1. Identification of the substance/mixture and of the company/undertaking Trade name Synonyms Company Sasol Solvents A Division of Sasol Chemical Industries 2 Sturdee Avenue Rosebank 2196 Republic of South Africa Information (Product safety) Telephone: +27 11 280 0000 Fax: +27 11 280 0198 E-mail address msds.info@sasol.com Emergency telephone Europe, Israel, Africa, Americas +44 (0)1235 239 670 number Middle East, Arabic African +44 (0)1235 239 671 countries Asia Pacific +65 3158 1074 China +86 10 5100 3039 South Africa +27 (0)17 610 4444 Australia +61 2 9032 0460 2. Hazards identification Identification of the risks R10 Flammable. R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes. R67 Vapours may cause drowsiness and dizziness. 3. Composition/information on ingredients Preparation on the base: Propan-1-ol; n-propanol Contents: >= 32.60 - <= 73.40 %W/W CAS-No. 71-23-8 Index-No. 603-003-00-0 EC-No. 200-746-9 Symbol(s) F, Xi R-phrase(s) -R11 -R41 -R67 Butan-2-ol Contents: >= 22.30 - <= 50.10 %W/W CAS-No. 78-92-2 Index-No. 603-004-01-3 EC-No. 201-158-5 Symbol(s) Xi R-phrase(s) -R10 -R36/37 -R67 Print Date 08.03.2012 100000003953 1/8
2-Methylpropan-1-ol; Iso-butanol Contents: >= 15.20 - <= 34.30 %W/W CAS-No. 78-83-1 Index-No. 603-108-00-1 EC-No. 201-148-0 Symbol(s) Xi R-phrase(s) -R10 -R37/38 -R41 -R67 Butan-1-ol; n-butanol Contents: >= 4.80 - <= 10.90 %W/W CAS-No. 71-36-3 Index-No. 603-004-00-6 EC-No. 200-751-6 Symbol(s) Xn R-phrase(s) -R10 -R22 -R37/38 -R41 -R67 Pentanol isomers, with the exception of those specified elsewhere in this Annex Contents: >= 1.50 - <= 3.30 %W/W CAS-No. 598-75-4 Index-No. 603-006-00-7 EC-No. 209-950-2 Symbol(s) Xn R-phrase(s) -R10 -R20 -R37 -R66 Pentanol isomers, with the exception of those specified elsewhere in this Annex Contents: >= 0.70 - <= 1.50 %W/W CAS-No. 6032-29-7 Index-No. 603-006-00-7 EC-No. 227-907-6 Symbol(s) Xn R-phrase(s) -R10 -R20 -R37 -R66 For the full text of the R-phrases mentioned in this Section, see Section 16. 4. First aid measures General advice Inhalation Skin contact Eye contact Ingestion Do not leave the victim unattended. Move to fresh air in case of accidental inhalation of vapours. If breathing is irregular or stopped, administer artificial respiration. Get medical attention immediately Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get medical attention if irritation develops and persists. Remove contact lenses. Rinse immediately with plenty of running water, also under eyelids, for at least 15 minutes. Get medical attention immediately If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Print Date 08.03.2012 100000003953 2/8
5. Firefighting measures Suitable extinguishing media Specific hazards during firefighting Special protective equipment for firefighters Further information Water spray, Foam, CO 2, Dry powder Hazardous/toxic decomposition products may occur. Wear self-contained breathing apparatus and protective suit. In the event of fire, cool tanks with water spray. 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up 7. Handling and storage Use personal protective equipment. Do not breathe vapours or spray mist. Ensure adequate ventilation. Keep away from sources of ignition - No smoking. Avoid subsoil penetration. Do not flush into surface water or sanitary sewer system. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). The material taken up must be disposed of in accordance with regulations. Handling Safe handling advice Storage Requirements for storage areas and containers Wear personal protective equipment. Avoid contact with skin and eyes. Keep away from sources of ignition - No smoking. Keep containers tightly closed in a cool, well-ventilated place. Keep away from sources of ignition - No smoking. 8. Exposure controls/personal protection Components with workplace control parameters NATIONAL OCCUPATIONAL EXPOSURE LIMITS Components Type Control parameters Update Basis Print Date 08.03.2012 100000003953 3/8
N-PROPANOL PROPAN-1-OL 500 mg/m 3 200 ppm 625 mg/m 3 250 ppm SEC-BUTYL ALCOHOL 300 mg/m 3 100 ppm 450 mg/m 3 150 ppm ISOBUTYL ALCOHOL 150 mg/m 3 50 ppm 225 mg/m 3 75 ppm BUTAN-1-OL N-BUTYL ALCOHOL 150 mg/m 3 50 ppm Contains no substances with occupational exposure limit values. EUROPEAN OCCUPATIONAL EXPOSURE LIMITS Contains no substances with occupational exposure limit values. Engineering measures Provide sufficient air exchange and/or exhaust in work rooms. Personal protective equipment Respiratory protection Self contained breathing apparatus (SCBA) or supplied air ( airline mask) Hand protection Gloves suitable for permanent contact: Material: butyl-rubber Break through time: 4 h Material thickness: 0.5 mm Eye protection Skin and body protection Hygiene measures Protective measures Safety glasses with side-shields Protective suit, Safety shoes Wash hands before breaks and immediately after handling the product. Wear suitable protective equipment. Print Date 08.03.2012 100000003953 4/8
