: Airco Fresh (Aerosol)

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Transcription:

MSDS Version: E03.00 Date of issue: 12/02/2015 Blend Version: 5 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Airco Fresh (Aerosol) Product code : W30202 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Use of the substance/mixture Function or use category : Antiseptic product for air conditioning. : Aerosol propellants 1.2.2. Uses advised against 1.3. Details of the supplier of the safety data sheet Wynn's Belgium Industriepark-West 46 9100 Sint-Niklaas - Belgium T +32 3 766 60 20 - F +32 3 778 16 56 msds@wynns.eu - www.wynns.be 1.4. Emergency telephone number Emergency number : BIG: +32(0)14/58.45.45 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Aerosol 3 Full text of H-statements: see section 16 H229 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Signal word (CLP) Hazard statements (CLP) EUH-statements Precautionary statements (CLP) : Warning : H229 - Pressurised container: May burst if heated : EUH208 - Contains 1,2-Benzisothiazol-3(2H)-one. May produce an allergic reaction : P102 - Keep out of reach of children P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P251 - Do not pierce or burn, even after use P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 C/122 F Detergent Regulation : Labelling of contents:(regulation (EC) No. 648/2004 of 31 March 2004 on detergents): Component % non-ionic surfactants <5% BENZISOTHIAZOLINONE 2.3. Other hazards 18/08/2015 EN (English) 1/7

SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % w Classification according to Directive 67/548/EEC 2-(2-butoxyethoxy)ethanol (CAS No) 112-34-5 (EC no) 203-961-6 (EC index no) 603-096-00-8 (REACH-no) 01-2119475104-44 1-2,5 Xi; R36 Name Product identifier % w Classification according to Regulation (EC) No. 1272/2008 [CLP] 2-(2-butoxyethoxy)ethanol (CAS No) 112-34-5 (EC no) 203-961-6 (EC index no) 603-096-00-8 (REACH-no) 01-2119475104-44 Full text of R- and H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 1-2,5 Eye Irrit. 2, H319 : Check the vital functions. Keep victim at rest in half upright position. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Keep watching the victim. Give psychological aid. Prevent cooling by covering the victim (no warming up). Keep the victim calm, avoid physical strain. If necessary seek medical advice. : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. If skin irritation or rash occurs: Get medical advice/attention. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell. As it is a spray can packaging it is most unlikely that large quantities will be swallowed. 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : All extinguishing agents can be used. 5.2. Special hazards arising from the substance or mixture Fire hazard Explosion hazard Reactivity : None to our knowledge. If there is a fire close by, use suitable extinguishing agents. as flammable aerosol. : Heating may cause an explosion. : Product is not explosive. Pressurised container: May burst if heated. 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Cool closed containers exposed to fire with water spray. Physical explosion risk: extinguish/cool from behind cover. : Do not enter fire area without proper protective equipment, including respiratory protection. 18/08/2015 EN (English) 2/7

SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Protective equipment Emergency procedures 6.1.2. For emergency responders Emergency procedures : Gloves. Safety glasses. : Mark the danger area. Exposure to fire/heat: keep upwind. Close doors and windows of adjacent premises. Wash contaminated clothes. : Ventilate area. 6.2. Environmental precautions Prevent soil and water pollution. Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Technical measures Maximum storage period : Small quantities of liquid spill: take up in non-combustible absorbent material and shovel into container for disposal. Scoop absorbed substance into closing containers. Wash clothing and equipment after handling. : Meets the legal requirements. IF ON SKIN: Wash with plenty of soap and water. Presents no particular risk when handled in accordance with good occupational hygiene practice. : Use good personal hygiene practices. IF ON SKIN: Wash with plenty of soap and water. Wash contaminated clothing before reuse. : Keep out of frost. : 24 months Storage temperature : <= 45 C Heat and ignition sources Prohibitions on mixed storage Storage area Special rules on packaging Packaging materials 7.3. Specific end use(s) Observe instructions for use. : Keep away from heat. : Keep away from strong acids and strong oxidizers. : Meets the legal requirements. Store in a dry place. Protect from heat and direct sunlight. Keep container tightly closed in a cool, well-ventilated place. : Meets the legal requirements. correctly labelled. : Pressurised small gas containers (aerosol cans). SECTION 8: Exposure controls/personal protection 8.1. Control parameters 2-(2-butoxyethoxy)ethanol (112-34-5) EU IOELV TWA (mg/m³) 67,5 mg/m³ EU IOELV TWA (ppm) 10 ppm EU IOELV STEL (mg/m³) 101,2 mg/m³ EU IOELV STEL (ppm) 15 ppm Belgium Limit value (mg/m³) 67,5 mg/m³ Belgium Limit value (ppm) 10 ppm Belgium Short time value (mg/m³) 101,2 mg/m³ Belgium Short time value (ppm) 15 ppm France VLE (mg/m³) 67,5 mg/m³ France VLE (ppm) 10 ppm France VME (mg/m³) 101,2 mg/m³ France VME (ppm) 15 ppm 18/08/2015 EN (English) 3/7

