Date of issue: 09/24/2018 Version: 1.0 SECTION 1: Identification 1.1. Identification Product form : Mixture Trade name : Synonyms : 100210044, 100210045, 100210046, 100210047, 100210048, 100210252, 100526538 1.2. Recommended use and restrictions on use Recommended use : Fertilizer. Restrictions on use : Keep out of reach of children. Avoid contact with eyes, skin or clothing. 1.3. Supplier OGM - Hydro Organics Wholesale, Inc. 295 Convair Avenue Chico, CA 95973-9013 - United States 1-800-882-1231 (Consumer Inquiries) info@hydro-organics.com 1.4. Emergency telephone number Emergency number : 1-800-305-1446 1-800-424-9300 - CHEMTREC 1-703-527-3887 - CHEMTREC - Outside North America - Collect Calls Accepted SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Serious eye damage/eye irritation Category 2A Causes serious eye irritation 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : Causes serious eye irritation : Wash hands, forearms and face thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention. 2.3. Other hazards which do not result in classification Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures : Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. 09/24/2018 EN (English US) Page 1
Name Product identifier % Ammonium calcium nitrate (CAS-No.) 15245-12-2 4.484 Other ingredients (CAS-No.) N/A Balance SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. : IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Do NOT induce vomiting unless directed to do so by medical personnel. 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects after eye contact : Causes serious eye irritation. 4.3. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Unsuitable extinguishing media 5.2. Specific hazards arising from the chemical Reactivity : Use extinguishing agent suitable for surrounding fire. : Avoid heavy hose streams. 5.3. Special protective equipment and precautions for fire-fighters Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : The product is non-reactive under normal conditions of use, storage and transport. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment Emergency procedures : Ventilate spillage area. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: Exposure controls/personal protection. : No emergency procedures are expected to be necessary if material is used under ordinary conditions as recommended. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Absorb spills with an inert material, clay granules or other inert absorbent material and put in container for disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep cool. Protect from sunlight. Keep container tightly closed. Keep only in original container. Avoid excess heat. 09/24/2018 EN (English US) 2/5
SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Appropriate engineering controls Appropriate engineering controls Environmental exposure controls : Adequate ventilation systems as needed to control concentrations of airborne contaminants below applicable threshold limit values. : Avoid release to the environment. 8.3. Individual protection measures/personal protective equipment Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: If prolonged exposure is anticipated, it is recommented for handlers to wear appropriate clothing to prevent skin contact. Respiratory protection: In case of insufficient ventilation, use NIOSH approved respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Black liquid Color : Black Odor Odor threshold ph : 3.45-3.7 Melting point Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties : Not explosive Oxidizing properties 09/24/2018 EN (English US) 3/5
9.2. Other information SECTION 10: Stability and reactivity 10.1. Reactivity The product is non-reactive under normal conditions of use, storage and transport. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid Excessive heat. 10.5. Incompatible materials Strong acids. Strong bases. Strong oxidizing agents. 10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information 11.1. Information on toxicological effects ph 3.45-3.7 GHS-US Properties toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cells mutagen Carcinogenicity Reproductive toxicity Specific target organ toxicant (single exposure) Specific target organ toxicant (repeated exposure) Aspiration hazard Classification Causes serious eye irritation. Potential health effects Inhalation Skin Eye Ingestion : Causes serious eye irritation. SECTION 12: Ecological information 12.1. Toxicity 12.2. Persistence and degradability 12.3. Bioaccumulative potential 09/24/2018 EN (English US) 4/5
12.4. Mobility in soil 12.5. Other adverse effects SECTION 13: Disposal considerations 13.1. Disposal methods Product/Packaging disposal recommendations : Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. SECTION 14: Transport information UN number Proper Shipping Name Transport hazard class(es) Packing group Environmental hazards DOT Not regulated Not regulated Not regulated Not regulated Not applicable IMDG Not regulated Not regulated Not regulated Not regulated Not applicable IATA Not regulated Not regulated Not regulated Not regulated Not applicable SECTION 15: Regulatory information 15.1. US Federal regulations 15.2. US State regulations SECTION 16: Other information Date of issue : 24 September 2018 SDS US (GHS HazCom 2012) - CGP The information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. 09/24/2018 EN (English US) 5/5