Page: 1 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Product Name Company Name Address Emergency Tel. Telephone/Fax Number Recommended Use Other Names Other APOXIE SCULPT - ALL COLOURS PART A Barnes Products Pty Ltd (ABN 004 011 46) 6 Homedale Road Bankstown NSW 2200 (02) 9793 7 Tel: (02) 9793 7 Fax: (02) 9793 7091 Modelling compounds Name 2. HAZARDS IDENTIFICATION Hazard Classification Risk Phrase(s) Safety Phrase(s) Product Code AVES APOXIE SCULPT - PART A provided has been prepared in good faith and believed to be correct. Barnes Products Pty Limited make no warranty either express or implied as to completeness, accuracy there, misuse or misinterpretation this information. HAZARDOUS SUBSTANCE. DANGEROUS GOODS. Hazard classification according to the criteria NOHSC. Dangerous goods classification according to the Australia Dangerous Goods Code. R36/38 Irritating to eyes and skin. R43 May cause sensitization by skin contact. R1/3 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S24/2 Avoid contact with skin and eyes. S26 In case contact with eyes, rinse immediately with plenty water and seek medical advice. S29 Do not empty into drains. S36/37 Wear suitable protective clothing and gloves. S4 In case accident or if you feel unwell seek medical advice immediately 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients 4. FIRST AID MEASURES Inhalation Ingestion Skin Eye First Aid Facilities Advice to Doctor Name CAS Proportion Kaolin Talc Propane, 2,2-bis[p- (2,3-epoxypropoxy)phen yl Colourants 1332-8-7 0-100 % 14807-96-6 0-100 % 208-99-8 0-100 % 0-30 % If inhaled, remove affected person from contaminated area. Keep at rest until recovered. If symptoms persist seek medical attention. Do not induce vomiting. Wash out mouth thoroughly with water. If symptoms develop seek medical attention. Remove contaminated clothing. Wash affected area thoroughly with soap and water Wash contaminated clothing before re-use or discard. Seek medical attention. If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing until advised to stop by the Poisons Centre or a doctor, or for at least 1 minutes. Seek immediate medical attention. Eye wash fountain, safety shower and normal washroom facilities. Treat symptomatically. Print Date: 7/06/2012
Page: 2 Other. FIRE FIGHTING MEASURES Suitable Extinguishing Media Hazards from Combustion Products Specific Hazards Hazchem Code Precautions in connection with Fire Unsuitable Extinguishing Media For advice in an emergency, contact a Poisons Centre (Phone Australia 13 1126; New Zealand 0800 POISON / 0800 764 766) or a doctor at once. Use carbon dioxide, dry chemical, foam, water fog or water mist. Under fire conditions this product may emit toxic and/or irritating fumes and gases including carbon monoxide, carbon dioxide and oxides nitrogen. Combustible material. This product will readily burn under fire conditions. 2Z Fire fighters should wear Self-Contained Breathing Apparatus (SCBA) operated in positive pressure mode and full protective clothing to prevent exposure to vapours or fumes. Water spray may be used to cool down heat-exposed containers. Fight fire from safe location. This product should be prevented from entering drains and watercourses. Do not use water jet. 6. ACCIDENTAL RELEASE MEASURES Emergency Procedures 7. HANDLING AND STORAGE Precautions for Safe Handling Conditions for Safe Storage Storage Temperatures Wear appropriate personal protective equipment and clothing to prevent exposure. Extinguish or remove all sources ignition and stop leak if safe to do so. Increase ventilation. Evacuate all unprotected personnel. If possible contain the spill. Place inert absorbent, non-combustible material onto spillage. Use clean non-sparking tools to collect the material and place into suitable labelled containers for subsequent recycling or disposal. Dispose waste according to the applicable local and national regulations. If contamination sewers or waterways occurs inform the local water and waste management authorities in accordance with local regulations. Use only in a well ventilated area. Keep containers sealed when not in use. Prevent the build up mists or vapours in the work atmosphere. Avoid inhalation vapours and mists, and skin or eye contact. Do not use near ignition sources. Do not pressurise, cut, heat or weld containers as they may contain hazardous residues. Maintain high standards personal hygiene i.e. Washing hands prior to eating, drinking, smoking or using toilet facilities. Store in a cool, dry, well-ventilated area away from sources ignition, oxidising agents, strong acids, foodstuffs, and clothing. Keep containers closed when not in use and securely sealed and protected against physical damage. Inspect regularly for deficiencies such as damage or leaks. Have appropriate fire extinguishers available in and near the storage area. Take precautions against static electricity discharges. Use proper grounding procedures. For information on the design the storeroom, reference should be made to Australian Standard AS1940 - The storage and handling flammable and combustible liquids. Reference should also be made to all applicable local and national regulations. Store below 49 C 8. EXPOSURE CONTROLS/PERSONAL PROTECTION National Exposure Standards No exposure value assigned for this specific material by the Safe Work, Australia. However, the available exposure limits for ingredients are listed below: Safe Work, Australia Exposure Standards: Substance TWA STEL NOTICES ppm mg/m³ ppm mg/m³ Talc - 2. - - - (containing no asbestos fibres) TWA (Time Weighted Average): The average airborne concentration a Print Date: 7/06/2012
