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Material Safety Data Sheet Section 1: Product & Company Identification Product Name: D-(+)- Raffinose, pentahydrate Product #: R-2621 Synonyms: O-α-D-Galactopyranosyl-(1 6)-α-D-glucopyranosyl β-d-fructofuranoside, Melitose, Melitriose Supplier: A.G. Scientific, Inc. 6450 Lusk Blvd E102 San Diego CA 92121 Tele# + 858-452-9925 Fax# + 858-452-9926 Emergency Tele#: ChemTel, Tele# in USA 1-800-255-3924, International 1-813-248-0585 Section 2: Composition / Information on Ingredients Component CAS# EC # % HCS Classification 17629-30-0 208-146-9 100 Section 3: Hazards Identification Symbols HMIS Classification 0 0 0 -- NFPA Classification 0 0 0 -- 1

Section 4: First Aid Measures General Overview: Inhalation: Skin: Eyes: Ingestion: Avoid contact, wear suitable protective clothing, gloves and eye/face protection. If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If breathing becomes difficult, give artificial respiration and seek medical attention. Wash immediately with water for 15 minutes. Remove contaminated clothing. Wash contaminated clothing before reuse. Seek medical attention if symptoms appear. In case of contact, immediately flush eyes or skin with copious amounts of water for at least 15 minutes. Remove contacts. Assure adequate flushing of the eyes by separating the eyelids with fingers. If swallowed, DO NOT induce vomiting. Wash mouth with water, never give anything to unconscious person. Seek medical attention. See section 11 for more detailed information on health effects & symptoms SECTION 5: Fire Fighting Measures Flammability of the product: Extinguishing Media: Hazardous thermal (de)composition products: Special Fire Fighting Procedures: Flash Point: Extinguishing powder, CO2 or water jet are acceptable extinguishing media. Utilize water jets or alcohol-resistant foam for larger fires. No decomposition noted, must be stored under recommended specifications. Wear self-contained breathing apparatus (SCBA) and protective clothing to prevent contact with skin and eyes. Be sure to use an approved/certified respirator or equivalent. Section 6: Accidental Release Measures Personal Precautions: Environmental Precautions: Methods for Clean-up: Use Personal Protection Equipment. Splash goggles. Gloves. Avoid dust formation. Do not let product enter drains. Sweep up & shovel into suitable disposal container. Ventilate area and wash spill site after material pickup is complete. SECTION 7: Handling & Storage Storage: Handling: Store at -20 C and protect from light. Keep container tightly sealed with inert gas and in cool, dry, well ventilated area. Use only in area provided with appropriate exhaust ventilation and protective gas. SECTION 8: Exposure controls / Personal Protection 2

Respiratory Protection: Skin and Body: Breathing protection with high concentration. Eyes: Chemical-resistant gloves and lab coat/other protective clothing. Avoid prolonged or repeated exposure. Wash thoroughly after handling. Ventilation/Engineering Measures: Hygiene: Other: Safety goggles. Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. Wash hands after handling compound and before eating, smoking, using lavatory and at the end of the day. Contains no substances with occupational exposure limit values. SECTION 9: Physical and Chemical Properties Appearance & Odor: A crystalline solid, odorless Formula C18H32O16 5H2O Molecular Wt. 594.5 gm/mol Melting Pt. 80 C Boiling Pt. Density: 1.47 Vapor Pressure: Evaporation Rate: Vapor Density: Solubility: Flash Point: Autoignition Temp: 3

SECTION 10: Stability and Reactivity Stability: Hazardous decomposition products: Materials to Avoid: Conditions to avoid: Stable under proper storage conditions Carbon monoxide, carbon dioxide No decomposition noted, must be stored under recommended specifications. SECTION 11: Toxicological Information RTECS#: ACUTE Toxicity: CHRONIC Toxicity: Chronic Exposure: Carcinogen: Mutagen: Teratogen: Reproductive: IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. AGGIH: No component of this product present at levels greater than or equal to 0.1% is identified as probable, potential human carcinogen by ACGIH. NTP: No component of this product present at levels greater than or equal to 0.1% is identified as known or, anticipated human carcinogen by NTP. OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as known or, potential human carcinogen by OSHA. EPA: No classification on carcinogenic data is available from EPA SECTION 12: Ecological Information Ecotoxicity: Mobility: Persistence and degradability: Bioaccumulative potential: Other adverse effects: Corrosivity Characteristic: General Notes: Do not allow undiluted product or large quantities of it to reach groundwater, water course or sewer system. Do not allow materials to be released into the environment without proper government permits. SECTION 13: Disposal Considerations Residue Waste or Unused product: Contaminated Packaging: Only professional staff trained in such techniques must undertake waste disposal. Observe all appropriate federal, provincial or state and local regulations. Do not re-use empty containers. Dispose of as unused product. 4

SECTION 14: Transportation Information UN ID#: ADR / RID (LAND): DOT regulations: IMDG/IMO (SEA): IATA/DGR (AIR): Special Provisions: SECTION 15: Regulatory Information Health Phrases: Risk Phrases: Safety Phrases: EU Regulations: US Regulations: U.S. Federal Regulations: WHMIS (Canada): TSCA. No products were found. California Proposition 65: No products were found. SARA 302/304/311/312 extremely hazardous substances: No products were found SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: No products were found. SARA 311/312 MSDS distribution-chemical inventory-hazard identification: No products were found. SARA 313 toxic chemicals notification and release reporting: No products were found. Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: No products were found. Clean Air Act (CAA) 112 accidental release prevention: No products were found. Clean Air Act (CAA) 112 regulated flammable substances: No products were found. Clean Air Act (CAA) 112 regulated toxic substances: No products were found. OSHA: No products were found. SECTION 16: Other Information LIABILITY STATEMENT: The above information is believed to be correct but does not purport to be all-inclusive and shall be used only as a guide. A.G. Scientific shall not be held liable for any damages resulting from handling or from contact with the above product. A.G. Scientific products are for research purposes only. Not for human use or consumption. 5