1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY Product identifier: Commercial Product Name: Substance name: CAS number: 7440-50-8 REACH Registration Number: Please contact the supplier Relevant identified uses of the substance or mixture and uses advised against: Recommended use: Industrial use Supplier: REACHLaw Ltd (Only Representative) Keilaranta 15 02150 Espoo Finland +358(0) 9 412 3055 +358(0) 9 412 3049 Email: SDS@reachlaw.fi Webpage: www.reachlaw.fi Identification of the foreign producer: RTB Bor Grupa TIR d.o.o. Djordja Vajferta 20-24 19210 Bor Serbia Tel: +381 30 425 576 Fax: +381 30 425 256 Email: rtbizvoz@open.telekom.rs, reach.rtb@rtb.rs Webpage: www.rtb.rs Emergency telephone number: Poison centres Europe: http://www.who.int/pcs/poisons/centre/directory/euro/en/ Contact a poison control centre. See also section 16 2. HAZARDS IDENTIFICATION Classification of the substance or mixture: Label elements: Not a hazardous substance or mixture according to Regulation EC No. 1272/2008. Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC. Not a hazardous substance or mixture according to Regulation EC No. 1272/2008. Page 1 of 7
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name of the substance CAS / EC Reg. number Concentration % Classification (Cu) 7440-50-8 231-159-6 >99,99-4. FIRST AID MEASURES Description of first aid measures Inhalation: IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing Skin contact: If on skin, rinse well with water Eye contact: powder: If in eyes, rinse with water for 15 minutes Ingestion: Rinse mouth with water. Call a POISON CENTRE or doctor/ physician if feeling unwell. DO NOT induce vomiting unless directed to do so by a physician or poison control centre. Never give anything by mouth to an unconscious person. Most important symptoms and effects, both acute and delayed: Powder can cause localized skin irritation in folds of the skin or under tight clothing Indication of immediate medical attention and special treatment needed: Remove and wash contaminated clothing and gloves, including the inside, before re-use. 5. FIRE FIGHTING MEASURES Extinguishing media: Suitable extinguishing media: Extinguishing media which must not be used for safety reasons: Special hazards arising from the substance or mixture: The product itself does not burn. No special protective measures against fire required No materials to be especially mentioned Dust can form an explosive mixture in air Fumes harmful Advice for fire-fighters: No special handling advice required. Do NOT use water jet on molten metal. Specific methods: Page 2 of 7
6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedure: In the case of dust or aerosol formation use respirator with an approved filter. In the case of respirable dust and/or fumes, use self-contained breathing apparatus Environmental precautions: Discharge into the environment must be avoided Methods and materials for containment and cleaning up: Collect in plastic or metal containers for disposal Reference to other sections: See also section 8 7. HANDLING AND STORAGE Precautions for safe handling: Conditions for safe storage, including any incompatibilities: Specific end use(s): Avoid dust formation. Avoid breathing dust. Heat only in areas with appropriate exhaust ventilation. Smoking, eating and drinking should be prohibited in the application area. Handle in accordance with good industrial hygiene and safety practice. Keep tightly closed in a dry, cool and well-ventilated place. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters: Other information on limit values: DNELs: PNECs: Exposure controls: Occupational exposure controls: fumes: TWA: 0,2 mg/m3, respirable dust, dust / mist: TWA: 1 mg/m3 STEL: 2 mg/m3 Smoking, eating and drinking should be prohibited in the application area. Handle in accordance with good industrial hygiene and safety practice. Heat only in areas with appropriate exhaust ventilation. Provide appropriate exhaust ventilation at places where dust is formed. Page 3 of 7
