OCCUPATIONAL SAFETY AND ENVIRONMENTAL HEALTH GUIDELINE

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OCCUPATIONAL SAFETY AND ENVIRONMENTAL HEALTH GUIDELINE Date: 04-22-2009 Revision: 02 Page: 1 of 6 SUMMARY: SCOPE: REFERENCE REGULATIONS: Employees using laboratory fume hoods shall observe all applicable standards and guidelines to minimize exposure to hazardous materials in the lab. This Guideline applies to all personnel using laboratory fume hoods. OSHA 29 CFR 1910.1450 Occupational exposure to hazardous chemicals in laboratories MIOSHA PART 431 Hazardous Work in Laboratories RESPONSIBILITY: OSEH Review and revise the Laboratory Fume Hoods Guideline. Provide technical assistance. Conduct annual certification of all laboratory fume hoods. Employees Comply with this Guideline and any further safety recommendations initialized by the principal investigator/supervisor. Conduct assigned tasks in a safe manner, wear appropriate personal protective equipment, and only use equipment for which they have been formally trained. Inform supervisor of faulty equipment, alarms, or other problems noted with fume hoods in the lab. Consult with your supervisor when there are questions regarding health and safety. Report any job related injuries or illnesses, questions on health and safety, or any unsafe or unhealthy working conditions to your supervisor. Contact OSEH to evaluate potentially unsafe conditions.

Date: 04-22-2009 Revision: 02 Page: 2 of 6 Principle Investigators/Supervisors Implement procedures in accordance with this Guideline and contact OSEH to request technical assistance. Assure that staff is aware of this Guideline, instructed on the details of implementation, and provided with equipment and controls. Maintain documentation as required. Report all problems with fume hoods to the Plant Operations Call Center (POCC) at 647-2059. Do not allow employees to use fume hoods that are posted out of service, broken or in alarm. Report all workplace accidents or injuries and complete Illness or Injury Report Form. PROCEDURES: Training All personnel using laboratory fume hoods should be fully trained in their proper operation. This includes knowledge of the controller operation, monitoring devices, and designed sash height to contain chemicals and protect users. Base line training is achieved by attending the OSEH laboratory safety class. More detailed training should be obtained from the lab supervisor on the operation of specific hoods in the lab. Proper Use of Fume Hood Sash Certification labels and arrows are placed on the face of the fume hood by OSEH. These indicate a specific sash height that the hood should be operated at to provide containment of chemicals and protection of employees. Work in the fume hood should not be conducted with the sash height any higher than that marked by the sticker and arrow. Whenever possible, lower the sash to the lowest position when working in the hood to provide a safety shield for the face and upper body. Avoid placing one s head in the hood. Fully close the sash when the hood is not in use. This will improve safety and may reduce energy consumption.

Date: 04-22-2009 Revision: 02 Page: 3 of 6 Proper Use of Fume Hood Always confirm the hood is operating by checking alarms and monitors and observing noise and air movement that would indicate proper operation. All experimental materials and equipment should be placed at least 6 inches back from the face. For proper air circulation, keep rear baffle openings clear. Large objects should be placed 2 to 3 inches above the work surface to insure proper air flow. Keep nearby windows and doors shut and pedestrian traffic to a minimum, when working in the hood. Monitor as appropriate while performing any ongoing procedures or reactive experiments. Laboratory fume hoods are not to be used as permanent storage for chemicals or equipment. Chemical containers should be capped or covered when not in use and should be properly labeled as to the contents. No other types of exhaust can be connected to the hood exhaust system without proper engineering consultation from Utilities and Plant Engineering (UPE) or Architecture, Engineering & Construction (AEC). Periodically and after spills clean the interior and exterior surfaces and the sash with deionized water and then a soap solution. Wear appropriate protective equipment to protect from chemicals used in the hood. Keep papers, paper towels, work surface diapers, vials, or any other small objects from being drawn into the hoods ventilation system. Alarms or Monitors Laboratory fume hood alarms or monitors should never be turned off. If the alarm sounds or the monitor lights indicate low flow, work should be stopped, equipment turned off, and the sash lowered. Lab personnel should leave the area if highly toxic or volatile chemicals are being used. Report all problems to the Plant Operations Call Center (POCC) at 647-2059. Manual Controllers Laboratory fume hoods with manual controllers should be set to proper operating position before beginning work. Contact OSEH at 3-6973 for assistance. Perchloric Acid Use of perchloric acid requires a special hood approved for use by OSEH. Contact OSEH for more information on special handling.

