1 Identification of the substance/mixture and of the company/undertaking Product identifier Relevant identified uses of the substance or mixture and uses advised against Application of the substance / the preparation Details of the supplier of the safety data sheet Manufacturer/Supplier: Information department: Emergency telephone number: 2 Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC Classification system: Label elements GHS label elements Hazard pictograms Signal word Hazard-determining components of labelling: Hazard statements Precautionary statements
Additional information: Classification system NFPA ratings (scale 0-4) 3 0 1 HMIS HEALTH FIRE REACTIVITY 3 0 1 Other hazards Results of PBT and vpvb assessment PBT: vpvb: 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Dangerous components: Additional information 4 First aid measures Description of first aid measures General information After inhalation
After skin contact After eye contact After swallowing Most important symptoms and effects, both acute and delayed Indication of any immediate medical attention and special treatment needed 5 Firefighting measures Extinguishing media Suitable extinguishing agents For safety reasons unsuitable extinguishing agents Special hazards arising from the substance or mixture Advice for firefighters Protective equipment: Additional information 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Environmental precautions: Methods and material for containment and cleaning up: Reference to other sections 7 Handling and storage Precautions for safe handling
Information about protection against explosions and fires: Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and receptacles: Information about storage in one common storage facility: Further information about storage conditions: Specific end use(s) 8 Exposure controls/personal protection Additional information about design of technical systems: Control parameters Components with limit values that require monitoring at the workplace: 1310-73-2 Sodium hydroxide Additional information: Exposure controls Personal protective equipment General protective and hygienic measures Breathing equipment: Protection of hands: Material of gloves Penetration time of glove material Eye protection: Body protection:
9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Color: Odor: Odor threshold: ph-value: Change in condition Melting point/melting range: Boiling point/boiling range: Flash point: Flammability (solid, gaseous) Ignition temperature: Decomposition temperature: Auto igniting: Danger of explosion: Explosion limits: Lower: Upper: Oxidizing properties Vapor pressure: Density: Solubility in / Miscibility with Water: Viscosity: dynamic: kinematic: Other information 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: Possibility of hazardous reactions Conditions to avoid Incompatible materials: Hazardous decomposition products:
11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values that are relevant for classification: 497-19-8 Sodium carbonate 1310-73-2 Sodium hydroxide Primary irritant effect: on the skin: on the eye: Sensitization: Additional toxicological information: Carcinogenic categories IARC (International Agency for Research on Cancer) NTP (National Toxicology Program) 12 Ecological information Toxicity Aquatic toxicity: 497-19-8 Sodium carbonate 1310-73-2 Sodium hydroxide Persistence and degradability Bioaccumulative potential Mobility in soil Additional ecological information: General notes: Results of PBT and vpvb assessment PBT:
vpvb: Other adverse effects 13 Disposal considerations Waste treatment methods Recommendation Uncleaned packagings: Recommendation: Recommended cleansing agent: 14 Transport information UN-Number ADR, IMDG, IATA UN proper shipping name IMDG, IATA ADR Transport hazard class(es) DOT ADR 173.154 Exceptions for Class 8 (corrosive materials). Limited Quantities. (1) For corrosive materials in Packing Group II, inner packagings not over 1.0 L (0.3 gallon) net capacity each for liquids or not over 1.0 kg (2.2 pounds) net capacity each for solids, packed in a strong outer packaging. [ 173.154(b)(1)] Class Label IMDG, IATA Class Label Packing group DOT, ADR, IMDG, IATA Special precautions for user Danger code (Kemler): EMS Number: Segregation groups Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
UN "Model Regulation": 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Section 355 (extremely hazardous substances) TSCA (Toxic Substances Control Act) Cancerogenity categories MAK (German Maximum Workplace Concentration) National regulations Information about limitation of use: Disturbance regulations: Water hazard class: Other regulations, limitations and prohibitive regulations Chemical safety assessment: 16 Other information Abbreviations and acronyms: