SECTION 1: Product and company identification Product name : Fly Away Wipes Insect Repellant Use of the substance/mixture : Premoistened wipe Product code : 1541 Company : Total Solutions P.O. Box 240014 Milwaukee, WI 53224 - USA T (414) 354-6417 Emergency number : Chemtec: (800) 424-9300 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Skin Irrit. 2 H315 Eye Irrit. 2A H319 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) Not applicable GHS07 : Warning : Causes skin irritation Causes serious eye irritation SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable Full text of H-phrases: see section 16 : Wash thoroughly after handling Wear eye protection, face protection, protective gloves If on skin: Wash with plenty of soap and water If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Specific treatment (see First aid measures on this label) If skin irritation occurs: Get medical advice/attention If eye irritation persists: Get medical advice/attention Take off contaminated clothing and wash before reuse 3.2. Mixture Name Product identifier % Classification (GHS-US) N,N-diethyl-m-toluamide, deet (CAS No) 134-62-3 10-30 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove the victim into fresh air. First-aid measures after skin contact : Rinse skin with water/shower. First-aid measures after eye contact : Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. First-aid measures after ingestion : Rinse mouth with water. Do NOT induce vomiting. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. Date of issue: 2/16/2016 Revision date: 02/12/2016 Version: 1.1 P GHS SDS Page 1 of 5
Symptoms/injuries after inhalation : None under normal use. Symptoms/injuries after skin contact : Contact during a long period may cause light irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms/injuries after ingestion : Gastrointestinal complaints. 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media 5.2. Special hazards arising from the substance or mixture Reactivity : Upon combustion: CO and CO2 are formed. 5.3. Advice for firefighters Firefighting instructions : Exercise caution when fighting any chemical fire. Use water spray or fog for cooling exposed containers. Take account of environmentally hazardous firefighting water. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Isolate from fire, if possible, without unnecessary risk. 6.1.1. For non-emergency personnel Protective equipment : Protective goggles. Gloves. Protective clothing. Emergency procedures : Evacuate unnecessary personnel. Avoid contact with skin, eyes and clothing. Ventilate spillage area. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Stop leak if safe to do so. Stop release. Ventilate area. 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. 6.3. Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Methods for cleaning up : This material and its container must be disposed of in a safe way, and as per local legislation. 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Comply with the legal requirements. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Do not eat, drink or smoke when using this product. Do not get in eyes, on skin, or on clothing. Hygiene measures : Wash thoroughly after handling. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Keep container closed when not in use. Storage area : Meet the legal requirements. Store in a cool area. Store in a well-ventilated place. Special rules on packaging : meet the legal requirements. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment : Use appropriate personal protective equipment when risk assessment indicates this is necessary. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Premoistened wipe. Date of issue: 2/16/2016 Revision date: 02/12/2016 Version: 1.1 P GHS SDS Page 2 of 5
Odor Odor threshold ph Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure Relative density Relative vapor density at 20 C Specific gravity / density Solubility Log Pow Log Kow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic VOC content SECTION 10: Stability and reactivity 10.1. Reactivity Upon combustion: CO and CO2 are formed. 10.2. Chemical stability 10.3. Possibility of hazardous reactions Refer to section 10.1 on Reactivity. 10.4. Conditions to avoid 10.5. Incompatible materials : Mild odor : 1 g/ml -Tested using the liquid component of the towelette : Liquid component is soluble in water : 0 % -Tested using the liquid component of the towelette 10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified N,N-diethyl-m-toluamide, deet (134-62-3) ATE CLP (oral) 500.000 mg/kg body weight Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after inhalation : Not classified : Not classified : None under normal use. Date of issue: 2/16/2016 Revision date: 02/12/2016 Version: 1.1 P GHS SDS Page 3 of 5
Symptoms/injuries after skin contact Symptoms/injuries after eye contact Symptoms/injuries after ingestion SECTION 12: Ecological information 12.1. Toxicity 12.2. Persistence and degradability 12.3. Bioaccumulative potential SECTION 13: Disposal considerations : Contact during a long period may cause light irritation. : Causes serious eye irritation. : Gastrointestinal complaints. 13.1. Waste treatment methods Waste treatment methods : Do not flush wipes. Waste disposal recommendations : Dispose of contents/container to local/regional/national regulations. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT : Not regulated for transport Additional information Other information : No supplementary information available. ADR Transport by sea Air transport SECTION 15: Regulatory information All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR 372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. California Proposition 65 - This product does not contain substances known to the state of California to cause cancer and/or reproductive toxicity This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labelling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: WARNING Causes substantial but temporary eye injury. Harmful if swallowed. Do not get in eyes. Use of this product may cause skin reactions in rare cases. Wash treated clothing before wearing it again. Wash hands before eating, drinking, chewing gum, using tobacco or using the toilet. SECTION 16: Other information Training advice : Normal use of this product shall imply use in accordance with the instructions on the packaging. Full text of H-phrases: ------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ H302 Harmful if swallowed ------ H315 Causes skin irritation ------ H319 Causes serious eye irritation Date of issue: 2/16/2016 Revision date: 02/12/2016 Version: 1.1 P GHS SDS Page 4 of 5
NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 0 - Materials that will not burn. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. Prepared by: Technical Department This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. No warranty is expressed or implied regarding the accuracy of this data or the results obtained from the use thereof. Our company assumes no responsibility for personal injury or property damage to the vendee, users or third parties caused by the material. Such vendees or users assume all risks associated with the use of this material. Date of issue: 2/16/2016 Revision date: 02/12/2016 Version: 1.1 P GHS SDS Page 5 of 5