α: i l; β: i l ]) with the MIP models consistently giving higher profiles (Figure -5). Dispersive regimes were also sensitive to algorithm choice but to a lesser degree both in terms of saturation distribution patterns (Figure -4[α: m p; β: m p ]) and profiles (Figure -6)..4 MIP Vs. CIP: Effect of Z on Regimes oth algorithms returned virtually identical stable regimes once again (Figure -7[α: a d; β: a d ]). Migratory regimes (Figure -7[α: e h; β: e h ]) also appeared to be largely unaffected by algorithm choice as the coordination number was varied..5 Summary Under stable flow, CIP and MIP models predicted exactly the same flow pattern. For migratory flow, however, MIP models predicted residual saturations 50-500% greater than those predicted by corresponding CIP models. Given the excellent agreement between results of MIP models and experimental observations (Discussed in Chapter 4), we can conclude that network models that incorporate the MIP algorithm rather than the CIP algorithm would be much better at approximating gravity-driven migratory flow behaviour. Table -1: Pore radii distributions for models used for R mean sensitivity, arranged according to PSD variance. Sigma 2 6.75 R mean, µm 5.5 15.5 25.5 35.5 R min, R max 1, 10 11, 20 21, 30 31, 40 a b c d Sigma 2 200 R mean, µm 25.5 75.5 125.5 175.5 R min, R max; µm 1, 50 51, 100 101, 150 151, 200 e f g h Sigma 2 816.75 R mean, µm 50 100 150 250 R min, R max; µm 1, 100 51, 150 101, 200 201, 300 i j k l 369

ppendix - Comparison of Drainage lgorithms under Gravity-Driven Flow during Gas Injection Table -2: Pore radii distributions for the models used for PSD variance sensitivity, arranged according to R mean. R mean, µm 25.5 Sigma 2 0.75 6.75 70 200 R min, R max; µm 24, 27 21, 30 11, 40 1, 50 a b c d R mean, µm 50.5 Sigma 2 30 200 520 817 R min, R max; µm 41, 60 26, 75 11, 90 1, 100 e f g h R mean, µm 75.5 Sigma 2 70 397 990 1850 R min, R max; µm 61, 90 41, 110 21, 130 1, 150 i j k l R mean, µm 250.5 Sigma 2 200 3300 10150 20751 R min, R max; µm 226, 275 151, 350 76, 425 1, 500 m n o p MIP algorithm CIP algorithm a b c d a b c d e f g h e f g h i j k l i j k l α β Figure -1: Comparison of the sensitivity of gas saturation patterns in (α) MIP, and (β) CIP models to variation in mean pore radius. (α) and (β) have been arranged according to the layout of model parameters in Table -1. 370

ppendix - Comparison of Drainage lgorithms under Gravity-Driven Flow during Gas Injection Rmean=75.5; CIP Rmean=75.5; MIP Rmean=100.5; CIP Rmean=100.5; MIP Figure -2: Comparison of gas saturation profiles of braided migratory regimes simulated using CIP and MIP algorithms. Compare the pore occupancy graphics in Figure -1 [f and f ] for () and in Figure -1 [j and j ] for (). Rmean=150.5; CIP Rmean=150.5; MIP Rmean=250.5; CIP Rmean=250.5; MIP Figure -3: Comparison of gas saturation profiles of dispersive migratory regimes simulated using CIP and MIP algorithms. Var=PSD variance. Compare the pore occupancy graphics in Figure -1[k and k ] for () and in Figure -1[l and l ] for (). 371

Stable Migratory ppendix - Comparison of Drainage lgorithms under Gravity-Driven Flow during Gas Injection MIP algorithm CIP algorithm a b c d a b c d e f g h e f g h i j k l i j k l m n o p m n o p α β Figure -4: Comparison of the sensitivity of gas saturation patterns in (α) MIP and (β) CIP models to variation in PSD variance. (α) and (β) have been arranged according to the layout of model parameters in Table -2. Var = 397; Rmean=75.5; CIP Var = 397; Rmean=75.5; MIP Var = 990; Rmean=75.5; CIP Var = 990; Rmean=75.5; MIP Figure -5: Comparison of gas saturation profiles of braided migratory regimes simulated using CIP and MIP algorithms. Compare the pore occupancy graphics in Figure -4 [j and j ] for () and in Figure -4 [k and k ] for (). 372

ppendix - Comparison of Drainage lgorithms under Gravity-Driven Flow during Gas Injection Figure -6: Comparison of gas saturation profiles of dispersive migratory regimes simulated using CIP and MIP algorithms. Compare the pore occupancy graphics in Figure -4 [n and n ] for () and in Figure -4 [o and o ] for (). Stable R mean = 50.5 σ 2 = 30 Migratory R mean = 250. 5 σ 2 = 200 Var = 3300; Rmean=250.5; CIP Var = 3300; Rmean=250.5; MIP MIP algorithm CIP algorithm 2DZ 2DZ 4.0 3.33 2.67 2.33 4.0 3.33 2.67 2.33 a b c d a b c d e f g h e f g h α β Figure -7: Comparison of the sensitivity of gas saturation patterns in (α) MIP and (β) CIP models to variation in coordination number. Var = 10150; Rmean=250.5; CIP Var = 10150; Rmean=250.5; MIP 373