Revision Date 19/01/2012 Revision 3.0 Supersedes date 07/07/10 SAFETY DATA SHEET SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Internal Id A087 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Silicone oil. 1.3. Details of the supplier of the safety data sheet Supplier ARROW SOLUTIONS RAWDON ROAD MOIRA SWADLINCOTE DERBYSHIRE DE12 6DA TEL: +44 (0)1283 221044 EMERGENCY: +44 (0) 777 8505 330 FAX: +44 (0)1283 225731 sales@arrowchem.com 1.4. Emergency telephone number +44 (0) 777 8505 330 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) F+;R12. R52/53, R67, R66. 2.2. Label elements Labelling Extremely flammable Risk Phrases Safety Phrases R12 Extremely flammable. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R67 Vapours may cause drowsiness and dizziness. R66 Repeated exposure may cause skin dryness or cracking. A1 Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. A2 Do not spray on a naked flame or any incandescent material. S9 Keep container in a well-ventilated place. S16 Keep away from sources of ignition - No smoking. S23 Do not breathe vapour/spray. 1 / 6
S37 S35 S51 Wear suitable gloves. This material and its container must be disposed of in a safe way. Use only in well-ventilated areas. 2.3. Other hazards SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures HYDROCARBON PROPELLANT 60-100% CAS-No.: 68476-85-7 EC No.: 270-704-2 Classification (EC 1272/2008) Flam. Gas 1 - H220 Classification (67/548/EEC) F+;R12. NAPHTHA (PETROLEUM) HYDROTREATED LIGHT 10-30% CAS-No.: 64742-49-0 EC No.: 265-151-9 Classification (EC 1272/2008) Flam. Liq. 2 - H225 Skin Irrit. 2 - H315 STOT Single 3 - H336 Asp. Tox. 1 - H304 Aquatic Chronic 2 - H411 Classification (67/548/EEC) Xn;R65. Xi;R38. F;R11. N;R51/53. R67. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation Move the exposed person to fresh air at once. Provide rest, warmth and fresh air. Ingestion Rinse mouth thoroughly. DO NOT induce vomiting. Get medical attention immediately. Skin contact Wash skin thoroughly with soap and water. Get medical attention if irritation persists after washing. Eye contact Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. 4.2. Most important symptoms and effects, both acute and delayed Inhalation. Drowsiness, dizziness, disorientation, vertigo. Ingestion Due to the physical nature of this material it is unlikely that swallowing will occur. Skin contact Prolonged contact may cause redness, irritation and dry skin. Eye contact Irritation of eyes and mucous membranes. 4.3. Indication of any immediate medical attention and special treatment needed No recommendation given, but first aid may still be required in case of accidental exposure, inhalation or ingestion of this chemical. If in doubt, GET MEDICAL ATTENTION PROMPTLY! SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media 2 / 6
Extinguishing media Fire can be extinguished using: Foam, carbon dioxide or dry powder. 5.2. Special hazards arising from the substance or mixture Unusual Fire & Explosion Hazards Aerosol cans may explode in a fire. 5.3. Advice for firefighters Special Fire Fighting Procedures Use water to keep fire exposed containers cool and disperse vapours. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Do not smoke, use open fire or other sources of ignition. 6.2. Environmental precautions Do not discharge onto the ground or into water courses. 6.3. Methods and material for containment and cleaning up Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb spillage with non-combustible, absorbent material. 6.4. Reference to other sections SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Keep away from heat, sparks and open flame. Avoid contact with skin and eyes. Provide good ventilation. 7.2. Conditions for safe storage, including any incompatibilities Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50 C. 7.3. Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes HYDROCARBON PROPELLANT WEL 600 ppm 1430 mg/m3 750 ppm 1780 mg/m3 NAPHTHA (PETROLEUM) HYDROTREATED LIGHT WEL 1000 mg/m3 No std. WEL = Workplace Exposure Limit. 8.2. Exposure controls Engineering measures No specific ventilation requirements noted, except this product must not be used in a confined space without good ventilation. Respiratory equipment In case of inadequate ventilation use suitable respirator. Hand protection Chemical resistant gloves required for prolonged or repeated contact. Use protective gloves made of: Rubber, neoprene or PVC. Eye protection Wear approved chemical safety goggles where eye exposure is reasonably probable. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Aerosol. Odour Solvent. 3 / 6
Solubility 9.2. Other information No information required. Insoluble in water SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity No specific reactivity hazards associated with this product. 10.2. Chemical stability Stable under normal temperature conditions and recommended use. 10.3. Possibility of hazardous reactions Not known. 10.4. Conditions to avoid Avoid heat, flames and other sources of ignition. 10.5. Incompatible materials Materials To Avoid No incompatible groups noted. 10.6. Hazardous decomposition products Fire or high temperatures create: Oxides of: Carbon. Hydrocarbons. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects Medical Symptoms EYES AND MUCOUS MEMBRANES. Irritation of eyes and mucous membranes. RESPIRATORY SYSTEM. Upper respiratory irritation. SKIN. Skin irritation. NOSE. Irritation of nose due to vapour or dust contact. DIGESTIVE SYSTEM. Gastrointestinal symptoms, including upset stomach. NERVOUS SYSTEM. Drowsiness, dizziness, disorientation, vertigo. Mild intoxication (incl. fatigue, lassitude, irritability, headache, nausea). SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Dangerous for the environment: May cause long-term adverse effects in the aquatic environment. 12.1. Toxicity Acute Toxicity - Fish Not determined. Acute Toxicity - Aquatic Invertebrates Not determined. 12.2. Persistence and degradability Degradability The product is expected to be biodegradable. 12.3. Bioaccumulative potential Bioaccumulative potential The product is not bioaccumulating. 12.4. Mobility in soil Mobility: The product contains volatile organic compounds (VOC) which will evaporate easily from all surfaces. The product has poor water-solubility. 12.5. Results of PBT and vpvb assessment 12.6. Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS 4 / 6
General information Do not puncture or incinerate even when empty. 13.1. Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION 14.1. UN number UN No. (ADR/RID/ADN) 1950 14.2. UN proper shipping name Proper Shipping Name AEROSOLS 14.3. Transport hazard class(es) ADR/RID/ADN Class Class 2: Gases IMDG Class 2 ICAO Class/Division 2 Transport Labels FLAMMABLE GAS 2 14.4. Packing group ADR/RID/ADN Packing group 5F 14.5. Environmental hazards 14.6. Special precautions for user Tunnel Restriction Code (D) 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory References Chemicals (Hazard Information & Packaging) Regulations. Statutory Instruments Control of Substances Hazardous to Health. Approved Code Of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes Workplace Exposure Limits EH40. EU Legislation Dangerous Preparations Directive 1999/45/EC. 15.2. Chemical Safety Assessment SECTION 16: OTHER INFORMATION Revision Date 19/01/2012 Revision 3.0 Supersedes date 07/07/10 Date 11/09/2007 5 / 6
Risk Phrases In Full R12 R65 R11 R38 R51/53 R67 Hazard Statements In Full H220 H225 H304 H315 H336 H411 Extremely flammable. Harmful: may cause lung damage if swallowed. Highly flammable Irritating to skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Vapours may cause drowsiness and dizziness. Extremely flammable gas. Highly flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness. Toxic to aquatic life with long lasting effects. Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6 / 6