INF.41/Add.1/Rev.1. Economic Commission for Europe Inland Transport Committee

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Economic Commission for Europe Inland Transport Committee Working Party on the Transport of Dangerous Goods INF.41/Add.1/Rev.1 Joint Meeting of the RID Committee of Experts and the Working Party on the Transport of Dangerous Goods 26 September 2017 Geneva, 19 29 September 2017 Item 7 of the provisional agenda Reports of informal working groups Follow up to the work of the informal working group on reducing the risk of a BLEVE simulations of the behaviour of tanks exposed to fire in complement to document ECE/TRANS/WP.15/AC.1/2017/42 Transmitted by the Government of France

Model for the thermal response of Liquefied Petroleum Gas Tanks subjected to accidental heat input Emilie RASOOLY - Adrien WILLOT Etienne CATRY INERIS Structural Resistance Unit Accidental Risk Division RID ADR JOINT MEETING 09-2017 DRA-17-164468-08069A

Summary Introduction Tank subjected to full fire engulfment Evaluation of a valve efficiency Evaluation of thermal coating and increased steel thickness Conclusion on the PRV/thermal coating efficiency Calculation on tanks subjected to fire on lower part New calculation assumptions Calculation results Calculation analysis Conclusion DRA-17-164468-08069A 2

MPa Introduction Reminder of previous work: reliability of the model demonstrated Previous work [1]: development of a predictive tool to study the behaviour of different configurations tanks demonstration of reliability of the model by comparison with BAM experiments (2013) BLEVE time Behavior diagram of the tank [1] Working Party on the Transport of Dangerous Goods, Bern, 13 17 March 2017 DRA-17-164468-08069A 3

Tank subjected to full fire engulfment Evaluation of a valve efficiency - Calculation results Reminder: these results have been presented at RID ADR Joint meeting 03-2017 Common PRV considered (diameter 2 and P opening 16.5 bar) on LPG tank: volume 31m 3, filling rate 50% Thermal loading : full fire engulfment => Safety valve is not efficient in that case Full fire engulfment Results considering a common safety valve : risk of BLEVE DRA-17-164468-08069A 4

Tank subjected to full fire engulfment Evaluation of a valve efficiency - Calculation results Test of an ideal safety valve on the same tank with the same thermal loading This safety valve set to low pressure (8 bar) is not efficient: A very low applied stress is observed as expected Failure is due to a sharp fall of Yield stress of steel This result can be generalized to all filling rate Results considering an ideal safety valve (set to 8 bar) : risk of BLEVE due to sharp fall of Yield stress of steel DRA-17-164468-08069A 5

Tank subjected to full fire engulfment Evaluation of thermal coating and increased steel thickness - Calculation results 2 other protections are tested : thermal coating and increasing steel thickness of shell to 3 cm Thermal coating can avoid or delay BLEVE but several issues are raised concerning use on trucks: no retrofit about ageing behaviour with vibrations behaviour with various climatic conditions etc Increasing steel thickness of shell is efficient to avoid BLEVE, but 3 cm thick shell are needed (unfeasible) Results considering a thermal coating : no risk of BLEVE Results considering a 3 cm thick shell : no risk of BLEVE DRA-17-164468-08069A 6

Conclusion about tanks subjected to full fire engulfment Conclusion on the PRV/thermal coating efficiency (RID ADR Joint meeting 03-2017) Valves are not efficient for some scenarios (ex: full fire engulfment) Other protections (thermal coating or increasing of shell thickness) may delay/avoid BLEVE but may present issues (ageing, cost, etc ) Full fire engulfment DRA-17-164468-08069A 7

Calculation on tanks subjected to fire on lower part New calculation assumptions Calculations led on tanks with safety valve only and subjected to a smaller size fire (localized on lower part of tank) New calculations are therefore led considering a smaller size fire scenario with the following conservative parameters: Pool fire on lower part of tank Fire reaches immediately intense burning on the entire length of the truck and has an infinite duration (a real fire can have a duration of 3 hours, and an intense burning of 30 minutes) Large fire localized on lower half of tank - Conservative hypothesis- Calculation of real fire spreading [2] [2] CFPB, Feu de pneus et de cabines sur des citernes GPL, Mai 2010 DRA-17-164468-08069A 8

Calculation on tanks subjected to fire on lower part New calculation assumptions Characteristics of the LPG tanks (same as those considered at RID ADR Joint meeting 03-2017): Volume: 31 m 3 Common PRV pressure relief valve- (diameter: 2 & Popening: 16.5 bar) 3 scenarios are calculated for 3 filling rates (great influence on results): 85%, 50% and 30% Example of heating of a tank filling rate: 30 % DRA-17-164468-08069A 9

Calculation on tanks subjected to fire on lower part Calculation results 85 % 50 % Filling rate: 85 % -safety valve efficient no BLEVE Filling rate: 50 % - safety valve NOT efficient, BLEVE 30 % Filling rate: 30 % - safety valve NOT efficient, BLEVE DRA-17-164468-08069A 10

Calculation on tanks subjected to fire on lower part Calculation analysis Previous results show the great influence of filling rate on results The impact of filling rate is explained below: Large Fire on liquid phase (Pool fire) Filling rate: 85% Filling rate: 30% FIRE The steel shell in contact with the gas phase is not impacted by the fire In that case, most of blast scenarios can be excluded with a standard PRV FIRE The steel shell in contact with the gas phase is impacted by the fire In that case, the blast risk is high (included case where the tank is equipped with an ideal PRV) DRA-17-164468-08069A 11

Conclusion Full fire engulfment: Safety valve only can not protect tank because of mainly the reduction in the steel resistance due to high temperature Tank with an appropriate safety valve and a thermal coating could survive a full fire engulfment until it empties completely Fire on lower part only tank equipped with a common pressure relief valve : Pressure relief valve may avoid or delay BLEVE for tank with high filling rate BLEVE may occur for low filling rate, due to heating of shell in direct contact with gas Way forward: Assess the maximal fire a tank equipped with the best safety valve would survive even under low (unfavorable) filling ratio conditions Compare this fire with the fire most likely to happen. This «typical» fire can be estimated thanks to: Refined modeling of fire using a computational fluid dynamics software (FDS Fire Dynamics Simulator) to obtain better precision on distribution of heat fluxes for 3D tank modeling Statistical assessment to estimate the most likely fire hypothesis This will allow to assess the efficiency of safety valves in terms of risk reduction even if they would not ensure total resistance to fire in 100% of the cases DRA-17-164468-08069A 12