9. Physical and chemical properties Form State of matter Colour Odour ph 7 Liquid Liquid; at 20 C; 1,013 hpa Colourless Alcohol-like Melting point/range -89.5 C Boiling point/boiling range Flash point 30 C 99-103 C Autoignition temperature 343 C Lower explosion limit Upper explosion limit 2.1 %(V) 13.5 %(V) Density 0.804 g/cm 3 Solubility/qualitative Water solubility Completely soluble Viscosity, dynamic 2.728 mpa.s; 20 C Relative vapour density 2.6(Air = 1.0) Completely miscible, Completely soluble 10. Stability and reactivity Materials to avoid Hazardous decomposition products Oxidizing agents, Reducing agents, Acids and bases No decomposition if stored normally. 11. Toxicological information Acute oral toxicity n-propanol: LD50 rat: 1,870 mg/kg; literature value LD50 rat: 2,460 mg/kg; literature value LD50 rabbit: 74.1 mg/kg; literature value butan - 2- ol: LD50 rabbit: 4,900 mg/kg; literature value LDLo rabbit: 3,000 mg/kg; literature value Print Date 08.03.2012 100000003953 5/8
Acute inhalation toxicity Acute dermal toxicity LD50 rat: 6,200 mg/kg; literature value n-propanol: LC50 rat: 4,000 mg/l; literature value; 4 h LC50 rabbit: 2,630 mg/m3; literature value; 4 h LCLo rat: 8,000 mg/m3; literature value; 4 h LC50 rat: 19,200 mg/m3; literature value; 4 h LC50 rat: 48,500 mg/m3; literature value; 4 h LCLo rat: 16,000 mg/l; literature value; 4 h n-propanol: LD50 rabbit: 4,060 mg/kg; literature value LD50 rabbit: 3,400 mg/kg; literature value LD50 rat: > 2,000 mg/kg; literature value 12. Ecological information Ecotoxicity effects Toxicity to fish 13. Disposal considerations Product Contaminated packaging n-propanol: LC50 Pimephales promelas: 4,480 mg/l; 96 h; literature value LC50 Pimephales promelas: 3,670 mg/l; 96 h; literature value Pimephales promelas: 1,430 g/l; 96 h; literature value In accordance with local and national regulations., The product should not be allowed to enter drains, water courses or the soil. Packaging that cannot be cleaned must be disposed of in the same way as the material itself. Print Date 08.03.2012 100000003953 6/8
14. Transport information ADR RID ADNR IMDG ICAO/IATA UN number: 1987; Class: 3; Packaging group: III; F1; Description of the goods: ALCOHOLS, N.O.S. UN number: 1987; Class: 3; Packaging group: III; F1; Description of the goods: ALCOHOLS, N.O.S. UN number: 1987; Class: 3; Packaging group: III; F1; Description of the goods: ALCOHOLS, N.O.S. UN number: 1987; Class: 3; EmS: F-E, S-D; Packaging group: III; Description of the goods: ALCOHOLS, N.O.S. UN number : 1987; Class: 3; Packaging group: III; Description of the goods: Alcohols, n.o.s. 15. Regulatory information Labelling Regulatory base Symbol(s) R-phrase(s) 1999/45/EC Xi: Irritant R10: Flammable. R37/38: Irritating to respiratory system and skin. R41: Risk of serious damage to eyes. R67: Vapours may cause drowsiness and dizziness. S-phrase(s) S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37/39: Wear suitable gloves and eye/face protection. S60: This material and its container must be disposed of as hazardous waste. Print Date 08.03.2012 100000003953 7/8
16. Other information Full text of R-phrases referred to under sections 2 and 3 R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R22 Harmful if swallowed. R36/37 Irritating to eyes and respiratory system. R37 Irritating to respiratory system. R37/38 Irritating to respiratory system and skin. R41 Risk of serious damage to eyes. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. All reasonable efforts were exercised to compile this SDS in accordance with ISO 11014 and ANSIZ400.1.1993. The SDS provides information regarding the health, safety and environmental hazards, at the date of issue, to facilitate the safe receipt, use and handling of the product in the workplace. Since Sasol and its subsidiaries cannot anticipate or control all conditions under which the product may be handled, used and received in the workplace, it remains the obligation of each user, receiver or handler to, prior to usage, review this SDS in the context within which the product will be received, handled or used in the workplace. The user, handler or receiver must ensure that the necessary mitigating measures are in place as regards health and safety. This does not substitute the need or requirement for any relevant risk assessments to be conducted. It further remains the responsibility of the receiver, handler or user to communicate such information to all relevant parties that may be involved in the receipt, use or handling of the product. Although all reasonable efforts were exercised in the compilation of this SDS, Sasol does not expressly warrant the accuracy or assume any liability for the incompleteness of the information contained herein or any advice given. The product is sold and risk passes in accordance with the specific terms and conditions of sale. The MSDS was created by: F. SHAI The MSDS was approved by: M. HUYSER Print Date 08.03.2012 100000003953 8/8