SAFETY DATA SHEET ARBO CLEANER NO 13 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING PRODUCT NAME: ARBO CLEANER NO 13 PART No.: SUPPLIER: P2 Adshead Ratcliffe & Co. Ltd. Derby Road, Belper Derbyshire. DE56 1WJ Tel: (+44) 01773 826661 Fax: (+44) 01773 821215 2. COMPOSITION/INFORMATION ON INGREDIENTS NAME CAS No.: 108-88-3 EINECS Nr.: CLASSIFICATION 203-625-9 Xn,F R-11, 20 CONTENT 60-100 % The Full Text for all R-Phrases are Displayed in Section 16 3. HAZARDS IDENTIFICATION Highly flammable. Harmful by inhalation. 4. FIRST AID MEASURES GENERAL: INHALATION: INGESTION: SKIN: EYES: Consult a physician for specific advice. Move the exposed person to fresh air at once. Perform artificial respiration if breathing has stopped. When breathing is difficult, properly trained personnel may assist affected person by administering 100% oxygen. Keep the affected person warm and at rest. Get prompt medical attention. DO NOT induce vomiting. Get medical attention immediately. Promptly get affected personnel to drink large volumes of water to dilute the swallowed chemical. Remove affected person from source of contamination. Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove clothing if soaked through and wash as above. Get medical attention if any discomfort continues. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. 1/5
5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA: SPECIAL FIRE FIGHTING PROCEDURES: UNUSUAL FIRE & EXPLOSION HAZARDS: Water spray, fog or mist. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. Keep run-off water out of sewers and water sources. Dike for water control. Cool containers exposed to flames with water until well after the fire is out. Move container from fire area if it can be done without risk. If risk of water pollution occurs, notify appropriate authorities. May explode in a fire. May develop highly toxic or corrosive fumes if heated. May explode when heated or when exposed to flames or sparks. May travel considerable distance to source of ignition and flash back. Vapour explosion and poison hazard indoors, outdoors and in sewers. 6. ACCIDENTAL RELEASE MEASURES SPILL CLEANUP METHODS: Provide ventilation and confine spill. Do not allow runoff to sewer. Absorb in vermiculite, dry sand or earth and place into containers. Clean-up personnel should use respiratory and/or liquid contact protection. Absorb small quantities with paper towels and evaporate in safe place (fume hood). Allow sufficient time for vapours to completely clear the hood ducts, then burn the paper in a location away from combustible materials. 7. HANDLING AND STORAGE USAGE PRECAUTIONS: STORAGE PRECAUTIONS: STORAGE CRITERIA: Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Avoid acids, moisture, and combustible materials. Wear full protective clothing for prolonged exposure and/or high concentrations. Flammable/combustible - Keep away from oxidizers, heat and flames. May attack some plastics, rubber and coatings. Keep in cool, dry, ventilated storage and closed containers. Ground container and transfer equipment to eliminate static electric sparks. Flammable liquid storage. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION INGREDIENT NAME: CAS No.: STD LT EXP 8 Hrs ST EXP 15 Min 108-88-3 OES 50 ppm(sk) 150 ppm(sk) VENTILATION: PROTECTIVE GLOVES: EYE PROTECTION: OTHER PROTECTION: HYGIENIC WORK PRACTICES: Provide adequate general and local exhaust ventilation. Use protective gloves made of: Polyvinyl alcohol (PVA). Viton rubber (fluor rubber). P.T.F.E (Teflon). Wear approved safety goggles. Use engineering controls to reduce air contamination to permissible exposure level. Provide eyewash, quick drench. Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes contaminated. Promptly remove any clothing that becomes contaminated. Isolate contaminated clothing and wash before reuse. 2/5