Page: 3 Biological Limit Values Engineering Controls Respiratory Protection Eye Protection Hand Protection Footwear Body Protection particular substance when calculated over a normal eight-hour working day, for a five-day week. STEL (Short Term Exposure Limit): The average airborne concentration over a 1 minute period which should not be exceeded at any time during a normal eight-hour workday. No biological limit available Provide sufficient ventilation to keep airborne levels as low as possible. Where vapours or mists are generated, particularly in enclosed areas, and natural ventilation is inadequate, a local exhaust ventilation system is required. If engineering controls are not effective in controlling airborne exposure then an approved respirator with a replaceable mist filter should be used. Reference should be made to Australian/New Zealand Standards AS/NZS 171, Selection, Use and Maintenance Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices, in order to make any necessary changes for individual circumstances. Safety glasses with side shields or chemical goggles should be worn. Final choice appropriate eye/face protection will vary according to individual circumstances. Eye protection devices should conform with Australian/New Zealand Standard AS/NZS 1337 - Eye Protectors for Industrial Applications. Wear gloves impervious material e.g. rubber. Final choice appropriate gloves will vary according to individual circumstances i.e. methods handling or according to risk assessments undertaken. Reference should be made to AS/NZS 2161.1: Occupational protective gloves - Selection, use and maintenance. Wear safety footwear. Final choice will vary according to individual circumstances. Reference should be made to AS/NZS 2210.1: 2010 Safety, protective and occupational footwear-guide to selection, care and use. Suitable protective workwear, e.g. cotton overalls buttoned at neck and wrist is recommended. Chemical resistant apron is recommended where large quantities are handled. Industrial clothing should conform to the specifications detailed in AS/NZS 2919: Industrial clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Odour Melting Point Boiling Point Solubility in Water Specific Gravity ph Value Vapour Pressure Vapour Density (Air=1) Flash Point Flammability Auto-Ignition Temperature Flammable Limits - Lower Flammable Limits - Upper Putty like material, semi st. Putty odour Does not melt. Slightly soluble 2.2 8.0 (% weight basis suspension) >93 C (ASTM D93) Combustible material 10. STABILITY AND REACTIVITY Chemical Stability Conditions to Avoid Stable under normal conditions storage and handling. Heat, flames and other sources ignition. Temperatures above 200 C Print Date: 7/06/2012
Page: 4 Incompatible Materials Hazardous Decomposition Products Hazardous Polymerization Strong acids or bases. 11. TOXICOLOGICAL INFORMATION Toxicology Inhalation Ingestion Skin Eye Chronic Effects Skin Sensitisation 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence / Degradability Mobility Environ. Protection Thermal decomposition may result in the release toxic and/or irritating fumes and gases including carbon monoxide, carbon dioxide and oxides nitrogen. Will not occur by itself, but if a large amount is mixed with an aliphatic amine, it will cause an uncontrolled polymerisation leading to a significant heat build up. No toxicity data available for this product. Inhalation product vapours may cause irritation the nose, throat and respiratory system. Ingestion this product may irritate the gastric tract causing nausea and vomiting. Irritating to skin. Skin contact will cause redness, itching and swelling. Repeated exposure may cause skin dryness and cracking and may lead to dermatitis. Irritating to eyes. On eye contact this product will cause tearing, stinging, blurred vision, and redness No exposure to dust is anticipated during normal use this product due to the form the product. Grinding or machining coated materials however may release dust. Use approved dust respirator when grinding, sanding or machining the dried items. Chronic exposure to dust may aggravate existing respiratory disorders. Onset and progression are related to dust concentrations and duration exposure. Prolonged or repeated skin contact may lead to allergic contact dermatitis and sensitisation in some individuals. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 13. DISPOSAL CONSIDERATIONS Disposal Considerations 14. TRANSPORT INFORMATION Transport U.N. Number Do not discharge this material into waterways, drains and sewers. Do not allow into drains or watercourses or dispose where ground or surface waters may be affected. Wastes including emptied containers are controlled wastes and should be disposed in accordance with all applicable local and national regulations. This material is classified as a Class 9 (Miscellaneous Dangerous Goods) dangerous Goods according to The Australian Code for the Transport Dangerous Goods by Road and Rail (7th edition). Class 9 Dangerous Goods are incompatible in a placard load with any the following: - Class 1, Explosives (when the class 9 substance is a fire risk substance), - Division.1, Oxidizing agents (when the class 9 substance is a fire risk substance), and - Division.2, Organic peroxides (when the class 9 substance is a fire risk substance). Note: Special Provision AU01 Environmentally Hazardous Substances meeting the descriptions UN 3077 or UN 3082 are not subject to this Code when transported by road or rail in: a) packagings; b) IBCs; or c) any other receptacle not exceeding 00 Kg(L). 3077 Print Date: 7/06/2012
Page: Proper Shipping Name DG Class Hazchem Code Packing Group EPG Number IERG Number IMDG Marine Pollutant (MP) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. - (CONTAINS: EPOXY RESIN) 9 2Z III 9C1 47 Yes 1. REGULATORY INFORMATION Regulatory Poisons Schedule Hazard Category 16. OTHER INFORMATION Date preparation or last revision MSDS Contact Person/Point Classified as Hazardous according to criteria National Occupational Health & Safety Commission (NOHSC), Australia. Not classified as a Scheduled Poison according to the Standard for the Uniform Scheduling Medicines and Poisons (SUSMP). Not Scheduled Irritant,Dangerous for the environment MSDS Created: June 2012 Managing Director (02) 9838 0222 After hours (02) 9487 7231...End Of MSDS... Copyright ACOHS Pty Ltd Copyright in the source code the HTML, PDF, XML, XFO and any other electronic files rendered by an Infosafe system for Infosafe MSDS displayed is the intellectual property Acohs Pty Ltd. Copyright in the layout, presentation and appearance each Infosafe MSDS displayed is the intellectual property Acohs Pty Ltd. The compilation MSDS's displayed is the intellectual property Acohs Pty Ltd. Copying any MSDS displayed is permitted for personal use only and otherwise is not permitted. In particular the MSDS's displayed cannot be copied for the purpose sale or licence or for inclusion as part a collection MSDS without the express written consent Acohs Pty Ltd. Print Date: 7/06/2012