SAFETY DATA SHEET acc.to ISO/DIS for USA 1 PRODUCT AND COMPANY IDENTIFICATION

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Transcription:

SAFETY DATA SHEET acc.to ISO/DIS 11014 for USA 1 PRODUCT AND COMPANY IDENTIFICATION Product identifier Relevant identified uses of the substance or mixture and uses advised against Identified uses: Lubricating grease Uses advised against: No uses advised against identified. Details of the supplier of the safety data sheet Manufacturer Fuchs Europe Schmierstoffe GmbH Friesenheimer Str. 19 68169 Mannheim Telephone: 0621 3701-0 (ZENTRALE) Fax: 0621 3701-570 Contact Person: Fuchs Europe Schmierstoffe GmbH Abteilung Produktsicherheit Telephone: 0621 3701-1333 Fax: 0621 3701-7303 e-mail: PRODUKTSICHERHEIT@FUCHS-EUROPE.DE US contact telephone : 708-333-8900 Emergency telephone: 800-255-3924 2 HAZARDS IDENTIFICATION Classification of the substance or mixture The product has not been classified as hazardous, but needs to be labelled according to the legislation in force. Hazard summary Physical Hazards: Health Hazards Inhalation: Eye contact: Skin Contact: Ingestion: Other Health Effects: By handling of mineral oil products and chemical products no particular hazard is known when normal precautions (item 7) and personal protective equipment (item 8) are kept. SDS_US - 000000000600656096 1/8

Environmental hazards: This product is water polluting. Label Elements Safety data sheet available for professional user on request. Other hazards: HMIS Hazard ID HEALTH 0 FLAMMABILITY 1 PHYSICAL HAZARDS 0 PERSONAL PROTECTION Hazard rating: 0 - Minimal; 1 - Slight; 2 - Moderate; 3 - Serious; 4 - Severe; *Chronic health effect 3 COMPOSITION / INFORMATION ON INGREDIENTS Mixtures General information: Lubricating grease: Thickener system and additives in synthetic base oil. Chemical name Concentration * Identifier Notes >=1.00 - <2.40% 26780-96-1 >=0.10 - <1.00% 1303-96-4 ** * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. # This substance has workplace exposure limit(s). Classification Chemical name Classification CLP: Aquatic Chronic 3;H412 CLP: Repr. 1B;H360, Eye Dam. 2;H319 DSD: Directive 67/548/EEC. CLP: Regulation No. 1272/2008. 4 FIRST AID MEASURES General: Description of first aid measures Inhalation: Eye contact: Skin Contact: Ingestion: Change clothes and shoes contaminated or soaked by the product. Never put rags contaminated by the product into cloth-pockets. Supply fresh air; consult doctor in case of symptoms. Promptly wash eyes with plenty of water while lifting the eye lids. Wash with soap and water. The product is not skin irritating. Rinse mouth thoroughly. SDS_US - 000000000600656096 2/8

Most important symptoms and effects, both acute and delayed: May cause skin and eye irritation. Indication of any immediate medical attention and special treatment needed Hazards: Treatment: Get medical attention if symptoms occur. 5 FIRE-FIGHTING MEASURES Extinguishing media Suitable extinguishing media: Unsuitable extinguishing media: Special hazards arising from the substance or mixture: Advice for firefighters Special fire fighting procedures: Special protective equipment for fire-fighters: CO2, fire extinguishing powder or fog like water spraying. Extinguish larger fires with alcohol resistant foam or spray water with suitable tensides added Water with a full water jet. During fire, gases hazardous to health may be formed. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. 6 ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures: Environmental Precautions: Methods and material for containment and cleaning up: Reference to other sections: Not required. Avoid release to the environment. Environmental manager must be informed of all major spillages. Prevent further leakage or spillage if safe to do so. Do not allow to enter drainage system, surface or ground water. Scrape up spillage or absorb with absorbing material. Dispose of the material collected according to regulations. No dangerous decomposition substances known 7 HANDLING AND STORAGE Precautions for safe handling: Conditions for safe storage, including any incompatibilities: Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Local regulations concerning handling and storage of waterpolluting products have to be followed. SDS_US - 000000000600656096 3/8

Specific end use(s): Not available. 8 EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits Chemical name Type Exposure Limit Values Source Molybdenum thiocarbamate - Inhalable fraction. - as Mo TWA 10 mg/m3 US. ACGIH Threshold Limit Values (02 Molybdenum thiocarbamate - Respirable fraction. - as Mo TWA 3 mg/m3 US. ACGIH Threshold Limit Values (02 Molybdenum thiocarbamate - Respirable fraction. - as Mo TWA 0.5 mg/m3 US. ACGIH Threshold Limit Values (02 Molybdenum thiocarbamate - Total dust. - as Mo PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Molybdenum thiocarbamate - as Mo PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) (02 2006) Molybdenum thiocarbamate - Total dust. - as Mo TWA 10 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Molybdenum thiocarbamate - as Mo TWA 5 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) - Inhalable fraction. STEL 6 mg/m3 US. ACGIH Threshold Limit Values (02 - Inhalable fraction. TWA 2 mg/m3 US. ACGIH Threshold Limit Values (02 TWA 10 mg/m3 US. OSHA Table Z-1-A (29 CFR 1910.1000) (1989) Exposure controls Appropriate engineering controls: Individual protection measures, such as personal protective equipment General information: Eye/face protection: Skin protection Hand Protection: Other: Respiratory Protection: Wash hands before breaks and after work. Use personal protective equipment as required. Personal protection equipment should be chosen according to the CEN standards and in discussion with the supplier of the personal protective equipment. The usual precautionary measures should be adhered to inhandling the chemicals or the mineral oil products. Wear goggles/face shield. Nitrile butyl rubber (NBR). Avoid long-term and repeated skin contact. Suitable gloves can be recommended by the glove supplier. Use skin protection cream for preventive skin protection. Protective gloves, where permitted in acc. to safety directions. The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed. Do not carry cleaning cloths impregnated with the product in trouser pockets. Wear suitable protective clothing. In case of inadequate ventilation use suitable respirator. Seek advice from local supervisor. Avoid breathing vapour/ aerosol. SDS_US - 000000000600656096 4/8

