SAFETY DATA SHEET 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING REACH REGISTRATION NOTES APPLICATION SUPPLIER This material is a mixture. All components have been registered under REACH by the Manufacturer or Supplier. Industrial solvent/heating Fuel Caldo Oils Limited Head Office Worsley Brow Sutton, StHelens Merseyside KT22 9RX +44(0)1744 8133 CONTACT PERSON info@caldo.co.uk EMERGENCY TELEPHONE Please contact +44(0) 1744 8133 2 HAZARDS IDENTIFICATION CLASSIFICATION (1999/4) Xn;R6. R66. CLASSIFICATION (EC 1272/2008) Physical Flam. Liq. 4 - H227 Health EUH066;Asp. Tox. 1 - H304 Environmental Not classified. LABEL IN ACCORDANCE WITH (EC) NO. 1272/2008 CONTAINS DISTILLATES (PETROLEUM), HYDROTREATED LIGHT; KEROSINE - UNSPECIFIED HAZARD STATEMENTS EUH066 Repeated exposure may cause skin dryness or cracking. H227 Com bus tible liquid. H304 May be fatal if swallowed and enters airways. SUPPLEMENTARY PRECAUTIONARY STATEMENTS P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301/310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331 Do NOT induce vomiting. P370/378 In case of fire: Use for extinction. P403/23 Store in a well-ventilated place. Keep cool. P40 Store locked up. P01 Dispose of contents/container to 3 COMPOSITION/INFORMATION ON INGREDIENTS DISTILLATES (PETROLEUM), HYDROTREATED LIGHT; KEROSINE - UNSPECIFIED 60-99% CAS-No.: 64742-47-8 EC No.: 26-149-8 CLASSIFICATION (EC 1272/2008) Asp. Tox. 1 - H304 CLASSIFICATION (67/48) Xn;R6 1 /
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16 COMPOSITION COMMENTS The material is a mixture 4 FIRST-AID MEASURES PRODUCT NO.:03/060 GENERAL INFORMATION Remove victim immediately from source of exposure. Place unconscious person on the side in the recovery position and ensure breathing can take place. Keep the affected person warm and at rest. Get prompt medical attention. INHALATION Remove victim immediately from source of exposure. Place unconscious person on the side in the recovery position and ensure breathing Get medical attention. INGESTION DO NOT INDUCE VOMITING! When risk of unconsciousness, place and transport the victim in secured side position. Drink plenty of water. Do not give victim anything to drink if he is unconscious. Get medical attention immediately! SKIN CONTACT Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if any discomfort continues. EYE CONTACT Promptly wash eyes with plenty of water while lifting the eye lids. Make sure to remove any contact lenses from the eyes before rinsing. Continue to rinse for at least 1 minutes. Get medical attention if any discomfort continues. FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Stop flow of material to fire. Fire can be extinguished using: Water fog or mist. Foam. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. Do not use water jet as an extinguisher, as this will spread the fire. SPECIAL FIRE FIGHTING PROCEDURES Avoid breathing fire vapours. Use water to keep fire exposed containers cool and disperse vapours. Keep run-off water out of sewers and water sources. Dike for water control. 6 ACCIDENTAL RELEASE MEASURES ENVIRONMENTAL PRECAUTIONS Protect drains by covering to avoid any spillage entering the drainage system. SPILL CLEAN UP METHODS Stop leak if possible without risk. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Wear necessary protective equipment. Absorb in vermiculite, dry sand or earth and place into containers. Disposal should be carried out in accordance with the Hazardous Waste Regulations. If any liquid enters the drainage system or watercourse inform the local authorities, Fire Brigade and Enviroment Agency 7 HANDLING AND STORAGE 2 /
