SAFETY DATA SHEET ECCO-MUL E 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY: PRODUCT NAME: APPLICATIONS: EMERGENCY TELEPHONES: ECCO-MUL E EMULSIFIER 44 (0)1224 720000 [24 hours] SUPPLIER: BAKER HUGHES INTEQ BAKER HUGHES BUILDING STONEYWOOD PARK NORTH DYCE, ABERDEEN. AB21 7EA TELEPHONE: 44 (0)1224-720000 2. COMPOSITION/INFORMATION ON INGREDIENTS: INGREDIENT NAME: MODIFIED AMINOAMIDE MINERAL OIL EINECS CAS No.: CONTENT SYMBOL RISK: 30-60 wt% Xi,N 36/38, 50/53 265-149-8 64742-47-8 30-60 wt% Xn 65, 66 The full text for all R-phrases are shown in section 16 3. HAZARDS IDENTIFICATION: Irritating to eyes and skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 4. FIRST AID MEASURES: INHALATION: INGESTION: SKIN: EYES: Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical attention. DO NOT INDUCE VOMITING! Promptly get affected personnel to drink large volumes of water to dilute the swallowed chemical. Get medical attention immediately! Wash the skin immediately with soap and water. Get medical attention if irritation persists after washing. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. 1 / 5
5. FIRE FIGHTING MEASURES: EXTINGUISHING MEDIA: Fire can be extinguished using: Powder, foam or CO2. Do NOT use Water Jets which may spread the fire. HAZARDOUS COMBUSTION PRODUCTS: Fire or high temperatures create: Oxides of: Nitrogen. PROTECTIVE MEASURES IN FIRE: Self contained breathing apparatus and suitable protective clothing must be worn in fire conditions. 6. ACCIDENTAL RELEASE MEASURES: PERSONAL PRECAUTION IN SPILL: Wear protective clothing and equipment. For further information on suitable protective clothing see Section 8 of the safety data sheet "Exposure Controls and Personal Protection". PRECAUTIONS TO PROTECT ENVIRONMENT: Prevent contamination of soil and water. Prevent from spreading or entering into drains, ditches or rivers by using sand, earth, or appropriate barriers. SPILL CLEANUP METHODS: Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. See Section 13, Disposal Considerations, for information regarding the disposal of contained spills. 7. HANDLING AND STORAGE: USAGE PRECAUTIONS: Avoid spilling, skin and eye contact. Avoid the generation and inhalation of mists, vapours or aerosols. Protective measures during handling are detailed in Section 8 of this Safety Data Sheet. STORAGE PRECAUTIONS: Keep in cool, dry, ventilated storage and closed containers. 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION: INGREDIENT NAME: MINERAL OIL CAS No.: STD: LT EXP. 8 HRS: ST EXP. 15 MIN: 64742-47-8 SUP 1000 mg/m3 No Std INGREDIENT COMMENTS: Exposure limit for oil refers to mist. PROTECTIVE EQUIPMENT: VENTILATION: RESPIRATORS: Provide adequate general and local exhaust ventilation to keep airborne levels below the designated exposure limits. If ventilation is insufficient, suitable respiratory protection must be provided. Wear chemical respirator with organic vapour cartridge. PROTECTIVE GLOVES: Use protective gloves made of: Nitrile. EYE PROTECTION: Wear splash-proof eye goggles to prevent any possibility of eye contact. 2 / 5
