Oil Europe. H222: Extremely flammable aerosol. EUH066: Repeated exposure may cause skin dryness or cracking. Danger GHS02: Flame

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Transcription:

Sent to: Public Server Addition Page: 1 Compilation Date: 03/11/2014 Revision No: 1 Section 1: Identification of the substance/mixture and of the company/undertaking 1.1: Product identifier Product name: Product code: Q10 PF Aerosol 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of substance / mixture: Lubricant / Lubricating oil. Use as a functional fluid. 1.3. Details of the supplier of the safety data sheet Company name: Q Ltd, Unit 2, Crown Point Ind Est Sth, King Street, Denton, Manchester, M34 6PE United Kingdom Tel: +44 (0) 161 484 6505 Email: office@qoileurope.com 1.4. Emergency telephone number Emergency tel: +44 (0) 161 484 6505 (Office Hours Only) Section 2: Hazards identification 2.1. Classification of the substance or mixture Classification under CHIP: F+: R12 Classification under CLP: Flam. Aerosol 1: H222; -: EUH066 Most important adverse effects: Extremely flammable. 2.2. Label elements Hazard statements: Signal words: Hazard pictograms: H222: Extremely flammable aerosol. EUH066: Repeated exposure may cause skin dryness or cracking. Danger GHS02: Flame

Page: 2 2.2. Label elements cont d Precautionary statements: P202: Do not handle until all safety precautions have been read and understood. P281: Use personal protective equipment as required. P302+350: IF ON SKIN: Gently wash with plenty of soap and water. P211: Do not spray on an open flame or other ignition source. P251: Pressurized container: Do not pierce or burn, even after use. P410+412: Protect from sunlight. Do not expose to temperatures exceeding 50 ºC. Label elements under CHIP: Hazard symbols: Extremely flammable. Risk phrases: Safety phrases: Precautionary phrases: R12: Extremely flammable. S2: Keep out of the reach of children. S29: Do not empty into drains. S51: Use only in well-ventilated areas. Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep away from sources of ignition - No smoking. Keep out of the reach of children. 2.3. Other hazards Other hazards: PBT: In use, may form flammable / explosive vapour-air mixture. This substance is not identified as a PBT substance.

Page: 3 Section 3: Composition/information on ingredients 3.2. Mixtures Hazardous ingredients: EINECS CAS CHIP Classification CLP Classification Percent KEROSINE - UNSPECIFIED - DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 265-149-8 64742-47-8 Xn: R65; N: R51/53 Asp. Tox. 1: H304 70-90% PROPANE 200-827-9 74-98-6 F+: R12 Flam. Gas 1: H220; Press. Gas: H280 1-10% Substance with a Community workplace exposure limit. BUTANE 203-448-7 106-97-8 F+: R12 Flam. Gas 1: H220; Press. Gas: H280 1-10% Substance with a Community workplace exposure limit. 4-HYDROXY-4-METHYLPENTAN-2-ONE 204-626-7 123-42-2 Xi: R36 Eye Irrit. 2: H319 1-10% Section 4: First aid measures 4.1. Description of first aid measures Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench the affected skin with running water for 10 minutes or longer if substance is still on skin. Eye contact: Ingestion: Inhalation: Immediately flood the eye with plenty of water for at least 15 minutes,holding the eye open. Remove any contact lenses and open eyes wide apart. Get medical attention if any discomfort continues Do not induce vomiting. If conscious, give half a litre of water to drink immediately. Consult a doctor.. Remove from exposure, rest and keep warm. In severe cases, or if recovery is not rapid or complete, seek medical advice. 4.2. Most important symptoms and effects, both acute and delayed Skin contact: There may be mild irritation at the site of contact. Eye contact: There may be irritation and redness. Ingestion: There may be irritation of the throat. Inhalation: Drowsiness or mental confusion may occur. There may be loss of consciousness. Delayed / immediate effects: Immediate effects can be expected after short-term exposure. 4.3. Indication of any immediate medical attention and special treatment needed Immediate / special treatment: Not applicable.

