Acros Organics BVBA Company Identification: Janssen Pharmaceuticalaan 3a 2440 Geel, Belgium Acros Organics Company Identification: (USA)

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Material Safety Data Sheet 2-Chlorobenzoic acid, 98% Section 1 - Chemical Product and Company Identification MSDS Name: 2-Chlorobenzoic acid, 98% Catalog Numbers: 15924-0000, 15924-0050, 15924-1000, 15924-5000 Synonyms: OCBA Acros Organics BVBA Company Identification: Janssen Pharmaceuticalaan 3a 2440 Geel, Belgium Acros Organics Company Identification: (USA) One Reagent Lane Fair Lawn, NJ 07410 For information in the US, call: 800-ACROS-01 For information in Europe, call: +32 14 57 52 11 Emergency Number, Europe: +32 14 57 52 99 Emergency Number US: 201-796-7100 CHEMTREC Phone Number, US: 800-424-9300 CHEMTREC Phone Number, Europe: 703-527-3887 Hazard Symbols: Section 2 - Composition, Information on Ingredients CAS# Chemical Name: % EINECS# 118-91-2 2-Chlorobenzoic acid 98% 204-285-4 XI Risk Phrases: 36/37/38 Section 3 - Hazards Identification EMERGENCY OVERVIEW Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Skin: Causes eye irritation. Causes skin irritation. May be harmful if absorbed through the skin.

Ingestion: Inhalation: Chronic: Eyes: Skin: Ingestion: Inhalation: Notes to Physician: General Information: Extinguishing Media: General Information: Spills/Leaks: May cause irritation of the digestive tract. Causes respiratory tract irritation. May be harmful if inhaled. Section 4 - First Aid Measures Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Get medical aid. Flush skin with plenty of soap and water. Get medical aid. Wash mouth out with water. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Treat symptomatically and supportively. Section 5 - Fire Fighting Measures As in any fire, wear a self-contained breathing apparatus in pressuredemand, MSHA/NIOSH (approved or equivalent), and full protective gear. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - Accidental Release Measures Use proper personal protective equipment as indicated in Section 8. Vacuum or sweep up material and place into a suitable disposal container. Section 7 - Handling and Storage Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 118-91-2:

Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 Respirators: approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - Physical and Chemical Properties Physical State: Powder Color: white to off-white Odor: Not available ph: 3.4(0.2g/l aq.sol.) Vapor Pressure: Not available Viscosity: Not available Boiling Point: 285 deg C @ 760 mmhg ( 545.00 F) Freezing/Melting Point: 139-143 deg C Autoignition Temperature: 530 deg C ( 986.00 deg F) Flash Point: 173 deg C ( 343.40 deg F) Explosion Limits: Lower: Not available Explosion Limits: Upper: Not available Decomposition Temperature: Not available Solubility in water: Soluble in hot water Specific Gravity/Density: Molecular Formula: C7H5ClO2 Molecular Weight: 156.57 Section 10 - Stability and Reactivity Chemical Stability: Not available Conditions to Avoid: Incompatible materials, dust generation, moisture. Incompatibilities with Other Materials Strong oxidizing agents, strong bases.

Hazardous Decomposition Products Hazardous Polymerization RTECS#: Hydrogen chloride, carbon monoxide, carbon dioxide. Has not been reported. Section 11 - Toxicological Information CAS# 118-91-2: DG4976000 RTECS: CAS# 118-91-2: Draize test, rabbit, eye: 20 mg/24h Moderate; LD50/LC50: Draize test, rabbit, skin: 500 mg/24h Mild;. Other: Oral, rat : LD50 = 2465 mg/kg 2-Chlorobenzoic acid - Not listed as a carcinogen by ACGIH, IARC, NTP, Carcinogenicity: or CA Prop 65. Other: Ecotoxicity: Other: The toxicological properties have not been fully investigated. See actual entry in RTECS for complete information. Section 12 - Ecological Information Not available Avoid entering into waters or underground water. Do not empty into drains. log POW = 1.98 Section 13 - Disposal Considerations Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - Transport Information IATA IMO RID/ADR Shipping Name: Not available Not available Not available Hazard Class: UN Number: Packing Group: European/International Regulations Section 15 - Regulatory Information European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. WGK (Water Danger/Protection) CAS# 118-91-2: 2

Canada CAS# 118-91-2 is listed on Canada's DSL List </ TD> US Federal TSCA CAS# 118-91-2 is listed on the TSCA Inventory. Section 16 - Other Information MSDS Creation Date: 7/16/1996 Revision #1 Date 6/26/2000 Revisions were made in Sections: General revision. The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantibility or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential, or exemplary damages howsoever arising, even if the company has been advised of the possibility of such damages. --------------------------------------------------------------------------------