HYGIENIC WORK PRACTICES: Wash at the end of each work shift and before eating, smoking and using the toilet. 9. PHYSICAL AND CHEMICAL PROPERTIES: APPEARANCE: Liquid. COLOUR: Dark. Amber. ODOUR/TASTE: Characteristic. SOLUBILITY DESCRIPTION: Slightly soluble in water. BOILING POINT ( C, interval): >200 PRESSURE: 760mmHg MELT./FREEZ. POINT ( C, interval): 9 DENSITY/SPECIFIC GRAVITY (g/ml): 0.94 TEMPERATURE ( C): 25 VISCOSITY: 60 cst TEMPERATURE ( C): 20 FLASH POINT ( C): >65 METHOD: P/M Pensky-Martens. AUTO IGNITION TEMP. ( C): >200 FLAMMABILITY LIMIT - LOWER(%): N/A FLAMMABILITY LIMIT - UPPER(%): N/A PARTITION COEFF. (log Pow): >3 10. STABILITY AND REACTIVITY: STABILITY: Stable. CONDITIONS TO AVOID: Avoid contact with acids and oxidising substances. HAZARDOUS POLYMERIZATION: Will not polymerize. HAZARDOUS DECOMP. PRODUCTS: High temperatures generate: Oxides of: Nitrogen. 11. TOXICOLOGICAL INFORMATION: INHALATION: INGESTION: SKIN: EYES: Liquid inhaled in the form of fine droplet sprays or, mists or aerosols or aspirated during vomiting may cause chemical pneumonitis. May cause gastrointestinal irritation. Irritating to skin. Prolonged or repeated contact may cause dermatitis. Irritating to eyes. 12. ECOLOGICAL INFORMATION: ECOLOGICAL INFORMATION: 72hr EC50 (Skeletonema costatum): 1-10 mg/l 48hr LC50 (Acartia tonsa): 100-1000 mg/l 96hr LC50 (Scophthalamus maximus) >1800 mg/l 10 day LC50 (Corophium voluator): 100-1000 mg/l MOBILITY: This material is insoluble in water and will float on the surface of water. BIO ACCUMULATION: Expected to have the potential for bioaccumulation. DEGRADABILITY: 28 day biodegradation (OECD 306): 37-50% 3 / 5
13. DISPOSAL CONSIDERATIONS: DISPOSAL METHODS: Dispose of unused material as Special (Hazardous) Waste. The recommended form of disposal is incineration by an approved chemical disposal firm. Dispose of using licenced waste hauliers and disposal contractors. 14. TRANSPORT INFORMATION: LABEL FOR CONVEYANCE: ROAD TRANSPORT: UN No. ROAD: 3082 ADR CLASS: 9 HAZARD No. (ADR) 90 Environmentally hazardous substance; miscellaneous dangerous substances. ADR LABEL No.: 9 RAIL TRANSPORT: RID CLASS No.: 9 SEA TRANSPORT: UN No. SEA: 3082 IMDG CLASS: 9 AIR TRANSPORT: ICAO CLASS: 9 AIR PACK GR.: III 15. REGULATORY INFORMATION: LABEL FOR SUPPLY: RISK PHRASES: SAFETY PHRASES: UK REGULATORY REFERENCES: R-36/38 Irritating to eyes and skin. R-51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-24/25 Avoid contact with skin and eyes. S-26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S-60 This material and its container must be disposed of as hazardous waste. S-61 Avoid release to the environment. Refer to special instructions/ Safety Data Sheets. Prepared in accordance with the Chemicals (Hazard Information & Packaging for Supply) Regulations, 2002 (CHIP 3). EU DIRECTIVES: European Union (EINECS): Y. 4 / 5
16. OTHER INFORMATION: REVISION COMMENTS: Sections changed since last update: 14, ISSUED BY: Melanie Thatcher (Tel 44-(0)1224-408173) REV. No./REPL. SDS GENERATED: 8 August 2003 R-PHRASES (Full Text) R-36/38 Irritating to eyes and skin. R-50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R-66 Repeated exposure may cause skin dryness or cracking. R-65 Harmful: may cause lung damage if swallowed. DISCLAIMER: THIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS, TO THE REST OF THE COMPANY'S KNOWLEDGE AND BELIEF, ACCURATE AND RELIABLE AS OF THE DATE INDICATED. HOWEVER, NO WARRANTY, GUARANTEE OR REPRESENTATION IS MADE AS TO ITS ACCURACY, RELIABILITY OR COMPLETENESS. IT IS THE USER'S RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITABILITY OF SUCH INFORMATION FOR HIS OWN PARTICULAR USE. 5 / 5