SAFETY DATA SHEET CARBOMUL HT 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY: PRODUCT NAME: APPLICATIONS: EMERGENCY TELEPHONES: CARBOMUL HT NON-IONIC EMULSIFIER FOR INVERT EMULSION MUDS 44 (0)1224 720000 [24 hours] SUPPLIER: BAKER HUGHES INTEQ BAKER HUGHES BUILDING STONEYWOOD PARK NORTH DYCE, ABERDEEN. AB21 7EA TELEPHONE: 44 (0)1224-720000 2. COMPOSITION/INFORMATION ON INGREDIENTS: INGREDIENT NAME: AMIDO AMINE MINERAL OIL EINECS CAS No.: CONTENT SYMBOL RISK: 30-60 wt% Xi 36/38 265-149-8 64742-47-8 10-40 wt% Xn 65, 66 The full text for all R-phrases are shown in section 16 3. HAZARDS IDENTIFICATION: Irritating to eyes and skin. 4. FIRST AID MEASURES: INHALATION: INGESTION: SKIN: EYES: Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical attention. DO NOT INDUCE VOMITING! Promptly get affected personnel to drink large volumes of water to dilute the swallowed chemical. Get medical attention immediately! Wash the skin immediately with soap and water. Get medical attention if irritation persists after washing. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. 1 / 5
5. FIRE FIGHTING MEASURES: EXTINGUISHING MEDIA: Fire can be extinguished using: Powder, foam or CO2. Do NOT use Water Jets which may spread the fire. UNUSUAL FIRE & EXPLOSION HAZARDS: No unusual fire or explosion hazards noted. HAZARDOUS COMBUSTION PRODUCTS: Fire or high temperatures create: Oxides of: Nitrogen. PROTECTIVE MEASURES IN FIRE: Self contained breathing apparatus and suitable protective clothing must be worn in fire conditions. 6. ACCIDENTAL RELEASE MEASURES: PERSONAL PRECAUTION IN SPILL: Wear protective clothing and equipment. Spillages may be slippery underfoot. Wear safety slip-proof shoes during the clean-up operation. For further information on suitable protective clothing see Section 8 of the safety data sheet "Exposure Controls and Personal Protection". PRECAUTIONS TO PROTECT ENVIRONMENT: Prevent contamination of soil and water. Prevent from spreading or entering into drains, ditches or rivers by using sand, earth, or appropriate barriers. SPILL CLEANUP METHODS: Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. See Section 13, Disposal Considerations, for information regarding the disposal of contained spills. 7. HANDLING AND STORAGE: USAGE PRECAUTIONS: Avoid spilling, skin and eye contact. Protective measures during handling are detailed in Section 8 of this Safety Data Sheet. STORAGE PRECAUTIONS: Keep in cool, dry, ventilated storage and closed containers. Keep away from heat, sparks and open flame. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION: INGREDIENT NAME: MINERAL OIL CAS No.: STD: LT EXP. 8 HRS: ST EXP. 15 MIN: 64742-47-8 SUP 1000 mg/m3 No Std INGREDIENT COMMENTS: SUP = Supplier's recommendation. PROTECTIVE EQUIPMENT: VENTILATION: RESPIRATORS: Provide adequate general and local exhaust ventilation to keep airborne levels below the designated exposure limits. If ventilation is insufficient, suitable respiratory protection must be provided. PROTECTIVE GLOVES: Use protective gloves made of: Rubber, neoprene or PVC. 2 / 5
