MATERIAL SAFETY DATA SHEET AGRIANCE P.O. Box 8213, In case of emergency, Call Netanya, 42293, Israel. 972-9-865-6454 1. PRODUCT IDENTIFICATION Product Name : BUPRIFAL Active Ingredient (%) : Bupirimate 25% Chemical Name : 5-butyl-2-(ethylamino)-6-methyl-4-pyrimidinyl dimethylsulfamate Chemical formula C 13 H 24 N 4 O 3 S Chemical Class Fungicide Structure: 2. COMPOSITION / INFORMATION ON INGREDIENTS Components Percentage CAS No. Symbols R Phrases Bupirimate 25% 41483-43-6 Xi N R43, R51/53 n-butanol 30% 71-36-3 Xn R10, R22, R37/38, R41, R67 Other ingredients 45% 3. HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW This product is considered to be hazardous and contains hazardous components. 3.2 POTENTIAL HEALTH EFFECTS Adverse Human Health Irritating to skin. Effects Harmful : may cause lung damage if swallowed. Primary route of exposure Environmental Hazard: 3.3 Most Important adverse physicochemical effects: 4. FIRST AID MEASURES Vapours inhalation. Skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Flammable. 4.1 General Advice: Human health hazards : Environmental hazard : 4.2 FIRST AID: Ingestion : Flammable.Irritating to skin Harmful : may cause lung damage if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. DO NOT INDUCE VOMITING. Rinse mouth with water. PRODUCT NAME : BUPRIFAL Page 1 of 5
Seek medical advice (show the label where possible). Eye Contract : Rinse immediately with plenty of water. Seek medical attention immediately. Skin Contact : Remove affected clothing and rinse all exposed skin area with water. Washclothing before re-using. Seek medical attention if irritation develops. Inhalation : Remove victim to fresh air. Keep the affected person warm. Obtain medical attention. 4.3 Note to physician: Treat symptomatically. Give supportive therapy. Administer activated charcoal. 5. FIRE FIGHTING MEASURES 5.1 Suitable Extinguishing Media : 5.2 Special exposure hazards 5.3 Protection agsainst fire: 5.4 Special Procedures Small fire: dry chemical, carbon dioxide Large fire: water spray, Alcohol foam. May form flammable vapour-air mixture. When heated to decomposition, emits dangerous fumes., carbon dioxide, carbon monoxide, sulfur oxides, nitrogen oxides Use water spray or fog for cooling exposed containers. Wear suitable protective clothing Wear self-contained breathing apparatus, rubber boots and thick rubber gloves Exercise caution when fighting any chemical fire. 6. ACCIDENTAL RELEASE MEASURES 6.1 Personal Precautions: 6.2 Environmental Precautions: 6.3 Methods for Cleaning Up: Wear recommended personal protective equipment. See Heading 8. Prevent entry to sewers and public waters. Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. Clean up any spills as soon as possible, using an absorbent material to collect it. Use suitable disposal containers. 7. HANDLING AND STORAGE 7.1 HANDLING: Avoid contact with skin and eyes. Do not breath gas, fumes, vapour or spray. When using, do not eat, drink or smoke. 7.2 STORAGE: Store in tightly closed, properly ventilated containers away from heat, sparks, open flame. Keep away from sources of ignition Keep in original containers. Keep away from food, drink and animal feeding stuffs. Protect from freezing 7.3 Stable under recommended storage conditions. PRODUCT NAME : BUPRIFAL Page 2 of 5