Individual protection measures: Respiratory protection: Hand protection: Eye/face protection: Skin protection: Environmental exposure controls: In the case of respirable dust and/or fumes, use selfcontained breathing apparatus Protective gloves Safety goggles Recommended preventive skin protection Discharge into the environment must be avoided 9. PHYSICAL AND CHEMICAL PROPERTIES Important Health Safety and Environmental Information: Appearance: Red brown metal Odour: Odourless Odour threshold: ph: Melting point / freezing point: 1083 C Initial boiling point and boiling range: 2595 C Flash point: Evaporation rate: Flammability (solid, gas): The product is not flammable. Dust may form explosive mixture in air. Vapour pressure: 1 mm @ 1083 C Vapour density:. Relative density: 8,94 Solubility(ies): Water solubility: Insoluble in hot/cold water Partition coefficient: n-octanol /water: Viscosity: Explosive properties: Oxidising properties: 10. STABILITY AND REACTIVITY Reactivity: Chemical stability: Possibility of hazardous reactions: Conditions to avoid: Incompatible materials: Hazardous decomposition products: Stable at normal ambient temperature and pressure Stable at normal ambient temperature and pressure Stable at normal ambient temperature and pressure Avoid dust formation Acetylene, ammonium nitrate, 3 - Bromates, 4 - Chlorates, iodates, Chlorine, Fluorine, Peroxides Heating can release hazardous gases ( oxides) Page 4 of 7
11. TOXICOLOGICAL INFORMATION Information on toxicological effects Acute toxicity: Irritation and corrosion: Sensitisation: Sub acute, sub chronic and prolonged toxicity: STOT - single exposure: STOT - repeated exposure: Aspiration hazard:. Toxic at ingestion / inhalation in large quantities Not corrosive. May cause eye and skin irritation (dust) Avoid prolonged or repeated breathing of vapour No aspiration toxicity classification 12. ECOLOGICAL INFORMATION Aquatic toxicity: Toxicity to other organisms: Persistence and degradability: Biodegradation: Chemical degradation: Bio accumulative potential: Results of PBT and vpvb assessment: Possibly toxic Potential bioaccumulation 13. DISPOSAL CONSIDERATIONS Waste treatment methods: Dispose of as special waste in compliance with local and national regulations. 14. TRANSPORT INFORMATION UN number: UN proper shipping name: Transport hazard class(es): Packing group: Environmental hazards: Discharge into the environment must be avoided Special precautions for users: For personal protection see section 8. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Page 5 of 7
15. REGULATORY INFORMATION Safety, health and environmental regulations / legislation specific for the substance or mixture: Chemical safety assessment: 16. OTHER INFORMATION Additions, Deletions, Revisions: Version 1.0 Key or legend to abbreviations and acronyms: Key literature references and sources for data: Classification procedure: - REACH: according to Regulation (EC) No. 1907/2006 - CLP: REGULATION (EC) No 1272/2008 - DSD: Classification according to EU Directives 67/548/EEC or 1999/45/EC SAFETY DATA SHEET: RTB BOR GRUPA TIR d.o.o.. Page 6 of 7
Contact a poison control centre. Emergency telephone number: AUSTRIA (Vienna Wien) +43 1 40 400 2222; BELGIUM (Brussels Bruxelles) +32 70 245 245; BULGARIA (Sofia) +359 2 9154 409 / +359 887 435 325; CZECH REPUBLIC (Prague Praha) +42 2 2491 9293 or +42 2 2491 5402; DENMARK (Copenhagen) +45 35 31 54 04; FINLAND (Helsinki) +358 9 471 977; FRANCE (Paris) +33 1 40 05 4848; GERMANY (Berlin) +49 30 450 653565; GREECE (Athens Athinai) +30 10 779 3777; HUNGARY (Budapest) +36 80 20 11 99; ICELAND (Reykjavik) +354 525 111, +354 543 2222; IRELAND (Dublin) +353 1 8379964; ITALY (Rome) +39 06 305 4343; LATVIA (Riga) +371 704 2468; LITHUANIA (Vilnius) +370 2 36 20 52, +370 2 36 2092; NETHERLANDS (Bilthoven) +31 30 274 88 88; NORWAY (Oslo) +47 22 591300; POLAND (Gdansk) +48 58 301 65 16 or +48 58 349 2831; PORTUGAL (Lisbon) 808 250 143 (for use only in Portugal), +351 21 330 3284; ROMANIA (Bucharest) +40 21 230 8000; SLOVAKIA (Bratislava) +421 2 54 77 4 166; SLOVENIA (Ljubljana) + 386 41 650 500; SPAIN (Barcelona) +34 93 227 98 33 or +34 93 227 54 00 bleep 190; SWEDEN (Stockholm) +46 8 33 12 31 (International) 112 (National); UNITED KINGDOM (London) 0870 243 2241 Page 7 of 7