1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Identification of the substance or mixture Product name Product type Product description Use of the substance/mixture Sector of Use None identified. Supplier/Manufacturer email address of person responsible for this SDS Emergency telephone number (with hours of operation) 2. Liquid. Supplemental coolant additive. Chemical Product Category HAZARDS IDENTIFICATION Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II SAFETY DATA SHEET Process Category Article Category Environmental Release Category Dober 11230 Katherine's Crossing Woodridge, IL 605175075 regulatory@dobergroup.com ChemTel +018132480585 24 hours The product is classified as dangerous according to Directive 1999/45/EC and its amendments. Classification Human health hazards Causes burns. See Section 11 for more detailed information on health effects and symptoms. 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/preparation Ingredient name Europe Mixture Sweden CAS number % Number Classification Denmark Date of issue 03/22/2011. Page 1/13
3. Norway COMPOSITION/INFORMATION ON INGREDIENTS disodium metasilicate 6834920 1030 2299129 sodium benzothiazol2yl sulphide 2492264 15 2196608 Xn; R21 sodium 4(or 5)methyl1Hbenzotriazolide 64665572 15 2650049 Xn; R22 France Netherlands Germany Finland United Kingdom (UK) Date of issue 03/22/2011. Page 2/13
3. Austria Belgium COMPOSITION/INFORMATION ON INGREDIENTS Switzerland Ireland Estonia Lithuania Slovakia Date of issue 03/22/2011. Page 3/13
3. COMPOSITION/INFORMATION ON INGREDIENTS [2] Slovenia Latvia [2] Bulgaria There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Substance classified with a health or environmental hazard [2] Substance with a workplace exposure limit [3] PBTsubstance [4] vpvbsubstance Occupational exposure limits, if available, are listed in Section 8. 4. FIRST AID MEASURES Firstaid measures Eye contact Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Date of issue 03/22/2011. Page 4/13
4. FIRST AID MEASURES Skin contact Inhalation Get medical attention immediately. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or selfcontained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouthtomouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Ingestion Get medical attention immediately. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Protection of firstaiders No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or selfcontained breathing apparatus. It may be dangerous to the person providing aid to give mouthtomouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. See Section 11 for more detailed information on health effects and symptoms. 5. FIREFIGHTING MEASURES Extinguishing media Suitable Not suitable Special exposure hazards Hazardous thermal decomposition products Special protective equipment for firefighters Use an extinguishing agent suitable for the surrounding fire. None known. In a fire or if heated, a pressure increase will occur and the container may burst. Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Decomposition products may include the following materials carbon dioxide carbon monoxide nitrogen oxides sulfur oxides metal oxide/oxides Firefighters should wear appropriate protective equipment and selfcontained breathing apparatus (SCBA) with a full facepiece operated in positive pressure mode. Clothing for firefighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. Date of issue 03/22/2011. Page 5/13
6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Methods for cleaning up Small spill Large spill No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Do not breathe vapour or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment (see Section 8). Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Stop leak if without risk. Move containers from spill area. Dilute with water and mop up if watersoluble. Alternatively, or if waterinsoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Stop leak if without risk. Move containers from spill area. Approach the release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilt product. 7. HANDLING AND STORAGE Handling Put on appropriate personal protective equipment (see Section 8). Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. Do not get in eyes or on skin or clothing. Do not breathe vapour or mist. Do not ingest. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Keep away from acids. Empty containers retain product residue and can be hazardous. Do not reuse container. Storage Packaging materials Recommended Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and wellventilated area, away from incompatible materials (see section 10) and food and drink. Separate from acids. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination. Use original container. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure limit values Ingredient name Europe Occupational exposure limits Sweden Denmark Norway France Netherlands Date of issue 03/22/2011. Page 6/13
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Germany Finland United Kingdom (UK) Austria Switzerland Belgium Spain Turkey Czech Republic Ireland Italy Estonia Lithuania Slovakia sodium poly acrylate Nariadenie Vlády Slovenskej republiky (Slovakia, 6/2007). TWA 5 mg/m³ 8 hour(s). Form total compact aerosols Hungary Poland Slovenia Latvia sodium poly acrylate Greece LV Nat. Standardisation and Meterological Centre (Latvia, 5/2007). TWA 5 mg/m³ 8 hour(s). Form dust Portugal Bulgaria Romania Date of issue 03/22/2011. Page 7/13