8. EXPOSURE CONTROL/PERSONAL PROTECTION 8.1 Industrial Hygiene Facilities storing or utilizing this material should be equipped with an eyewashfacility and safety shower. TLV (USA) No data available. ( Solvesso 150 ) OEL=50 ppm ( Solvesso 150 ) TLV-STEL [ppm] TLV-STEL [mg/m3] : 8 Hour TWA [mg/m3] 50 (15 min, n-butanol ) 154 ( n-butanol ) 10 ( Bupirimate ) 8.2. Personal Protective Equipment (PPE) Respiratory protection During handling wear suitable respiratory equipment Skin and body Wear suitable protective clothing and chemical resistant boots protection Hand protection: Wear suitable gloves resistant to chemical penetration. Eye protection Chemical goggles or safety glasses Protective measures Good ventilation of the workplace required. Wash thoroughly after handling. Wash clothing before re-using 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 General Information Physical State: Liquid Appearance : Amber/Orange Odor Aromatic Solubility in water: ph 7.22 Flash Point ( C) 40 (closed cup) Density [kg/m 3] 920 Boiling point ( C) 128 Explosion limits Not explosive 10. STABILITY AND REACTIVITY 10.1 Stability: Stable under recommended storage and handling conditions. 10.2 Hazardous Properties: 10.3 Conditions to avoid: 10.4 Hazardous decomposition products : May form flammable vapour-air mixture. Heat, Open fire When heated to decomposition, emits dangerous fumes., carbon dioxide, carbon monoxide, nitrogen oxides, sulfur oxides PRODUCT NAME : BUPRIFAL Page 3 of 5
11. TOXICOLOGICAL INFORMATION 11.1 Acute Toxicity: Acute Oral: LD50 ( rat ) : > 4000 mg/kg AcuteSkin: LD50 ( rat ) : > 3000 mg/kg Acute Inhalation LC50 ( rat ) : > 5.3 mg/l/4h Dermal Irritation: (rabbit) Irritating to skin Eye Irritation : (rabbit) No eye irritation Sensitization: This material was found to be non-sensitising in guinea pigs.. 11.2 Carcinogenicity No carcinogenic effects 11.3 Mutagenicity Non- mutagenic 11.4 Teratogenicity: Not teratogenic 12. ECOLOGICAL INFORMATION 12.1 Ecotoxicity Effects: Fish: Algae: Daphnia magna Birds Bees: LC50 (96h) = 6.2 mg/l Oncorhynchus mykiss EbC50 (72h)= 4.9 mg/l ErC50 (72h)= 7.5 mg/l EC50 (48h) = 11.9 mg/l LD50 > 5000 (Bupirimate technical) LD50 ( Oral ) : > 105.8 μg/ bee LD50 ( Contact ) : > 100 μg/ bee 13. DISPOSAL CONSIDERATION 13.1 Disposal: Dispose of this material and its container at hazardous or special waste collection point. Dispose in a safe manner in accordance with local/national regulations.do not contaminate ponds, waterways or ditches with chemical or used container. Do not re-use empty containers. 14. TRANSPORT INFORMATION 14.1. Hazard Label Proper shipping UN1993 FLAMMABLE LIQUID, N.O.S. (n-butanol), 3, III name: UN No. 1993 H.I. No.: 30 14.2 Land transport Tremcard nr. 30GF1-III ADR/RID Class : 3 Special provision : 640E Group : III PRODUCT NAME : BUPRIFAL Page 4 of 5
14.3 Sea transport Class 3 Packaging Group III EmS- Nr. F-E, S-E 14.4 IMDG- Marine Pollution: Yes 15. REGULATORY INFORMATION 15.1 Hazardous Components: 15.2 Symbols Methomyl T+: Very Toxic N: Dangerous for the environment 15.3 Risk Phrases: R 10 : Flammable. R 38 : Irritating to skin. R 51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 65 : Harmful: may cause lung damage if swallowed. 15.4 Safety phrases: S02 - Keep out of reach of children. S13 - Keep away from food, drink and animal feedingstuffs. S20/21 - When using, do not eat, drink or smoke. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. contamination. S61- Avoid release to the environment. Refer to special instructions/safety data sheets. SP62 If swallowed, do not induce vomiting: seek medical advice immediately andshow this container or label. 15.5 Special labelling of certain preparations: To avoid risks to man and the environment, comply with the instructions for use. 16. OTHER INFORMATION Disclaimer: The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall we be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if we have been advised of the possibility of such damages. PRODUCT NAME : BUPRIFAL Page 5 of 5