Date: 04-22-2009 Revision: 02 Page: 4 of 6 Radioactive Materials Use of radioactive materials must be authorized by OSEH. Certification OSEH conducts an annual certification of face velocity and monitor operation. If an inspection is needed, notify OSEH at 763-6973. Face velocity certification criteria is between 80 and 120 linear feet per minute (LFM). The certification criteria for high performance fume hoods, which are designed to contain at lower face velocities, is 70 to 120 LFM. This certification is documented on a sticker placed on the front of the hood. Hoods failing the certification will be posted out of service. Any chemical fume hood tagged out of service should not be used. Detailed information on this program can be found in the OSEH Engineering Control Standard of Care documents # 1 and 2. http://www.oseh.umich.edu/pdf/soc/soc1.pdf http://www.oseh.umich.edu/pdf/soc/soc2.pdf Maintenance Maintenance of fume hoods is conducted by the Plant department. Hoods posted out of service by OSEH are immediately report to Plant Operations. Questions on maintenance of hoods can be referred to the Plant Operations Call Center (POCC) at 647-2059. Ductless Fume Hoods Ductless fume hoods are not acceptable in place of a traditional ventilated hood. NFPA 45 states "Ductless chemical fume hoods that pass air from the hood interior through an absorption filter and then discharge the air into the laboratory are only applicable for use with nuisance vapors and dusts that do not present a fire or toxicity hazard." Purchases of these types of hoods are subject to a health and safety review by OSEH before purchase approval is granted. OSEH does not recommend the use of ductless hoods for the following reasons: 1. The filtered air is returned to the lab space and there are no guarantees that the filtration system will adequately remove the chemical contaminants. 2. Ductless, filtration fume hoods often do not meet face velocity or ASHRAE test criteria requirements for containment of chemicals. 3. The determination of the type of filter used in each hood is dependent upon the type of chemicals used in the fume hood. In a University setting, this determination is often difficult, as researchers and projects change frequently.

Date: 04-22-2009 Revision: 02 Page: 5 of 6 4. Filter saturation is generally determined using only one chemical. In a university setting, fume hoods are frequently used for many chemicals and mixtures. Therefore, estimating a filter's saturation point and establishing a regular maintenance schedule is very difficult. 5. Filters saturated with flammable chemicals can be a fire hazard. Filters saturated with other chemicals may also be a potential source of chemical exposure. 6. OSEH Radiation Safety Service and Biological & Laboratory Safety must evaluate each laboratory's experimental procedures and radioisotope usage to determine if the ductless filtration fume hood would be adequate for their experiments. 7. The filters for ductless fume hoods must be disposed of as hazardous waste. The disposal of these filters is very expensive to the University and individual departments. OSEH recommends changing the filters on these units a minimum of every 6 months. (Replacement filters for most units cost approximately $600-$1200.) 8. Periodic exposure monitoring on people utilizing ductless fume hoods may be necessary to assess chemical exposure. The select few applications that OSEH would approve the use of these hoods involve specific types, limited numbers, and minimal volumes of chemicals. The following procedures should be followed when purchasing a ductless fume hood. 1. Contact OSEH to review information about the intended use. 2. Write Standard Operating Procedures (SOP) for proper use, training, and maintenance. 3. Use only chemicals listed by the manufacturer as acceptable for that particular filter. 4. Use only small quantities of chemicals in the hood. 5. Do not conduct reactions involving pressure and heat in the hood. 6. Do not store chemicals in hood. 7. Keep all chemical containers capped while in the hood. 8. Evaluate filter saturation and maintain a replacement schedule. Document all filter changes and keep a log of use.

Date: 04-22-2009 Revision: 02 Page: 6 of 6 RELATED DOCUMENTS: TECHNICAL SUPPORT: ANSI/AIHA Z9.5-2003 ANSI/ASHRAE 110-1995 NFPA 45 Standard on Fire Protection for Laboratories UM Fume Hood and Laboratory Ventilation Standards UM Biological Safety Cabinet/Fume Hood Helpful Hints pamphlet UM Engineering Control Standard of Care #1http://www.oseh.umich.edu/pdf/soc/SOC1.pdf UM Engineering Control Standard of Care #2 http://www.oseh.umich.edu/pdf/soc/soc2.pdf OSEH provides technical support in choosing proper engineering controls for working with hazardous chemicals in laboratories. Contact OSEH if there are any questions regarding laboratory fume hoods.