Thermal hazards: Hygiene measures: Environmental Controls: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing to remove contaminants. Discard contaminated footwear that cannot be cleaned. 9 PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State: Solid Form: Paste Color: Yellow Odor: Characteristic Odor Threshold: ph: Not applicable Melting Point: Boiling Point: Not applicable Flash Point: Not applicable Evaporation Rate: Flammability (solid, gas): Flammability Limit - Upper (%) : Flammability Limit - Lower (%) : Vapor pressure: Vapor density (air=1): Density: 0.9000 g/cm3 (25 C) Solubility(ies) Solubility in Water: Insoluble in water Solubility (other): Partition coefficient (n-octanol/water): Autoignition Temperature: Decomposition Temperature: NLGI: 1 Flow time Explosive properties: Oxidizing properties: 10 STABILITY AND REACTIVITY Reactivity: Chemical Stability: Possibility of Hazardous Reactions: Stable under normal temperature conditions and recommended use. None under normal conditions. SDS_US - 000000000600656096 5/8

Conditions to Avoid: Incompatible Materials: Hazardous Decomposition Products: Avoid heat or contamination. Strong oxidizing substances. Strong acids. Strong bases. Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapors. 11 TOXICOLOGICAL INFORMATION Specified substance(s): Acute Toxicity (Oral); Acute Toxicity (Dermal): Inhalation: LD 50 (Rat): 490 mg/kg LD 50 (Rat): 2,660 mg/kg LD 50 (Rabbit): > 5,100 mg/kg LD 50 (Rat): > 10,000 mg/kg Ingestion: Skin Corrosion/Irritation: Serious Eye Damage/Eye Irritation: Respiratory sensitizer/skin sensitizer: Carcinogenicity: Mutagenesis: Reproductive Toxicity: 12 ECOLOGICAL INFORMATION SDS_US - 000000000600656096 6/8

Ecotoxicity: Specified substance(s): Acute toxicity(fish): LC 50 (Fish, 96 h): 50-64 mg/l LC 50 (Fish, 96 h): 74 mg/l Acute toxicity(aquatic Invertebrates): EC 50 (Water Flea, 48 h): 56 mg/l EC 50 (Water Flea, 48 h): 1,085-1,400 mg/l Acute toxicity(aquatic plants): EC 50 (Alga, 72 h): > 100 mg/l EC 50 (Alga): 158 mg/l Persistence and Degradability: Bioaccumulative Potential: Mobility: 13 DISPOSAL CONSIDERATIONS Disposal methods: Measures for Avoidance and Recovery: Do not empty into drains; dispose of this material and its container in a safe way. When storing used products, ensure that the waste categories and mixing instructions are observed. Dispose in accordance with all applicable regulations. 14 TRANSPORT INFORMATION DOT Not regulated. IMDG - International Maritime Dangerous Goods Code Not regulated. IATA Not regulated. 15 REGULATORY INFORMATION US Federal Regulations US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) SDS_US - 000000000600656096 7/8

CERCLA Hazardous Substance List (40 CFR 302.4): Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Not listed. SARA 302 Extremely Hazardous Substance SARA 304 Emergency Release Notification SARA 311/312 Hazardous Chemical: SARA 313 (TRI Reporting) Other federal regulations Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130): US State Regulations US. California Proposition 65 US. New Jersey Worker and Community Right-to-Know Act US. Massachusetts RTK - Substance List US. Pennsylvania RTK - Hazardous Substances US. Rhode Island RTK Inventory Status DSL TSCA On or in compliance with the inventory On or in compliance with the inventory 16 OTHER INFORMATION Revision Information: Revision Date: 05.09.2014 SDS No.: Disclaimer: The data contained in this safety data sheet are based on our current knowledge and experience and are given to the best of our knowledge and belief. It characterizes the product only with regard to safety requirements for handling, transport and disposal. The data do not describe the product's properties (tech. product specification). Neither should any agreed property nor the suitability of the product for any specific technical application be deduced from the data contained in this safety data sheet. Modifications on this document are not allowed. The data are not transferable to other products. In the case of mixing the product with other products or in the case of processing, the data in this safety data sheet are not necessarily valid for the new-made material. It is the responsibility of the recipient of the product to observe federal, state and local law. Please contact us to obtain up-to-date safety data sheets. This document was issued electronically and has no signature. SDS_US - 000000000600656096 8/8