USAGE PRECAUTIONS Do not use in confined spaces without adequate ventilation and/or respirator. Eliminate all sources of ignition. Keep away from heat, sparks and open flame. Avoid inhalation of vapours. USAGE DESCRIPTION Pump at no greater than 7 metres per second. Avoid static build up by suitable earthing arrangements. STORAGE PRECAUTIONS Store in tightly closed original container in a dry, cool and well-ventilated place. Keep away from heat, sparks and open flame. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Name Std TWA - 8 hrs STEL - 1 min Notes DISTILLATES (PETROLEUM), HYDROTREATED LIGHT; KEROSINE - UNSPECIFIED WEL 340 1200 mg/m3 No std. No std. WEL = Workplace Exposure Limit. INGREDIENT COMMENTS WEL = Workplace Exposure Limits PROTECTIVE EQUIPMENT ENGINEERING MEASURES Must not be handled in confined space without sufficient ventilation. RESPIRATORY EQUIPMENT No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational exposure limit. HAND PROTECTION Chemical resistant gloves required for prolonged or repeated contact. Use protective gloves made of: Impermeable material. EYE PROTECTION Wear approved safety goggles. OTHER PROTECTION Wear appropriate clothing to prevent any possibility of liquid contact and repeated or prolonged vapour contact. HYGIENE MEASURES Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly with soap & water if skin becomes contaminated. DO NOT SMOKE IN WORK AREA! 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Liquid COLOUR Colourless to Green ODOUR No characteristic odour. PHYSICAL DATA COMMENTS A non hazardous green dye may have been added at customer request. SOLUBILITY Immiscible with water Soluble in: Organic solvents BOILING POINT ( C) BULK DENSITY AUTO IGNITION TEMPERATURE ( C) FLAMMABILITY LIMIT - UPPER(%) 18-20 760 mm Hg 803 kg/m3 230 7.0 RELATIVE DENSITY FLASH POINT ( C) FLAMMABILITY LIMIT - LOWER(%) 0.803 @ 1 c 70 CC (Closed cup). 0.6 10 STABILITY AND REACTIVITY 3 /
STABILITY No particular stability concerns. Avoid: Heat, sparks, flames. CONDITIONS TO AVOID Avoid excessive heat for prolonged periods of time. HAZARDOUS DECOMPOSITION PRODUCTS Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2). 11 TOXICOLOGICAL INFORMATION HEALTH WARNINGS No specific health warnings noted. 12 ECOLOGICAL INFORMATION ECOTOXICITY Not known. DEGRADABILITY The product is slowly degradable. 13 DISPOSAL CONSIDERATIONS DISPOSAL METHODS This material must be disposed of via an Authorised Waste/Disposal Company in accordance with Local and or National Waste Disposal Regulations. WASTE CLASS This material and container must be disposed of as a HAZARDOUS WASTE. 14 TRANSPORT INFORMATION No transport warning sign required. PROPER SHIPPING NAME Not classified as hazardous for transportation UK ROAD PACK GR. ADR PACK GROUP ADR CLASS HAZARD NO. (ADR) Not classified for transportation. Not relevant IMDG CLASS AIR CLASS EMS 1 REGULATORY INFORMATION UK REGULATORY REFERENCES Health and Safety at Work Act 1974. The Chemical (Hazard Information and Packaging for Supply Regulations) 1993 amended & 2002. Health and Safety (First Aid) Regulations 1981. CDG Road, The Classification, Packaging and Labelling Regulations 1996. EU DIRECTIVES Dangerous Substance Directive 67/48/EEC. Dangerous Preparations Directive 1999/4/EC. STATUTORY INSTRUMENTS The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Control of Substances Hazardous to Health. APPROVED CODE OF PRACTICE Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. GUIDANCE NOTES Workplace Exposure Limits EH40. 16 OTHER INFORMATION INFORMATION SOURCES Fire and Related Properties of Industrial Chemicals, Fire Protection Association. REVISION COMMENTS Issued in new format for REACH compliance R66 and R67 applied according to Hydrocarbon Solvent Producers Association guidelines. Alterations to section(s) 1 2 3 16 4 /
ISSUED BY PCL Technical Team REVISION DATE REV. NO./REPL. SDS GENERATED SDS NO. SAFETY DATA SHEET STATUS Approved. DATE 28/10/2010 6-02/03/09 1087 29/11/02 RISK PHRASES IN FULL R6 Harmful: may cause lung damage if swallowed. HAZARD STATEMENTS IN FULL H304 May be fatal if swallowed and enters airways. DISCLAIMER The information in this document has been compiled on the basis of the best available knowledge in accordance with the legislative requirements. It does not imply that the information is complete or accurate in all cases. It is the user's responsibilty to satisfy themselves as to the application of the information and/or the recommendations given for their own use. /