EYE PROTECTION: Wear splash-proof eye goggles to prevent any possibility of eye contact. OTHER PROTECTION: Wear appropriate clothing to prevent any possibility of skin contact. HYGIENIC WORK PRACTICES: Wash at the end of each work shift and before eating, smoking and using the toilet. 9. PHYSICAL AND CHEMICAL PROPERTIES: APPEARANCE: Liquid. Clear. COLOUR: Amber. ODOUR/TASTE: Characteristic. SOLUBILITY DESCRIPTION: Insoluble in water. Soluble in: Hydrocarbons. BOILING POINT ( C, interval): 190-250 PRESSURE: 760mmHg MELT./FREEZ. POINT ( C, interval): <0 DENSITY/SPECIFIC GRAVITY (g/ml): 0.92 TEMPERATURE ( C): 20 VAPOUR DENSITY (air=1): >1 VISCOSITY: 1000.00 cps TEMPERATURE ( C): 20 FLASH POINT ( C): >63 METHOD: P/M Pensky-Martens. AUTO IGNITION TEMP. ( C): ~220 FLAMMABILITY LIMIT - LOWER(%): 0.6 FLAMMABILITY LIMIT - UPPER(%): 8.0 PARTITION COEFF. (log Pow): >3 10. STABILITY AND REACTIVITY: STABILITY: Normally stable. CONDITIONS TO AVOID: Avoid contact with strong oxidisers. HAZARDOUS POLYMERIZATION: Will not polymerize. HAZARDOUS DECOMP. PRODUCTS: High temperatures generate: Oxides of: Nitrogen. 11. TOXICOLOGICAL INFORMATION: INHALATION: INGESTION: SKIN: EYES: Liquid inhaled in the form of fine droplet sprays or, mists or aerosols or aspirated during vomiting may cause chemical pneumonitis. May cause gastrointestinal irritation. Irritating to skin. Irritating to eyes. 12. ECOLOGICAL INFORMATION: ECOLOGICAL INFORMATION: 72hr EC50 (Skeletonema costatum) >750 mg/l 48hr LC50 (Acartia tonsa) >740 mg/l 96hr LC50 (Scophthalamus maximus) >5600 mg/l 10 day LC50 (Corophium volutator) >390 mg/kg MOBILITY: This material is insoluble in water and will float on the surface of water. 3 / 5
BIO ACCUMULATION: Expected to have the potential for bioaccumulation. DEGRADABILITY: All organic components are biodegradable. ACUTE FISH TOXICITY: Not classified as harmful to aquatic organisms. 13. DISPOSAL CONSIDERATIONS: DISPOSAL METHODS: Dispose of unused material as Special (Hazardous) Waste. The recommended form of disposal is incineration by an approved chemical disposal firm. Dispose of using licenced waste hauliers and disposal contractors. 14. TRANSPORT INFORMATION: ROAD TRANSPORT: ROAD TRANSPORT NOTES: RAIL TRANSPORT: RAIL TRANSPORT NOTES: SEA TRANSPORT: SEA TRANSPORT NOTES: AIR TRANSPORT: AIR TRANSPORT NOTES: Not Classified for Road Transport Not Classified for Rail Transport Not Classified for Sea Transport Not Classified for Air Transport 15. REGULATORY INFORMATION: LABEL FOR SUPPLY: RISK PHRASES: SAFETY PHRASES: R-36/38 Irritating to eyes and skin. S-24/25 Avoid contact with skin and eyes. S-26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S-60 This material and its container must be disposed of as hazardous waste. 16. OTHER INFORMATION: REVISION COMMENTS: Sections changed since last update: 2, 5, 6, 8, 9, 10, 12, 13, 15. ISSUED BY: Melanie Thatcher (Tel 44-(0)1224-408173) REV. No./REPL. SDS GENERATED: 5 August 2002 R-PHRASES (Full Text) R-36/38 Irritating to eyes and skin. R-66 Repeated exposure may cause skin dryness or cracking. R-65 Harmful: may cause lung damage if swallowed. 4 / 5
DISCLAIMER: THIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS, TO THE REST OF THE COMPANY'S KNOWLEDGE AND BELIEF, ACCURATE AND RELIABLE AS OF THE DATE INDICATED. HOWEVER, NO WARRANTY, GUARANTEE OR REPRESENTATION IS MADE AS TO ITS ACCURACY, RELIABILITY OR COMPLETENESS. IT IS THE USER'S RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITABILITY OF SUCH INFORMATION FOR HIS OWN PARTICULAR USE. 5 / 5