Date of issue: 9/7/2016 Revision date: Supersedes: Version: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : Product code : 33754F 10% Type of product : Perfumes, Fragrances Product group : Finished Good 1.2. Relevant identified uses of the substan ce or mixture and uses advised against 1.2.1. Relevant identified uses Main use category Industrial/Professional use spec Use of the substance/mixture Function or use category : Industrial use,professional use : For professional use only Industrial : Perfumes, Fragrances : Odour agents 1.2.2. Uses advised against 1.3. Details of the supplier of the safety data sheet Supplies For Candles Unit 3a, Denaby Main Industrial Estate, Doncaster, South Yorkshire DN12 4LH info@suppliesforcandles.co.uk - www.suppliesforcandles.co.uk 1.4. Emergency telephone number Emergency number : +441709 588579 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Sensitisation Skin, H317 Category 1 Hazardous to the aquatic H412 environment Chronic Hazard, Category 3 Full text of hazard classes and H-statements : see section 16 Adverse physicochemical, human health and environmental effects Harmful to aquatic life with long lasting effects. May cause an allergic skin reaction. 2.2. Label elements Labelling according to Regulation (EC) No. 12 : 2008 [CLP] Extra labelling to displayextra classification(s) to display Hazard pictograms (CLP) GHS07
Signal word (CLP) : Warning Hazardous ingredients : Aldehyde C-16 Hazard statements (CLP) Precautionary statements (CLP) : H317 - May cause an allergic skin reaction H412 - Harmful to aquatic life with long lasting effects : P261 - Avoid breathing dust/fume/gas/mist/vapours/spray P272 - Contaminated work clothing should not be allowed out of the workplace P273 - Avoid release to the environment P280 - Wear protective gloves/protective clothing/eye protection/face protection 9/7/2016 EN (English) 1/6 P302+P352 - IF ON SKIN: Wash with plenty of water P321 - Specific treatment (see supplemental first aid instruction on this label) 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Aldehyde C-16 (CAS No) 77-83-8 (EC no) 201-061-8 methyl anthranilate (CAS No) 134-20-3 (EC no) 205-132-4 HEXAMETHYLINDANOPYRAN (CAS No) 1222-05-5 (EC no) 214-946-9 (EC index no) 603-212-00-7 Allergen report available upon request. Full text of H-statements: see section 16 0.434-1.834 Aquatic Chronic 2, H411 Skin Sens. 1B, H317 0.372-1.572 Eye Irrit. 2, H319 0.155-0.655 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove person to fresh air and keep comfortable for breathing. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. : Rinse eyes with water as a precaution. : Call a poison center or a doctor if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact : May cause an allergic skin reaction. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. 5.2. Special hazards arising from the substance or mixture Hazardous decomposition products in case of : Toxic fumes may be released. fire 5.3. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 9/7/2016 EN (English) 2/9
6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment 6.2. Environmental precautions : Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Wear personal protective equipment. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep cool. Storage temperature : 25 C Storage area Special rules on packaging Packaging materials : Store in a well-ventilated place. Store away from heat. : Store in a closed container. : Do not store in corrodable metal. 7.3. Specific end use(s) SECTION 8: Exposure controls/person al protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection : Ensure good ventilation of the work station. : Protective gloves : Safety glasses 9/7/2016 EN (English) 3/9
Skin and body protection Respiratory protection Environmental exposure controls : Wear suitable protective clothing : In case of insufficient ventilation, wear suitable respiratory equipment : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : light yellow. amber. Odour : Fruity. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point : Freezing point Boiling point Flash point : > 93.33 C Not Applicable Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information 9/7/2016 EN (English) 4/9
SECTION 10: Stability and reactivity 10.1. Reactivity The product is non-reactive under normal conditions of use, storage and transport. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid None under recommended storage and handling conditions (see section 7). 10.5. Incompatible materials 10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard : May cause an allergic skin reaction. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : Harmful to aquatic life with long lasting effects. 12.2. Persistence and degradability 12.3. Bioaccumulative potential 12.4. Mobility in soil 9/7/2016 EN (English) 5/9
12.5. Results of PBT and vpvb assessment 12.6. Other adverse effects SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. 9/7/2016 EN (English) 6/9
SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number UN-No. (ADR) UN-No. (IMDG) UN-No. (IATA) UN-No. (ADN) UN-No. (RID) : : : : : 14.2. UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) : : : : : 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) 14.4. Packing group : : : : : Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) : : : : : 14.5. Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available 14.6. Special precautions for user 9/7/2016 EN (English) 7/9
- Overland transport - Transport by sea - Air transport - Inland waterway transport - Rail transport 14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations The following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006: 3. Liquid substances or mixtures which are regarded as dangerous in accordance with Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008 Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances HEXAMETHYLINDANOPYRAN 15.1.2. National regulations Germany VwVwS Annex reference 12th Ordinance Implementing the Federal Immission Control Act - 12.BImSchV Netherlands SZW-lijst van kankerverwekkende stoffen SZW-lijst van mutagene stoffen NIET-limitatieve lijst van voor de voortplanting giftige stoffen Borstvoeding NIET-limitatieve lijst van voor de voortplanting giftige stoffen Vruchtbaarheid NIET-limitatieve lijst van voor de voortplanting giftige stoffen Ontwikkeling Denmark Classification remarks Recommendations Danish Regulation : Water hazard class (WGK) 1, low hazard to waters (Classification according to VwVwS, Annex 4) : Is not subject of the 12. BlmSchV (Hazardous Incident Ordinance) : Emergency management guidelines for the storage of flammable liquids must be followed : Young people below the age of 18 years are not allowed to use the product 15.2. Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Full text of H- and EUH-statements: Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 9/7/2016 EN (English) 8/9
Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Sens. 1 Sensitisation Skin, Category 1 Skin Sens. 1B H317 H319 H400 H410 H411 H412 FCF SDS EU CLP. Sensitisation Skin, category 1B May cause an allergic skin reaction Causes serious eye irritation Very toxic to aquatic life Very toxic to aquatic life with long lasting effects Toxic to aquatic life with long lasting effects Harmful to aquatic life with long lasting effects 9/7/2016 EN (English) 9/9