9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: COLOUR: ODOUR/TASTE: Liquid. Clear. Colourless. Aromatic. MOL. WEIGHT: 92.15 BOILING POINT ( C, interval): MELT./FREEZ. POINT ( C, interval): ~ 110 Pressure: ~ -95 DENSITY/SPECIFIC GRAVITY 0.87 Temperature ( C): 20 (g/ml): VAPOUR DENSITY (air=1): 3.14 VAPOUR PRESSURE: EVAPORATION RATE: SOLUBILITY DESCRIPTION: 36.7 mmhg Temperature ( C): 30 2.24 Reference: Insoluble in water. Soluble in: Acetone. Miscible with: Alcohol. Chloroform. Ether. SOLUBILITY VALUE (g/100g H2O 20 C): 0.05 ODOUR THRESHOLD, LOWER: 5.00 FLASH POINT ( C): ~ 4 Method: CC (Closed cup). AUTO IGNITION TEMP. ( C): 535 FLAMMABILITY LIMIT - LOWER(%): FLAMMABILITY LIMIT - UPPER(%): 1.27 7.10 10. STABILITY AND REACTIVITY STABILITY: MATERIALS TO AVOID: HAZARDOUS DECOMP. PRODUCTS: Avoid: Heat, sparks, flames. Moisture. NITROGEN DIOXIDE Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). 11. TOXICOLOGICAL INFORMATION TOXIC DOSE - LD 50: 5000 mg/kg (oral rat) HEALTH WARNINGS: ROUTE OF ENTRY: TARGET ORGANS: MEDICAL SYMPTOMS: Gas or vapour is toxic or extremely irritating even on brief exposure. This chemical may cause skin/eye irritation and burns (corrosive). Toxic through skin absorption (percutaneous). Narcotic effect. CNS depressant. INGESTION. May cause severe internal injury. Inhalation. Skin absorption. Ingestion. Skin and/or eye contact. Blood. Central nervous system. Eyes. Kidneys. Liver. Respiratory system, lungs. Skin. Extreme irritation of eyes and mucous membranes, including burning and tearing. Dilated pupils. May cause suffocation. Severe skin irritation. Nausea, vomiting. 3/5
MEDICAL CONSIDERATIONS: Unconsciousness, possibly death. Central nervous system depression. Drowsiness, dizziness, disorientation, vertigo. Behavioral changes. Hypotension (low blood pressure). Skin disorders and allergies. Convulsive disorders, CNS problems. 12. ECOLOGICAL INFORMATION LC 50, 96 HRS, FISH mg/l: DEGRADABILITY: N/D Readily eliminated. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHODS: Dispose of in accordance with Local Authority requirements. Absorb in vermiculite or dry sand, dispose in licensed special waste. 14. TRANSPORT INFORMATION LABEL FOR CONVEYANCE: UN No. ROAD: 1294 UK ROAD TRANSPORT CLASS: 3 ADR CLASS No.: 3 ADR CLASS: HAZARD No. (ADR): Class 3: Flammable liquids. 33 Highly flammable liquid (flash-point below 23 C). ADR LABEL No.: 3 HAZCHEM CODE: PROPER SHIPPING NAME I: 3[Y]E RID CLASS No.: 3 UN No. SEA: 1294 IMDG CLASS: 3 IMDG PACK GR.: II EmS No.: 3-07 4/5
MARINE POLLUTANT: No. ICAO CLASS: 3 AIR PACK GR.: II 15. REGULATORY INFORMATION LABEL FOR SUPPLY: CONTAINS RISK PHRASES: SAFETY PHRASES: STATUTORY INSTRUMENTS: GUIDANCE NOTES: R-11 Highly flammable. R-20 Harmful by inhalation. S-16 Keep away from sources of ignition - No Smoking. S-2 Keep out of the reach of children. S-46 If swallowed, seek medical advice immediately and show this container or label. S-51 Use only in well-ventilated areas. Chemicals (Hazard Information and Packaging) Regulations. Occupational Exposure Limits EH40. CHIP for everyone HSG(108). 16. OTHER INFORMATION REVISION DATE: 03/12/02 REV. No./REPL. SDS GENERATED: 28/11/02 SDS No.: 10070 R-PHRASES (Full Text): DISCLAIMER: R-11 Highly flammable. R-20 Harmful by inhalation. The information contained herein is derived from the best available sources and is believed to be accurate. However, no guarantee is expressed or implied regarding the accuracy of the data given in the use of this product. 5/5