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Recommended monitoring procedures If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances. Exposure controls Occupational exposure controls If user operations generate dust, fumes, gas, vapour or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Hygiene measures Respiratory protection Hand protection Eye protection Skin protection Environmental exposure controls Protection based on MAL Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Use a properly fitted, airpurifying or airfed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemicalresistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. According to the regulations on work involving coded products, the following stipulations apply to the use of personal protective equipment General Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be worn when soiling is so great that regular work clothes do not adequately protect skin against contact with the product. A face shield must be worn in work involving spattering if a full mask is not required. In this case, other recommended use of eye protection is not required. In all spraying operations in which there is return spray, the following must be worn respiratory protection and arm protectors/apron/coveralls/protective clothing as appropriate or as instructed. MALcode 004 Application When using scraper or knife, brush, roller etc. for pre and posttreatments in a spray booth where the operator is outside the spray zone and when working in similar new* facilities of the combinedcabin, spraycabin and spraybooth type where the operator is working inside the spray zone. When spraying in new* booths and cabins with nonatomizing guns. When spraying in existing* spray booths, if the operator is outside the spray zone. During downtimes, cleaning and repair in closed facilities, spray booths or cabins, if there is a risk of contact with wet paint or organic solvents. During nonatomising spraying in existing* facilities of the combinedcabin, spraycabin and spraybooth type where the operator is working inside the spray zone. When using scraper or knife, brush, roller, etc, for pre and posttreatments in cabins or booths of the existing* facility type, if the operator is inside the spray zone. When using scraper or knife, brush, roller, etc. for pre and posttreatments outside a closed facility, spray booth or spray cabin. Date of issue 03/22/2011. Page 8/13
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Protective clothing must be worn. During all spraying where atomisation occurs in cabins or spray booths where the operator is inside the spray zone and during spraying outside a closed facility, cabin or booth. Airsupplied full mask, protective clothing and hood must be worn. 9. Drying Items for drying/drying ovens that are temporarily placed on such things as rack trolleys, etc, must be equipped with a mechanical exhaust system to prevent fumes from wet items from passing through workers' inhalation zone. Polishing When polishing treated surfaces, a mask with dust filter must be worn. When machine grinding, eye protection must be worn. Work gloves must always be worn. Caution The regulations contain other stipulations in addition to the above. *See Regulations. PHYSICAL AND CHEMICAL PROPERTIES General information Physical state Relative density Solubility Viscosity Vapour density Volatility Liquid. [Clear.] Colour Colourless. Odour Thiazole [Slight] Important health, safety and environmental information ph 12.7 to 13.7 10. Conditions to avoid Hazardous decomposition products 1.2 to 1.23 Easily soluble in the following materials cold water and hot water. Not available. >1 [Air = 1] > 50% (v/v) STABILITY AND REACTIVITY Chemical stability Possibility of hazardous reactions Materials to avoid 11. The product is stable. Avoid excessive heat. TOXICOLOGICAL INFORMATION Toxicokinetics Absorption Potential acute health effects Inhalation Under normal conditions of storage and use, hazardous reactions will not occur. Reactive or incompatible with the following materials oxidizing materials, reducing materials, metals, acids and alkalis. Under normal conditions of storage and use, hazardous decomposition products should not be produced. Not available. Distribution Contains material which may cause damage to the following organs upper respiratory tract, skin, eye, lens or cornea. Metabolism Not available. Elimination Not available. Ingestion Skin contact May give off gas, vapor or dust that is very irritating or corrosive to the respiratory system. Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. May cause burns to mouth, throat and stomach. Corrosive to the skin. Causes burns. Date of issue 03/22/2011. Page 9/13
