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Transcription:

Safety Data Sheet Page 1 of 6 LOCTITE 549 known as Loctite 549 SDS No. : 173075 V001.6 Revision: 11.08.2016 printing date: 29.01.2019 Section 1. Identification of the substance/preparation and of the company/undertaking Product name: LOCTITE 549 known as Loctite 549 Other means of identification: LOCTITE 549 250ML Product code: IDH247797 Recommended use of the chemical and restrictions on use Intended use: Adhesive Identification of manufacturer, importer or distributor Importer: Henkel Malaysia Sdn Bhd 46th Floor, Menara TM, Jalan Pantai Baharu, 59200 Kuala Lumpur, Malaysia. Phone :+ 603 22461000 Fax : + 60322461188 E-mail address of person responsible for Safety Data Sheet: Emergency information: ap-ua-psra.sea@henkel.com FOR EMERGENCIES ONLY (Spill, major leak, Fire, Exposure, or Accident). Call CHEMTREC: +1 703-741-5970 Section 2. Hazards identification GHS Classification: GHS label elements: Substance or mixture is not classified as hazardous according to Globally Harmonized System(GHS). Substance or mixture is not classified as hazardous according to Globally Harmonized System(GHS). Substance or Mixture: Mixture Declaration of hazardous chemical: Section 3. Composition / information on ingredients Hazard component CAS-No. Content GHS Classification 10-30 %

Page 2 of 6 Section 4. First aid measures Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air. If symptoms persist, seek medical advice. Rinse with running water and soap. Obtain medical attention if irritation persists. Rinse immediately with plenty of running water (for 10 minutes), seek medical attention from a specialist. Rinse mouth, drink 1-2 glasses of water, do not induce vomiting, consult a doctor. Indication of immediate medical attention and special treatment needed: See section: Description of first aid measures Section 5. Fire fighting measures Suitable extinguishing media: Specific hazards arising from the chemical: Special protection equipment and precautions for firefighters: Additional fire fighting advice: Carbon dioxide, foam, powder In the event of a fire, carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx) can be released. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray. Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Avoid skin and eye contact. Ensure adequate ventilation. Do not let product enter drains. For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Section 7. Handling and storage Handling: Storage: Use only in well-ventilated areas. Avoid skin and eye contact. Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation. Store in original containers at 8-21 C (46.4-69.8 F) and do not return residual materials to containers as contamination may reduce the shelf life of the bulk product.

Page 3 of 6 Components with specific control parameters for workplace: Section 8. Exposure controls / personal protection MICA, RESPIRABLE FRACTION MICA, RESPIRABLE FRACTION Time Weighted Average (TWA): mg/m 3 3 Remarks ACGIH Time Weighted Average (TWA): mg/m 3 3 Remarks MY OEL The value is for particulate matter containing no asbestos and <1% crystalline silica. Respiratory protection: Ensure adequate ventilation. An approved mask or respirator fitted with an organic vapour cartridge should be worn if the product is used in a poorly ventilated area Filter type: A (EN 14387) Hand protection: Chemical-resistant protective gloves (EN 374). Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374): nitrile rubber (NBR; >= 0.4 mm thickness) This information is based on literature references and on information provided by glove manufacturers, or is derived by analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced. Eye protection: Body protection: Engineering controls: Hygienic measures: Wear protective glasses. Protective eye equipment should conform to EN166. Wear suitable protective clothing. Protective clothing should conform to EN 14605 for liquid splashes or to EN 13982 for dusts. Ensure good ventilation/extraction. Good industrial hygiene practices should be observed. Wash hands before work breaks and after finishing work. Do not eat, drink or smoke while working. Section 9. Physical and chemical properties Appearance: Odor: Odor threshold (CA): ph: Melting point / freezing point: Specific gravity: Boiling point: Flash point: Evaporation rate: Flammability (solid, gas): Lower explosive limit: orange liquid characteristic Not determined > 100 C (> 212 F) > 100 C (> 212 F)

Page 4 of 6 Upper explosive limit: Vapor pressure: Vapor density: Density: Solubility: Partition coefficient: n- octanol/water: Auto ignition: Decomposition temperature: Viscosity: VOC content: (2010/75/EC) < 0.1 mm hg 1.25 g/cm3 < 3 % Section 10. Stability and reactivity Reactivity/Incompatible materials: Chemical stability: Conditions to avoid: Hazardous decomposition products: Reaction with strong acids. Reacts with strong oxidants. Stable under recommended storage conditions. No decomposition if used according to specifications. carbon oxides. nitrogen oxides Irritating organic vapours. Section 11. Toxicological information Inhalative toxicity: Symptoms of Overexposure: Acute toxicity estimate (ATE) : > 20 mg/l Exposure time: 4 h Test atmosphere: Vapor. Method: Calculation method Prolonged or repeated contact may cause skin irritation. Prolonged or repeated contact may cause eye irritation. Acute oral toxicity: Method LD50 > 5,000 mg/kg rat Section 12. Ecological information General ecological information: Ecotoxicity: Cured Loctite products are typical polymers and do not pose any immediate environmental hazards. Do not empty into drains / surface water / ground water. Toxicity: LC50 400 mg/l Acute Toxicity Study Fish Exposure time 48 h Leuciscus idus Method DIN 38412-15 EC50 2,808 mg/l

Page 5 of 6 Acute Toxicity Study Exposure time Method Acute Toxicity Study Exposure time Method Daphnia 24 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) EC0 1,000 mg/l Bacteria 30 min Section 13. Disposal considerations Product Method of disposal: Dispose of in accordance with local and national regulations. Contribution of this product to waste is very insignificant in comparison to article in which it is used Packaging Disposal of uncleaned packages: After use, tubes, cartons and bottles containing residual product should be disposed of as chemically contaminated waste in an authorised legal land fill site or incinerated. Dispose of in accordance with local and national regulations. Section 14. Transport information General information: Not hazardous according to RID, ADR, ADN, IMDG, IATA-DGR. Section 15. Regulatory information Regulatory Information: Occupational Safety and Health (Classification, Labelling and Safety Data Sheet of Hazardous Chemicals) Regulations 2013 [P.U.(A) 310/213] Industry Code of Practice on Chemicals Classification and Hazard Communication Global inventory status: Regulatory list TSCA AICS DSL ENCS (JP) KECI (KR) PICCS (PH) IECSC ISHL (JP) NZIOC Notification

Page 6 of 6 Section 16. Other information Disclaimer: This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular properties.