Page: 4 Section 5: Fire-fighting measures 5.1. Extinguishing media Extinguishing media: Alcohol resistant foam. Water spray. Carbon dioxide. Dry chemical powder. 5.2. Special hazards arising from the substance or mixture Exposure hazards: Extremely flammable. In combustion emits toxic fumes. Forms explosive air-vapour mixture. Vapour may travel considerable distance to source of ignition and flash back. 5.3. Advice for fire-fighters Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes. Section 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions: Refer to section 8 of SDS for personal protection details. Turn leaking containers leakside up to prevent the escape of liquid. Mark out the contaminated area with signs and prevent access to unauthorised personnel. 6.2. Environmental precautions Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding. 6.3. Methods and material for containment and cleaning up Clean-up procedures: Do not use equipment in clean-up procedure which may produce sparks. Absorb into dry earth or sand. Clean-up should be dealt with only by qualified personnel familiar with the specific substance. 6.4. Reference to other sections Reference to other sections: Refer to section 8 of SDS. Section 7: Handling and storage 7.1. Precautions for safe handling Handling requirements: Smoking is forbidden. Use non-sparking tools. Ensure there is sufficient ventilation of the area. Do not handle in a confined space. Avoid the formation or spread of mists in the air. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions: Store in cool, well ventilated area. Keep container tightly closed. Keep away from sources of ignition. Prevent the build up of electrostatic charge in the immediate area. Ensure lighting and electrical equipment are not a source of ignition. Suitable packaging: Original container stored in a dry and cool place. 7.3. Specific end use(s) Specific end use(s): No data available.

Page: 5 Section 8: Exposure controls/personal protection 8.1. Control parameters Hazardous ingredients: Workplace exposure limits: Respirable dust State 8 hour TWA 15 min. STEL 8 hour TWA 15 min. STEL PROPANE UK 1800 mg/m3 7200 mg/m3 - - BUTANE UK 1450 mg/m3 1810 mg/m3 - - 4-HYDROXY-4-METHYLPENTAN-2-ONE UK 241 mg/m3 362 mg/m3 - - 8.2. Exposure controls Engineering measures: Respiratory protection: Hand protection: Eye protection: Skin protection: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical equipment are not a source of ignition. Respiratory protection not required. Impermeable gloves, change regularly to avoid permeation problems. Safety goggles. Ensure eye bath is to hand. Wear suitable protective clothing and gloves. Section 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties State: Aerosol Colour: Colourless Odour: Aromatic Evaporation rate: Fast Oxidising: Non-oxidising (by EC criteria) Solubility in water: Slightly soluble Boiling point/range C: <=35 Flash point C: <21 Relative density: 0.83 g/cm3 9.2. Other information Other information: Not applicable.

Page: 6 Section 10: Stability and reactivity 10.1. Reactivity Reactivity: Stable under recommended transport or storage conditions. 10.2. Chemical stability Chemical stability: Stable under normal conditions. 10.3. Possibility of hazardous reactions Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions Decomposition may occur on exposure to conditions or materials listed below. 10.4. Conditions to avoid Conditions to avoid: 10.5. Incompatible materials Materials to avoid: Heat. Hot surfaces. Sources of ignition. Flames. Strong oxidising agents. Strong acids. 10.6. Hazardous decomposition products Haz. decomp. products: In combustion emits toxic fumes. Section 11: Toxicological information 11.1. Information on toxicological effects Toxicity values: Not applicable. Symptoms / routes of exposure Skin contact: There may be mild irritation at the site of contact. Eye contact: There may be irritation and redness. Ingestion: There may be irritation of the throat. Inhalation: There may be a feeling of tightness in the chest with shortness of breath. Delayed / immediate effects: Immediate effects can be expected after short-term exposure. Section 12: Ecological information 12.1. Toxicity Ecotoxicity values: Not applicable. 12.2. Persistence and degradability Persistence and degradability: Biodegradable. 12.3. Bioaccumulative potential Bioaccumulative potential: No bioaccumulation potential.

Page: 7 Section 12: Ecological information 12.4. Mobility in soil Mobility: Readily absorbed into soil. 12.5. Results of PBT and vpvb assessment PBT identification: This substance is not identified as a PBT substance. 12.6. Other adverse effects Other adverse effects: Negligible ecotoxicity. Section 13: Disposal considerations 13.1. Waste treatment methods Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal company. NB: The user s attention is drawn to the possible existence of regional or national regulations regarding disposal. Section 14: Transport information 14.1. UN number UN number: UN1950 14.2. UN proper shipping name Shipping name: AEROSOLS 14.3. Transport hazard class(es) Transport class: 2 14.4. Packing group 14.5. Environmental hazards Environmentally hazardous: Yes Marine pollutant: No 14.6. Special precautions for user Special precautions: No special precautions. Tunnel code: D Transport category: 2 Section 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2. Chemical Safety Assessment Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture by the supplier.

Page: 8 Section 16: Other information Other information Other information: Phrases used in s.2 and 3: Legal disclaimer: This safety data sheet is prepared in accordance with Commission Regulation (EU) No 453/2010. * indicates text in the SDS which has changed since the last revision. EUH066: Repeated exposure may cause skin dryness or cracking. H220: Extremely flammable gas. H222: Extremely flammable aerosol. H304: May be fatal if swallowed and enters airways. H319: Causes serious eye irritation. R12: Extremely flammable. R36: Irritating to eyes. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65: Harmful: may cause lung damage if swallowed. The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for anydamage resulting from handling or from contact with the above product. Final Page