11. TOXICOLOGICAL INFORMATION Eye contact Corrosive to eyes. Causes burns. Product/ingredient name Result Species Dose Exposure disodium metasilicate LD50 Oral Rat >1000 mg/kg sodium benzothiazol2yl sulphide LD50 Dermal Rabbit >1250 mg/kg LD50 Oral Rat 5200 mg/kg sodium poly acrylate LD50 Oral Rat >40 g/kg sodium 4(or 5)methyl1Hbenzotriazolide LD50 Dermal Rabbit >2000 mg/kg LD50 Oral Rat 640 mg/kg Potential chronic health effects Chronic effects Carcinogenicity Mutagenicity Teratogenicity Developmental effects No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards. Fertility effects No known significant effects or critical hazards. Overexposure signs/symptoms Inhalation No specific data. Ingestion Skin Eyes 12. Ecotoxicity ECOLOGICAL INFORMATION Aquatic ecotoxicity Product/ingredient name disodium metasilicate sodium benzothiazol2yl sulphide Conclusion/Summary Persistence/degradability Other adverse effects PBT Adverse symptoms may include the following stomach pains Adverse symptoms may include the following pain or irritation redness blistering may occur Adverse symptoms may include the following pain watering redness No known significant effects or critical hazards. Not available. No known significant effects or critical hazards. Not applicable. Species Exposure Result Daphnia Water 48 hours Acute EC50 33.53 mg/l Fresh water flea Ceriodaphnia dubia Neonate <24 hours Algae Green 72 hours Acute EC50 0.4 mg/l Fresh water algae Pseudokirchneriella subcapitata Algae Green 96 hours Acute EC50 0.3 mg/l Fresh water algae Pseudokirchneriella subcapitata Daphnia Water 48 hours Acute EC50 2.9 ppm Fresh water flea Daphnia magna <24 hours Fish Rainbow 96 hours Acute LC50 0.73 ppm Fresh water trout,donaldson trout Oncorhynchus mykiss Date of issue 03/22/2011. Page 10/13
12. ECOLOGICAL INFORMATION P Not available. B Not available. T Not available. vpvb Not applicable. 13. DISPOSAL CONSIDERATIONS Methods of disposal The generation of waste should be avoided or minimised wherever possible. Significant quantities of waste product residues should not be disposed of via the foul sewer but processed in a suitable effluent treatment plant. Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor. Disposal of this product, solutions and any byproducts should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Hazardous waste The classification of the product may meet the criteria for a hazardous waste. Norway Hazardous waste The classification of the product may meet the criteria for a hazardous waste. 14. TRANSPORT INFORMATION International transport regulations Regulatory information UN number Proper shipping name Classes PG* Label Additional information ADR/RID Class Refer to bill of lading ADN/ADNR Class Refer to bill of lading IMDG Class Refer to bill of lading IATA Class Refer to bill of lading PG* Packing group The transport classification and information above has been approved by Dober. 15. REGULATORY INFORMATION Chemical Safety Assessment This product contains substances for which Chemical Safety Assessments are still required. EU regulations Classification and labeling have been determined according to EU Directives 67/548/EEC and 1999/45/EC (including amendments) and take into account the intended product use. Hazard symbol or symbols Risk phrases Safety phrases Contains Product use Europe inventory Black List Chemicals Corrosive R34 Causes burns. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). disodium metasilicate Industrial applications. Not determined. Not listed Date of issue 03/22/2011. Page 11/13
15. REGULATORY INFORMATION Priority List Chemicals Integrated pollution prevention and control list (IPPC) Air Not listed Not listed Integrated pollution prevention and control list (IPPC) Water National regulations Denmark Hazard symbol or symbols Not listed Risk phrases Safety phrases Contains Norway Hazard symbol or symbols R34 Causes burns. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). MALcode 004 Restrictions on use Not to be used by professional users below 18 years of age. See the National Working Environment Authorities Executive Order on young people's dangerous work. List of undesirable substances Corrosive disodium metasilicate Not listed Risk phrases Safety phrases Carcinogenic class Contains France Reinforced medical surveillance Netherlands Water Discharge Policy (ABM) Germany Hazard class for water Austria Limitation of the use of organic solvents Switzerland VOC content Italy Corrosive R34 Causes burns. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Not classified. disodium metasilicate Act of July 11, 1977 determining the list of activities which require reinforced medical surveillance not applicable Toxic to aquatic organisms. Contains substances that are harmful to the aquatic environment. Abatement effort A 2 Appendix No. 4 Permitted. Liberated. Date of issue 03/22/2011. Page 12/13
0 15. REGULATORY INFORMATION D.Lgs. 152/06 International regulations Not classified. Chemical Weapons Convention Not listed List Schedule I Chemicals Chemical Weapons Convention Not listed List Schedule II Chemicals Chemical Weapons Convention Not listed List Schedule III Chemicals 16. OTHER INFORMATION Full text of Rphrases referred to in sections 2 and 3 Full text of classifications referred to in sections 2 and 3 Sector of Use None identified. History Date of issue/ Date of revision Date of previous issue Version R21 Harmful in contact with skin. R22 Harmful if swallowed. R34 Causes burns. R36 Irritating to eyes. R37 Irritating to respiratory system. R50 Very toxic to aquatic organisms. C Corrosive Xn Harmful Xi Irritant N Dangerous for the environment Chemical Product Category 03/22/2011. No previous validation. 1 Process Category Article Category Environmental Release Category Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the abovenamed supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Date of issue 03/22/2011. Page 13/13