Material Safety Data Sheet KEYSTONE PINK POT & PAN DETERGENT 1. Product and company identification Trade name of product Product use KEYSTONE PINK POT & PAN DETERGENT Manual Warewashing Detergent Product dilution information Up to 1 oz/gallon or 7.8 ml/l in water Supplier's information Code Date of issue 2. Physical state Emergency overview Ecolab Co. 515 Tomken Road Mississauga ON L4W 2X5 1-8-352-5326 91487-1 6-February-213 EMERGENCY HEALTH INFORMATION 1-8-328-26 Outside United States and Canada CALL 1-651-222-5352 (in USA) Hazards identification Routes of entry Skin contact, Eye contact, Inhalation, Ingestion Potential acute health effects Eyes Moderately irritating to eyes. Skin Inhalation Ingestion Liquid. WARNING! MAY CAUSE EYE IRRITATION. Avoid contact with eyes. Wash thoroughly after handling. See toxicological information (Section 11) 3. Composition/information on ingredients Liquid. CAUTION! No specific hazard. No specific hazard. Name CAS number % by weight SODIUM C14-16 OLEFIN SULFONATE 68439-57-6 3-7 poly(oxy-1,2-ethanediyl),.alpha.-sulfo-.omega.-hydroxy-, c1-16-alkyl ethers, sodium 68585-34-2 1-5 salts COCAMINE OXIDE 61788-9-7 1-5 ALCOHOL 64-17-5.1-1 Within the present knowledge of the supplier, this product does not contain any hazardous ingredients in quantities requiring reporting, in accordance with local regulations. 1/6
4. Eye contact Skin contact Inhalation Ingestion 5. First-aid measures In case of contact, immediately flush eyes with plenty of water. Remove contact lenses and flush again. Get medical attention if irritation persists. No known effect after skin contact. Rinse with water for a few minutes. No special measures required. Treat symptomatically. Get medical attention if symptoms occur. Fire-fighting measures Auto-ignition temperature Flammable limits Hazardous thermal decomposition products Special remarks on fire hazards Special remarks on explosion hazards Fire-fighting media and instructions Special protective equipment for fire-fighters 6. Personal precautions Environmental precautions Methods for cleaning up No known effect after eye contact. Rinse with water for a few minutes. No known effect after skin contact. Rinse with water for a few minutes. No special measures required. Treat symptomatically. Get medical attention if symptoms occur. Decomposition products may include the following materials halogenated compounds metal oxide/oxides Accidental release measures Use an extinguishing agent suitable for the surrounding fire. Dyke area of fire to prevent runoff. In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Use personal protective equipment as required. Avoid contact of large amounts of spilt material and runoff with soil and surface waterways. Use a water rinse for final clean-up. Use personal protective equipment as required. Avoid contact of large amounts of spilt material and runoff with soil and surface waterways. Use a water rinse for final clean-up. 7. Handling Storage Handling and storage Avoid contact with eyes. Wash thoroughly after handling. Keep out of reach of children. Store in a closed container. Store between the following temperatures and 4 C Wash thoroughly after handling. Keep out of reach of children. 2/6
8. Engineering measures Exposure controls/personal protection Personal protection Eyes No protective equipment is needed under normal use conditions. Hands No protective equipment is needed under normal use conditions. Skin Respiratory Good general ventilation should be sufficient to control worker exposure to airborne contaminants. No protective equipment is needed under normal use conditions. No special protection is required. Good general ventilation should be sufficient to control worker exposure to airborne contaminants. No protective equipment is needed under normal use conditions. No protective equipment is needed under normal use conditions. No protective equipment is needed under normal use conditions. No special protection is required. Occupational exposure limits TWA (8 hours) STEL (15 mins) Ceiling Ingredient List name ppm mg/m³ Other ppm mg/m³ Other ppm mg/m³ Other Notations ethanol US ACGIH 3/212 - - - 1 - - - - - AB 4/29 1 188 - - - - - - - BC 4/212 - - - 1 - - - - - ON 7/21 - - - 1 - - - - - QC 9/211 1 188 - - - - - - - 9. Physical and chemical properties Physical state Liquid. Flash point > 1 C Product does not support combustion. Colour pink [Light] Odour Fragrance-like ph 7 to 1 [Conc. (% w/w) 1%] Boiling/ >1 C (>212 F) condensation point Melting/freezing point Relative density Vapour pressure Vapour density Odour threshold Evaporation rate Viscosity Dispersibility properties Solubility LogKow 1.16 to 1.36 Easily soluble in the following materials cold water and hot water. Liquid. > 1 C pink [Light] Fragrance-like 7.7 to 8.2 3/6
1. Stability and reactivity Stability Conditions of instability Reactivity Hazardous decomposition products Hazardous polymerisation 11. Toxicity data The product is stable. Under normal conditions of storage and use, hazardous polymerisation will not occur. Toxicological information Potential acute health effects Eyes Skin Inhalation Ingestion Reproductive effects Sensitization to Product Synergistic products (toxicologically) Under normal conditions of storage and use, hazardous decomposition products should not be produced. Under normal conditions of storage and use, hazardous polymerisation will not occur. Product/ingredient name Test Route Result Species sulfonic acids, c14-16-alkane hydroxy and LD5 Dermal 63 mg/kg Rabbit c14-16-alkene, sodium salts LD5 Oral 3983 mg/kg Rat amines, coco alkyldimethyl, n-oxides LD5 Dermal >2174 mg/kg Rat LD5 Oral 846 mg/kg Rat ethanol LD5 Dermal 158 mg/kg Rabbit LD5 Oral 147 mg/kg Rat poly(oxy-1,2-ethanediyl),.alpha.-sulfo-. omega.-hydroxy-, c1-16-alkyl ethers, sodium salts Other adverse effects Target organs Moderately irritating to eyes. Potential chronic health effects Carcinogenic effects Mutagenic effects Teratogenic effects LC5 Inhalation 117 mg/l Rat LD5 Dermal >2 mg/kg Rat LD5 Oral >25 mg/kg Rat Contains material which may cause damage to the following organs eyes. 4/6
12. Ecological information Ecotoxicity Not reported 13. Disposal considerations Waste disposal Diluted product can be flushed to sanitary sewer. Discard empty container in trash. Diluted product can be flushed to sanitary sewer. Discard empty container in trash. 14. Transport information Certain shipping modes or package sizes may have exceptions from the transport regulations. The classification provided may not reflect those exceptions and may not apply to all shipping modes or package sizes. TDG TDG Classification Not regulated. IMO/IMDG IMO/IMDG Classification Not regulated. For transport in bulk, see shipping documents for specific transportation information. Not intended for transport. 15. Regulatory information WHMIS Class D-2B Material causing other toxic effects (Toxic). Not hazardous by WHMIS criteria. Canada inventory All components are listed or exempted. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. 16. Other information Hazardous Material Information System (U.S.A.) Health * 1 Health Physical hazards Physical hazards National Fire Protection Association (U.S.A.) Health 1 Instability/Reactivity Health Instability/Reactivity Special Special 5/6
16. Other information Date of issue Responsible name 6-February-213 Regulatory Affairs 1-8-352-5326 Indicates information that has changed from previously issued version. Notice to reader The above information is believed to be correct with respect to the formula used to manufacture the product in the country of origin. As data, standards, and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING ACCURACY OF THIS INFORMATION. 6/6