8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Does not require any specific or particular technical measures. : Gloves. Safety glasses. Materials for protective clothing Hand protection Other information : None under normal conditions. : PVC (Polyvinyl chloride). Nitrile rubber. Neoprene. Choosing the proper glove is a decision that depends not only on the type of material, but also on other quality features, which differ for each manufacturer. : Breakthrough time : >30'. Thickness of the glove material >0.1 mm. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Appearance Colour Odour Odour threshold : Liquid : Clear. Liquid under pressure. : light blue. ph : 9,33 Relative evaporation rate (butylacetate=1) refraction index : 1,337 Melting point Freezing point Boiling point : Almost odourless. Flash point : > 100 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density @20 C Solubility Log Pow Log Kow Viscosity, kinematic @40 C Viscosity, dynamic @40 C Viscosity : Viscosity Index : Explosive properties Oxidising properties Explosive limits 9.2. Other information : 1000 kg/m³ VOC content : 1,8 % Other properties : Soluble in water. : The aerosol has a system with two chambers. The inner chamber (pouch of foil) contains the product to be sprayed, without propellant gas. The pressurized air between the pouch of product and the can (outer chamber) exerts pressure on the pouch and makes sure that product comes out when pushing the actuator. 18/08/2015 EN (English) 4/7

Additional information : Physical and chemical properties of the active product without gas. The physical and chemical data in this section are typical values for this product and are not intended as product specifications. SECTION 10: Stability and reactivity 10.1. Reactivity Product is not explosive. Pressurised container: May burst if heated. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid 10.5. Incompatible materials 10.6. Hazardous decomposition products SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard ph: 9,33 ph: 9,33 SECTION 12: Ecological information 12.1. Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. 12.2. Persistence and degradability Airco Fresh (Aerosol) Persistence and degradability The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. 12.3. Bioaccumulative potential Airco Fresh (Aerosol) Bioaccumulative potential Not established. 12.4. Mobility in soil 18/08/2015 EN (English) 5/7

12.5. Results of PBT and vpvb assessment 12.6. Other adverse effects SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number UN-No. (ADR) : 1950 : Container under pressure. Do not drill or burn even after use. Remove to an authorized waste treatment plant. 14.2. UN proper shipping name Proper Shipping Name (ADR) Transport document description (ADR) : AEROSOLS : UN 1950 AEROSOLS, 2.2, (E) 14.3. Transport hazard class(es) Class (ADR) : 2 Danger labels (ADR) : 2.2 14.4. Packing group Not applicable 14.5. Environmental hazards Other information : No supplementary information available. 14.6. Special precautions for user 14.6.1. Overland transport Classification code (ADR) : 5A Special provisions (ADR) : 190, 327, 344, 625 Transport category (ADR) : 3 Tunnel restriction code (ADR) : E Limited quantities (ADR) : 1l Excepted quantities (ADR) : E0 14.6.2. Transport by sea EmS-No. (1) : F-D, S-U 14.6.3. Air transport Instruction "cargo" (ICAO) : 203 Instruction "passenger" (ICAO) : 203/Y203 14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code Not applicable SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations Contains no REACH substances with Annex XVII restrictions Airco Fresh (Aerosol) is not on the REACH Candidate List Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances VOC content : 1,8 % 18/08/2015 EN (English) 6/7

15.1.2. National regulations Water hazard class (WGK) : 1 - low hazard to waters 15.2. Chemical safety assessment SECTION 16: Other information Full text of R-, H- and EUH-statements: Aerosol 3 Aerosol, Category 3 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 H229 Pressurised container: May burst if heated H319 Causes serious eye irritation R36 Irritating to eyes Xi Irritant This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 18/08/2015 EN (English) 7/7